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1.
Simen Gjelseth Antonsen Arne Joakim C. Bunkan Tomas Mikoviny Yngve Stenstrøm Armin Wisthaler 《Molecular physics》2020,118(15)
The kinetics of the O3, OH and NO3 radical reactions with diazomethane were studied in smog chamber experiments employing long-path FTIR and PTR-ToF-MS detection. The rate coefficients were determined to be k CH2NN+O3?=?(3.2?±?0.4)?×?10?17 and k CH2NN+OH?=?(1.68?±?0.12)?×?10?10 cm3 molecule?1 s?1 at 295?±?3?K and 1013?±?30 hPa, whereas the CH2NN?+?NO3 reaction was too fast to be determined in the static smog chamber experiments. Formaldehyde was the sole product observed in all the reactions. The experimental results are supported by CCSD(T*)-F12a/aug-cc-pVTZ//M062X/aug-cc-pVTZ calculations showing the reactions to proceed exclusively via addition to the carbon atom. The atmospheric fate of diazomethane is discussed. 相似文献
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Gerhard Rein 《Mathematical Methods in the Applied Sciences》1992,15(5):365-374
We consider a collisionless plasma, which consists of electrons and positively charged ions and is confined to a bounded domain in ?3. The distribution functions of the particles are assumed to satisfy specular reflections on the boundary of the domain and the boundary is assumed to be perfectly conducting. We establish the existence of stationary plasmas in the non-relativistic, electrostatic case described by the Vlasov–Poisson system as well as in the relativistic, electrodynamic case described by the relativistic Vlasov–Maxwell system. 相似文献
4.
Using topological methods we give a proof that the free product of two strict subgroup separable groups with infinite cyclic amalgamation is subgroup separable. 相似文献
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6.
Gerhard Lessner 《General Relativity and Gravitation》2004,36(5):1241-1242
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Stefan Pitsch Sebastian Wendeborn Ramanarayanan Krishnamurthy Armin Holzner Mark Minton Martin Bolli Christian Miculca Norbert Windhab Ronald Micura Michael Stanek Bernhard Jaun Albert Eschenmoser 《Helvetica chimica acta》2003,86(12):4270-4363
Pyranosyl‐RNA (‘p‐RNA’ ) is an oligonucleotide system isomeric to natural RNA and composed of the very same building blocks as RNA. Its generational, chemical, and informational properties are deemed to be those of an alternative nucleic acid system that could have been a candidate in Nature's evolutionary choice of the molecular basis of genetic function. We consider the study of the chemistry of p‐RNA as etiologically relevant in the sense that knowledge of its structural, chemical, and informational properties on the chemical level offers both a perspective and reference points for the recognition of specific structural assets of the RNA structure that made it the (supposedly) superior system among possible alternatives and, therefore, the system that became part of biology as we know it today. The paper describes the chemical synthesis of β‐d‐ (and L )‐ribopyranosyl‐(4′→2′)‐oligonucleotide sequences, presents a resume of their structural and chemical properties, and cautiously discusses what we may and may not have learned from the pyranosyl isomer of RNA with respect to the conundrum of RNA's origin. 相似文献
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10.
Gerhard Starke 《Numerische Mathematik》1997,78(1):103-117
Summary. The convergence rate of Krylov subspace methods for the solution of nonsymmetric systems of linear equations, such as GMRES
or FOM, is studied. Bounds on the convergence rate are presented which are based on the smallest real part of the field of
values of the coefficient matrix and of its inverse. Estimates for these quantities are available during the iteration from
the underlying Arnoldi process. It is shown how these bounds can be used to study the convergence properties, in particular,
the dependence on the mesh-size and on the size of the skew-symmetric part, for preconditioners for finite element discretizations
of nonsymmetric elliptic boundary value problems. This is illustrated for the hierarchical basis and multilevel preconditioners
which constitute popular preconditioning strategies for such problems.
Received May 3, 1996 相似文献