A novel and facile synthesis of 7,8-diacylcoumarins

Oxidation of N-carbonylhydrazones of 7-hydroxy-8-acetylcoumarin with lead tetraacetate results in the synthesis of 7,8-diacylcoumarins in good yields. The reaction proceeds via the transformation of a hydroxy into an acyl group reported for the first time in heterocyclic chemistry.     

Mass spectral study of 2-aryl-4-arylhydrazono-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazoles

The mass spectra upon electron impact at 70 eV of the title compounds are examined. The fragmentation pattern of the tetrahydro-benzotriazoles with unsymmetrically substituted the aryl groups in 2-position and in hydrazone group cannot support the aspect for a mononuclear heterocyclic rearrangement.     

1,3-Dipolar cycloadditions of mesitonitrile oxide with (9-fluorenylidene)-aceto- and malono-nitriles. Synthesis of mono- and bis-1,2,4-oxadiazolylmethane derivatives

Mesitonitrile oxide reacts with C ≡ N bond of (aryl)(9-fluorenylidene)acetonitriles 1 forming in very good yields the corresponding 1,2,4-oxadiazoles 2. Analogously also proceeds the reaction of mesitonitrile oxide with 9-fluorenylidenemalonodinitrile (3) with the formation of bis-1,2,4-oxadiazole derivative 4.     

Heterocyclic Rearrangement of 4,5,6,7-Tetrahydro-6,6-dimethyl-benzo[c][1,2,5]oxadiazol-4-one (Z)-Arylhydrazones into Corresponding 2-Aryl-4,5,6,7-tetrahydro-2H-benzo[d][1,2,3]triazol-4-one Oximes

The thermal base-catalysed and photochemical transformation (Boulton-Katritzky rearrangement) of the title tetrahydrobenzo[c][1,2,5]oxadiazoles to tetrahydro-2H-benzo[d][1,2,3]triazoles is studied. Attempts to induce analogous rearrangement in tetrahydro-2H-benzo[d][1,2,3]triazol-4-one arylhydrazones or oximes failed. Some CNDO/2 calculation are also carried out.     

The Extraction of Polycyclic Aromatic Hydrocarbons from Atmospheric Particulate Matter Samples by Accelerated Solvent Extraction (ASE)

Abstract

The Accelerated solvent extraction (ASE) of PAHs (23 2- to 6-ring species) spiked onto glass fibre filters (GFFs) was studied as a function of variable extraction solvents, pressure, temperature and extraction times. Acceptable recoveries (85% ± 15%) were obtained for certain combinations of conditions and a tentative method (1500 psi, 150°C, 70:30 hexane:acetone mixture, 7 min heat-up time, 5 min static extraction time, 60% flush volume, 2 static cycles was selected for further testing. However, this method did not prove as effective as the traditional Soxhlet method of extraction when these parameters were used to extract native PAHs from ambient atmospheric particulate matter collected on a GFF by Integrated Atmospheric Deposition Network (IADN) sampling protocols. The extraction recovery study for spiked GFFs was repeated using slightly different extraction conditions: 2000 psi, 100°C, 70:30 hexane:acetone, 5 min heat-up time, 5 min static extraction time, 150% flush volume, 3 static cycles. When this method was applied to the extraction of native PAHs from ambient atmospheric particulate matter collected on GFFs, the results showed equivalent or better recoveries to that of the Soxhlet method. The total time of extraction was 25 min requiring only 30 mL of solvent. This ASE method is presently used to quantitatively determine PAHs in IADN particle-phase samples.     

N-to-Delta axial transition form factors from lattice QCD

We evaluate the N to Delta axial transition form factors in lattice QCD with no dynamical sea quarks, with two degenerate flavors of dynamical Wilson quarks, and using domain wall valence fermions with three flavors of staggered sea quarks. We predict the ratio C(5)(A)(q(2))/C(3)(V)(q(2)) relevant for parity violating asymmetry experiments and verify the off-diagonal Goldberger-Treiman relation.     

Solvent effects in NMR spectra induced by benzene in amidoximes—V

Proton chemical shifts as well as solvent shifts induced by benzene in several amidoximes are examined with respect to their configuration and are compared to the solvent shifts induced in benzalanilines. The geometry of the benzene-solute ‘collision-complex’ is also discussed.     

N-to-delta electromagnetic-transition form factors from lattice QCD

The magnetic dipole (M1), the electric quadrupole (E2), and the Coulomb quadrupole (C2) amplitudes for gammaN-->Delta are calculated in quenched lattice QCD. Using a new method, which combines an optimal choice of interpolating fields for the Delta and an overconstrained analysis, we obtain statistically accurate results for the dipole form factor and for the ratios R(EM)=E2/M1 and R(SM)=C2/M1, up to momentum transfer squared 1.5 GeV2. We show for the first time, using lattice QCD, that both R(EM) and R(SM) are nonzero and negative, in qualitative agreement with experiment and indicating the presence of deformation in the N/Delta system.     

Fourier transform measurement of two-photon excitation spectra: applications to microscopy and optimal control

We report a novel Fourier transform method for measuring two-photon excitation spectra. We demonstrate this method using simple dye molecules and discuss its applications in two-photon fluorescence microscopy and optimal control. This method facilitates an intuitive interpretation of recent control experiments in terms of tuning the nonlinear spectrum of the exciting laser source.