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1.
1-(2-Thenoyl)-4-trifluoro-2-[2-hydroxy-3-sulfo-5-nitrophenylazo]butadione-1,3 (H2L) was synthesized from 2-thenoyltrifluoroacetone. The formation of a copper(II) complex of the synthesized reagent was studied in the presence and absence of 8-hydroxyquinoline (HR). Monoligand [Cu(HL)2] and mixed-ligand [Cu(HL)2HR] compounds were obtained at pH 4 and 3, respectively. The ratio of components in the monoligand and mixed-ligand compounds were 1 : 2 and 1 : 2 : 1, respectively. Beers law was obeyed in the ranges of copper concentrations from 0.20 to 2.56 and from 0.25 to 2.56 µg/mL, respectively. The dissociation constants of the reagent were .K1 = 4.25µ0.01 and .K2 = 8.20µ0.01 . The stability constants of [Cu(HL)2] and [Cu(HL)2HR] complexes were K1 = 4.96µ0.03 and 4.92µ0.01, respectively. A procedure was developed for the photometric determination of copper(II) in rocks.Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 2, 2005, pp. 157–161.Original Russian Text Copyright © 2005 by Alieva, Chyragov, Makhmudov.This revised version was published online in April 2005 with corrections to the author names and book review format. 相似文献
2.
R. A. Alieva S. Z. Gamidov F. M. Chyragov A. A Azizov 《Journal of Analytical Chemistry》2005,60(12):1114-1117
A method is developed for cadmium and zinc preconcentration on a minicolumn packed with a new chelating polymer sorbent. The effects of the test solution pH and volume, the sample matrix composition, the eluent volume, and the sample and eluent flow rates are studied. Zinc and cadmium in the eluate are determined by flame atomic absorption spectrometry. Under optimal conditions, the determined ion recovery is more than 95%. The detection limits (3σ, n = 20) are found to be 15.0 (Cd) and 17.2 (Zn) ng/mL. The developed method is employed for cadmium and zinc determination in samples of seawater and water obtained after oil pumping. 相似文献
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Sh. A. Alieva Zh. M. Putieva E. S. Kondratenko N. K. Abubakirov 《Chemistry of Natural Compounds》1978,13(5):546-549
Summary Six new diterpene glycosides — doronicosides A, B, C, D, E, and F — have been detected in the roots ofDoronicum macrophyllum Fisch. The qualitative and quantitative composition of the sugar chain of doronicoside D has been established. It has been shown that the negative aglycone of all the doronicosides is 15-hydroxy-(–)-kaur-16-en-19-oic acid, which, in the process of hydrolysis, is converted into 15-oxo-(–)-kauran-19-oic acid.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. N. Narimanov Azerbaidzhan State Medical Institute, Baku. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 658–662, September–October, 1977. 相似文献
5.
A. T. Shakhtakhtinskaya Z. M. Mamedova Sh. F. Mutallibova S. Z. Alieva R. G. Mardzhanova 《Reaction Kinetics and Catalysis Letters》1989,39(1):137-140
Acidity of catalyst surfaces of different nature such as -Al2O3, natural zeolite-clinoptilolite, and synthetic zeolite zeokar by adsorption of ammonia over a wide temperature range has been studied. Ammonia is adsorbed on the catalysts with different strengths, as evidenced by the presence of different types of acid sites.
(-Al2O3, - , () . , , .相似文献
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M. -H. Yu. Seyidov A. P. Odrinskii R. A. Suleymanov E. Acar T. G. Mammadov V. B. Alieva 《Physics of the Solid State》2014,56(10):2028-2034
The results of investigations of the pyroelectric current in a layered TlInS2 crystal doped with lanthanum are presented. A comparative analysis of the obtained results and data of photo-induced current transient spectroscopy has been performed. The revealed features of the contribution from electrically active defects to pyroelectric properties of the crystal have been discussed. 相似文献
8.
A. Kh. Kerimov A. T. Orudzheva Kh. A. Mamedova U. A. Alieva 《Russian Journal of Applied Chemistry》2013,86(9):1364-1369
Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of the intermediate oligohalohydrins with NaOH, was performed. The synthesized products are effi cient as active diluents for a compound based on ED-20 resin. 相似文献
9.
(p-Vinylphenyl)cyclopropylmethyl cinnamate was synthesized, and its radical polymerization was performed. The synthesized polyfunctional polymers containing UV-sensitive >C=O, >C=C<, and ? groups exhibit high photosensitivity. Photochemical cross-linking of the polymers was studied. The polymers synthesized can be used for preparing photosensitive materials. 相似文献
10.
The relationship between the mode content and the fractional Fourier and fractional Hankel transforms of a function is established. It is shown that the Laguerre-Gauss spectrum of a rotationally symmetric wave front can be determined from the wave front's fractional Hankel transforms taken at the optical axis. 相似文献