A weight-function approach for determining watershed initial conditions for combustion waves

In many generic combustion models, one finds that a combustionwave will develop with a specific wave speed. However, thereare possible initial temperature profiles which do not evolveinto such waves, but rather die out to the ambient temperature.There can exist, in some models, a clear distinction betweenthose initial conditions that do evolve into combustion wavesand those that do not; this is sometimes referred to as thewatershed initial condition. When fuel consumption is consideredto be negligible, analytical methods can be used to obtain theexact watershed. In this paper, we consider the problem of determiningpseudo-watersheds and ascertaining the relationship betweenthese pseudo-watersheds and the exact watersheds. In the processa novel weight-function approach for infinite spatial domainsis developed.     

Study of the internal structure and small-scale instabilities in the dense Z pinch

High-resolution laser diagnostics at the wavelength of 266 nm were applied for the investigation of Z pinches at the 1-MA generator. The internal structure of the stagnated Z pinches was observed in unprecedented detail. A dense pinch with strong instabilities was seen inside the column of the trailing plasma. Kink instability, disruptions, and micropinches were seen at the peak of the x-ray pulse and later in time. The three-dimensional structure of the stagnated Z pinch depends on the initial wire-array configuration and implosion scenario. Small-scale density perturbations were found in the precursor plasma and in the stagnated Z pinch. Development of instabilities is in agreement with three-dimensional magnetohydrodynamic simulations.     

Synthesis of cytotoxic cyanobactin,Wewakazole B

We report herein the synthesis of cytotoxic cyanobactin, Wewakazole B through an efficient solution-phase approach. The key steps of the synthesis are the macrocyclic lactamization of linear dodecapeptide and construction of two hexapeptides with three different substituted oxazole rings.     

X-ray absorption spectroscopy for wire-array Z-pinches at the non-radiative stage

Absorption spectroscopy was applied to wire-array Z-pinches on the 1 MA pulsed-power Zebra generator at the Nevada Terawatt Facility (NTF). The 50 TW Leopard laser was coupled with the Zebra generator for X-ray backlighting of wire arrays at the ablation stage. Broadband X-ray emission from a laser-produced Sm plasma was used to backlight Al star wire arrays in the range of 7–9 Å. Two time-integrated X-ray conical spectrometers recorded reference and absorption spectra. The spectrometers were shielded from the bright Z-pinch X-ray burst by collimators. The comparison of plasma-transmitted spectra with reference spectra indicates absorption lines in the range of 8.1–8.4 Å. Analysis of Al K-shell absorption spectra with detailed atomic kinetics models shows a distribution of electron temperature in the range of 10–30 eV that was fitted with an effective two-temperature model. Temperature and density distributions in wire-array plasma were simulated with a three-dimension magneto-hydrodynamic code. Post-processing of this code’s output yields synthetic transmission spectrum which is in general agreement with the data.     

Measurement of the ionization state and electron temperature of plasma during the ablation stage of a wire-array Z pinch using absorption spectroscopy

Wire-array plasmas were investigated in the nonradiative ablation stage via x-ray absorption spectroscopy. A laser-produced Sm plasma was used to backlight Al wire arrays. The Sm spectrum was simultaneously observed by two spectrometers: one recorded the unattenuated spectrum and the other the transmission spectrum with 1.45-1.55 keV K-shell absorption lines. Analysis of absorption spectra revealed electron temperature in the range of 10-30 eV and the presence of F-, O-, N- and C-like Al ions in the absorbing plasma. A comparison of this electron temperature with the postprocessed absorption spectra of a 2D MHD simulation yields results in general agreement with the data analysis.     

Mitigation of the plasma-implosion inhomogeneity in starlike wire-array Z pinches

Implosions in starlike triple and quadruple wire arrays were investigated in a 1 MA Zebra generator. Implosion in these loads is directed along the rays of the star and cascades from wire to wire to the center. Shadowgraphy shows improved homogeneity of imploding plasma and mitigation of instabilities. Despite the low azimuthal symmetry, starlike wire arrays produce a stable x-ray pulse with the highest peak power of >0.4 TW and the shortest duration of 8-12 ns among different types of tested loads. This can be linked to stabilization of instabilities due to the multiple nesting.