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1.
Acetates derived from the adducts of the Baylis-Hillman reaction can be reacted in a regioselective manner with amines in the presence of palladium(0) catalyst to afford alpha-dehydro-beta-amino esters (2 and 3) in good yields. The regioselectivity of the reaction can be controlled by temperature and reaction medium leading to the synthesis of regioisomers 2 or 3. The alpha-dehydro-beta-amino acid 3 is a turn inducer, and the dipeptides 6 derived from it show the presence of an eight-membered intramolecular hydrogen bond. Also, cobalt(II) chloride catalyzes the cleavage of epoxy peptides with alpha-dehydro-beta-amino acid derivative 3b to afford the corresponding dipeptide derivatives 8, which exhibit an intramolecular hydrogen bond and thus mimic a beta-turn. This intramolecular hydrogen bonding preorganizes the corresponding diallylated peptide 8c for cyclization via ring-closing metathesis to afford the cyclic peptide 9 as a constrained mimic of a beta-turn. 相似文献
2.
Yutaka Morita Manfred Hesse Hans Schmid Avijit Banerji Julie Banerji Asima Chatterjee Willi E. Oberhnsli 《Helvetica chimica acta》1977,60(4):1419-1434
Alstonia scholaris: The structure of the indole alkaloid nareline Besides the known akuammidine, picralinal, picrinine and pseudoakuammigine a new indole alkaloid called nareline (M=352) was isolated from Alstonia scholaris R. BR. , which belongs to the plant family of Apocynaceae. Its structure 2 was deduced by single crystal X-ray diffraction. 2 represents the absolute configuration. The spectroscopic data of 2 and its derivatives (Scheme 1) as well as their chemical behavior support this structure. In biogenetic sense nareline is related to the bases akuammiline ( 4 ) and picraline ( 5 ) (Scheme 2). In contrast to those the C-atom 5 is exocyclic and represents an aldehyde group which forms together with the oxygen atom of the N (4)-hydroxylamine group a cyclic half acetale. - By oxidation (CrO3/CH3COOH) of 2 the oxindol derivative 19 (oxonareline) is formed which contains a cyclic acetal as a partial structure element (Scheme 4). 相似文献
3.
Extraction of promethium(III), uranium(VI), plutonium(IV), americium(III), zirconium(IV), ruthenium(III), iron(III) and palladium(II) has been carried out with a mixture of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) and tributyl phosphate (TBP) in dodecane. The effects of nitric acid, TBP and CMPO concentrations on the extraction of these metal ions have been studied. The nature of the species of the above metal ions extracted into the organic phase has been suggested. 相似文献
4.
K.K. Banerji 《Tetrahedron》1973,29(10):1401-1403
The oxidation of mandelic acid and nine monosubstituted mandelic acids by acid permanganate, in the presence of fluoride ions, have been studied. The reaction is of first order with respect to each the oxidant, the substrate and hydrogen ions. The kinetic isotope effect, kH/kD = 3·76 at 25°. The oxidation exhibits a reaction constant ?+= ?2·23 ± 0·07 at 25°. The oxidation does not induce polymerisation of acrylonitrile and does not show any solvent isotope effect. The activation enthalpies entropies are linearly related (r = 0·979). A mechanism involving transfer of a hydride ion to the oxidant is proposed. 相似文献
5.
The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by the hydrogen ions. The hydrogen ion dependence has the form: kobs = a + b [H+]. The oxidation of α‐deuteriomandelic acid exhibited a substantial primary kinetic isotope effect (kH/kd = 5.29 at 303 K). Oxidation of p‐methylmandelic acid was studied in 19 different organic solvents. The solvent effect has been analyzed by using Kamlet's and Swain's multiparametric equations. A mechanism involving a hydride ion transfer via a chromate ester is proposed. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 248–254, 2002 相似文献
6.
Quinazoline is a heterocyclic compound having biological activities. It is aromatic in nature having bicyclic structure containing benzene ring and pyrimidine ring. Quinazoline and its derivatives are found to have wide range of biological activities that is anticancer, analgesic, antimicrobial, antihypertensive, anticonvulsant, antimalarial, antitumor, and anti-tubercular activities. The purpose of this review is to highlight the recent researches made by researchers on various biological activities of quinazoline derivatives on different targets. 相似文献
7.
