全文获取类型
收费全文 | 441篇 |
免费 | 13篇 |
国内免费 | 10篇 |
专业分类
化学 | 325篇 |
晶体学 | 1篇 |
力学 | 8篇 |
数学 | 83篇 |
物理学 | 47篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 12篇 |
2020年 | 8篇 |
2019年 | 7篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 15篇 |
2015年 | 5篇 |
2014年 | 20篇 |
2013年 | 15篇 |
2012年 | 25篇 |
2011年 | 30篇 |
2010年 | 23篇 |
2009年 | 25篇 |
2008年 | 33篇 |
2007年 | 38篇 |
2006年 | 21篇 |
2005年 | 20篇 |
2004年 | 24篇 |
2003年 | 15篇 |
2002年 | 14篇 |
2001年 | 8篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 9篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 3篇 |
排序方式: 共有464条查询结果,搜索用时 15 毫秒
1.
Inequalities satisfied by the zeros of the solutions of second-order hypergeometric equations are derived through a systematic use of Liouville transformations together with the application of classical Sturm theorems. This systematic study allows us to improve previously known inequalities and to extend their range of validity as well as to discover inequalities which appear to be new. Among other properties obtained, Szegő's bounds on the zeros of Jacobi polynomials for , are completed with results for the rest of parameter values, Grosjean's inequality (J. Approx. Theory 50 (1987) 84) on the zeros of Legendre polynomials is shown to be valid for Jacobi polynomials with |β|1, bounds on ratios of consecutive zeros of Gauss and confluent hypergeometric functions are derived as well as an inequality involving the geometric mean of zeros of Bessel functions. 相似文献
2.
J.T. Elizalde Galindo A.H. Adair C.E. Botez V. Corral Flores D. Bueno Baques L. Fuentes Cobas J.A. Matutes-Aquino 《Applied Physics A: Materials Science & Processing》2007,87(4):743-747
Measurements of ac-susceptibility and dc-magnetization were carried out on samples of Ni1-xZnxFe2O4 nanoparticles (x=0, 0.25, 0.5, 0.75) with average diameters 〈D〉≈7 nm. Values of the superparamagnetic blocking temperature
T̄B were obtained from the characteristic temperature behavior of the imaginary susceptibility χimag. An Arrhenius-type law, which accurately describes the relationship between the observation time τobs and the blocking temperature, was used to determine the effective energy barrier to magnetization reversal Ueff. A Zn-content dependence of the energy barrier is observed, where Ueff changes little for 0≤x≤0.25, it peaks at x=0.5, and decreases back upon further Zn-doping. The large increase of Ueff at x=0.5 is attributed to an enhanced magnetic anisotropy induced by the crossover between two spatial arrangements of spins
in the A and B sub-lattices of the ferrimagnetic inverse spinel.
PACS 75.50.Bb; 75.50.Gg; 75.30.Et 相似文献
3.
4.
We focus on continuous Markov chains as a model to describe the evolution of credit ratings. In this work it is checked whether a simple, tridiagonal type of generator provides a good approximation to a general one. Three different tridiagonal approximations are proposed and their performance is checked against two generators, corresponding to a volatile and a stable period, respectively. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
5.
Elías Molins Amílcar Labarta Javier Tejada Amparo Caubet Santiago Alvarez 《Transition Metal Chemistry》1983,8(6):377-380
Summary Magnetic moments and57Fe Mössbauer spectra at room temperature and at liquid nitrogen temperature of polynuclear ligand-bridged iron phthalocyanines, FePcL (L = pyrazine and 4,4-bipyridyl), are reported. The experimental data are in agreement with a pseudo-octahedral environment around the iron(II) cation. Partially oxidized derivatives, FePc(pz)I0.26 and FePc(bipy)I1.06 have been synthesized and their57Fe Mössbauer spectra and magnetic moments within the same temperature range obtained. Oxidation is shown to be metal centred and the iodine is found to be in I– form for FePc(pz)0.26 and as both I– and I
3
–
species for FePc(bipy)I1.06. While the magnetic moment of FePc(pz) increases upon oxidation, the opposite occurs for FePc(bipy). 相似文献
6.
We describe the preparation of 1,4′-bipyrazolyls and 4-pyrazolylpyrimidines by the reaction of 2-pyrazolyl-3-dimethylamino acrylate and acrylonitrile with double nucleophilic reagents such as hydrazines, urea and guanidine. Reactions were performed under microwave irradiation in 5-60 min. This is a useful procedure for the preparation of valuable compounds with applications in medicinal and coordination chemistry. 相似文献
7.
R. M. Aron P. Galindo D. Garcí a M. Maestre 《Transactions of the American Mathematical Society》1996,348(2):543-559
A Banach space is known to be Arens regular if every continuous linear mapping from to is weakly compact. Let be an open subset of , and let denote the algebra of analytic functions on which are bounded on bounded subsets of lying at a positive distance from the boundary of We endow with the usual Fréchet topology. denotes the set of continuous homomorphisms . We study the relation between the Arens regularity of the space and the structure of .
8.
Fustero S Navarro A Díaz D de La Torre MG Asensio A Sanz F González ML 《The Journal of organic chemistry》1996,61(25):8849-8859
Reaction of azaenolates of 2-alkyl-oxa(thia)zolines 6 with imidoyl chlorides 7 as electrophiles to furnish masked N-substituted beta-enamino acid derivatives 1-2 in 70-90% yield is described. Alternative routes are discussed. Compounds 1-2 generally appear in one tautomeric form, imino or enamino, depending on the nature of the imidoyl chloride. The configuration of the enamino moiety (Z) and the conformation (s-cis) of compounds 1-2 obtained were established by an NMR study and unequivocally set by nuclear Overhauser effect difference experiments. An X-ray structure of compound 1e is also reported, showing a strong intramolecular NH.N hydrogen bond. Ab initio calculations (HF/3-21G and HF/3-21+G) have been carried out on several representative examples (1e, 1p, and 1l) in an attempt to support and provide the correct geometry of these derivatives. Structural considerations among the possible isomers of compounds 1 are discussed. From these studies it was concluded that the theoretical calculations agree with the experimental results. In addition, a very simple one-pot procedure for the preparation of masked N-substituted alpha-alkylated beta-enamino acid derivatives 2 from 6, 7, and different alkyl halides (R(3)Y) is described. 相似文献
9.
Amparo Fuertes Emilio Escrivá Carmen Munoz Jaime Alamo Aurelio Beltrán-Porter Daniel Beltrán-Porter 《Transition Metal Chemistry》1987,12(1):62-68
Summary Knowledge of the kinetic and thermodynamic behaviour of aqueous solutions containing two divalent cations andtrans-1,2-cyclohexanediaminetetraacetate has been used to design synthetic pathways to ordered bimetallic complexesPart 1: E. Escriva, A. Fuertes and D. Beltran,Transition Met. Chem.,9, 184 (1984). 相似文献
10.
[reaction: see text] A lipase-catalyzed double monoaminolysis of dimethyl malonate by (+/-)-trans-cyclopentane-1,2-diamine allows the sequential resolution of the latter compound, affording an enantiopure bis(amidoester), which is subsequently transformed into an optically active polyamine. As an alternative, both enantiomers of the diamine can be obtained from enantiopure (+)- or (-)-2-aminocyclopentanol, prepared by enzymatic resolution. 相似文献