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Dr. Chenge Li Dr. Alison G. Tebo Marion Thauvin Marie-Aude Plamont Prof. Dr. Michel Volovitch Dr. Xavier Morin Prof. Dr. Sophie Vriz Prof. Dr. Arnaud Gautier 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18073-18079
Far-red emitting fluorescent labels are highly desirable for spectral multiplexing and deep tissue imaging. Here, we describe the generation of frFAST (far-red Fluorescence Activating and absorption Shifting Tag), a 14-kDa monomeric protein that forms a bright far-red fluorescent assembly with (4-hydroxy-3-methoxy-phenyl)allylidene rhodanine (HPAR-3OM). As HPAR-3OM is essentially non-fluorescent in solution and in cells, frFAST can be imaged with high contrast in presence of free HPAR-3OM, which allowed the rapid and efficient imaging of frFAST fusions in live cells, zebrafish embryo/larvae, and chicken embryos. Beyond enabling the genetic encoding of far-red fluorescence, frFAST allowed the design of a far-red chemogenetic reporter of protein–protein interactions, demonstrating its great potential for the design of innovative far-red emitting biosensors. 相似文献
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Alison L. Parry 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3178-3190
The ring‐opening metathesis polymerizations (ROMP), using RuCl2 (PCy3)2CHPh, of a series of peptide‐functionalized norbornene derivatives have been investigated. Incorporation of a PEG‐monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3178–3190, 2007 相似文献
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Recent developments in the aerobic oxidation of alcohols 总被引:1,自引:0,他引:1
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Efforts are made to explore the hysteresis characteristics of vortex shedding in a pipe flow, whose velocity varies periodically in time. Results obtained show that during acceleration of the flow, the vortex strength tends to be stronger, whereas during deceleration of the flow, the situation is reversed. As reconstructed from the velocity signals measured at a point in the flow field, the shed vortex arrays appear to possess uneven vortex strengths in response to periodically-varying incoming flows. Furthermore, in the hysteresis range, the streamwise spacings between the vortices appear to be unequal. 相似文献
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Rachel L. McSwain Alison R. Markowitz Kenneth R. Shull 《Journal of Polymer Science.Polymer Physics》2004,42(20):3809-3821
To develop a greater understanding of interfacial interactions between a semicrystalline polymer and a glassy polymer, adhesion tests were performed on very thin layers of poly(ethylene oxide) (PEO) sandwiched between two layers of poly(tetramethyl bisphenol A polycarbonate) (TMPC). The tests were designed to provide intimate contact between the surfaces while they were heated above the melting point of the PEO and cooled back to room temperature. A contact mechanics approach, based on the Johnson, Kendall, and Roberts theory, was used to determine values of the energy release rate describing the energetic driving force for crack propagation within the interfacial region. The ability to measure crack propagation at large values of the energy release rate was limited by rupture of the silicone elastomer that was used to provide a sufficiently compliant matrix for the adhesion experiment. By cycling the tensile stress at relatively low loading levels, we were able to measure fatigue crack propagation at values of the energy release rate that did not result in failure of the elastomer. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3809–3821, 2004 相似文献
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Past cellular automata models of self-replication have always been initialized with an original copy of the structure that will replicate, and have been based on a transition function that only works for a single, specific structure. This article demonstrates for the first time that it is possible to create cellular automata models in which a self-replicating structure emerges from an initial state having a random density and distribution of individual components. These emergent self-replicating structures employ a fairly general rule set that can support the replication of structures of different sizes and their growth from smaller to larger ones. This rule set also allows “random” interactions of self-replicating structures with each other and with other structures within the cellular automata space. Systematic simulations show that emergence and growth of replicants occurs often and is essentially independent of the cellular space size, initial random pattern of components, and initial density of components, over a broad range of these parameters. The number of replicants and the total number of components they incorporate generally approach quasi-stable values with time. 相似文献
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