Investigations are carried out for stability in photovoltaic response of bifunctional electroluminescent and photovoltaic devices, based on ternary blend of poly(3-hexylthiophene) (P3HT), phenyl [6,6′]C61 butyric acid methyl ester (PCBM), and 5,6,11,12-tetraphenylnaphthacene (rubrene). P3HT and PCBM are important and the most frequent materials used for photovoltaic applications, therefore, for relative comparison, photovoltaic cells were also prepared using a binary mixture of P3HT and PCBM. Devices based on the ternary blend exhibited better stability in all photovoltaic parameters and the lifetime was almost doubled, but their photovoltaic efficiency was lower than that of those based on the binary blend. Longer lifetime of ternary blend devices is because of a relatively better thermal, electrochemical, and morphological stabilities of the ternary blend system. However, the lower efficiencies are because of the reduced photo-current and low fill factor (FF) due to an increased recombination and introduction of defects/trapping sites by rubrene molecules. 相似文献
8.
Kar Aishwarya S. Rao Ankita Sahu Manjulata Kumar Shiny S. Tomar B. S. 《Journal of Radioanalytical and Nuclear Chemistry》2017,314(3):1667-1674
Journal of Radioanalytical and Nuclear Chemistry - Plutonium recovery is inevitable from plutonium bearing alumina crucibles generated over the years as part of carbon analysis during chemical... 相似文献
9.
Prashant Mishra Kaman Singh Utkarsh Dixit Ankita Agarwal Rayees Ahmad Bhat 《印度化学会志》2022,99(7):100528
The threat of phenol contamination in aquatic ecosystems is significant for the health of the earth's water systems as well as all humans on it. The present study was conducted to synthesize a cost-effective adsorbent (pea shells activated with sulfuric acid, PSASA) from agriculture waste (pea shells) and its use for effective removal of toxic 4-Aminophenol (4-AP). Newly designed PSASA exhibited significant adsorption of 4-AP which was confirmed by SEM, FT-IR, and XRD analysis. Surface topography confirmed high unevenness of the PSASA surface and the macroporous feature of the PSASA was confirmed by BET analysis. . Multiple testing was done to see how various factors affected adsorption such as adsorbent dose, temperature, pH, PZC, the effect of KCl and urea addition and the effect of the initial concentration of 4-AP. A drop in adsorption uptake of 4-AP was observed as the temperature increases from 25 °C to 45 °C. Maximum adsorption uptake (qm) was found to be 106.11 mg/g at an optimum pH of 7.0 and 25 °C. Among various adsorption isotherm models tested, Langmuir Isotherm gave the best explanation with high R2 values of experimental data. The pseudo-first-order model was found to explain the kinetics of adsorption well. The thermodynamic finding confirms the adsorption process was physical and exothermic. The adsorption of 4-AP was primarily governed by electrostatic interaction, hydrogen-bonding and π-π exchange mechanism. Because of the positive outcomes of the present research, we can use the PSASA as a cost-effective adsorbent for removing phenolic compounds. 相似文献
10.
Ring-opening (ROP) and enzymatic copolymerization (ECP) are among the most widely used approaches for synthesizing copolymers of polycaprolactone (PCL). It involves multiple-step reactions and the utilization of enzymes that make the process a lot more complicated, time consuming, and expensive. Atom transfer radical polymerization (ATRP) has been adopted to synthesize a novel amphiphilic copolymer in our study. The study presents a method to eliminate the ROP/ECP multiple steps in monomer polymerization thus making the process simpler and smoother. The synthesis of cationic polymer micelles copolymer of PCL-PGMA (polycaprolactone grafted poly glycidyl methacrylate) was carried out using direct functionalization of hydroxy group in crude PCL to achieve a higher degree of functionalization, i.e., 12.8% for macroinitiator. FTIR and 1H-NMR confirmed the successful synthesis of the copolymer with better control over the molecular weight with a PDI (1.84). DSC and XRD results showed the reduction of crystallinity by 86.81%, making copolymer more compatible for drug delivery application. The synthesized copolymer was further converted to nano-micelles drug carrier having an average size of 96.08 ± 21.22 nm. The drug encapsulation efficiency achieved was 60.0 ± 1.7%, and nano-micelles rendered a slow and controlled release of naproxen with long-term storage stability. 相似文献