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1.
Alban Orsini 《Tetrahedron letters》2005,46(13):2259-2262
Trimethylsilyl acetylenes can be selectively deprotected in the presence of a catalytic amount of silver salts. AgNO3 and AgOTf proved to be the most effective catalyst in a mixture of methanol, water and dichloromethane. Other functional groups, and especially silyl ethers, are not affected in these conditions. 相似文献
2.
Contribution to the study of the behaviour of catechin in alkaline medium When catechin ( 1 ) is warmed with aqueous alkali it first undergoes rapid epimerisation. After some time a novel bridged carbocyclic enol, catechinic acid ( 3 ) separates out and may be isolated in excellent yield. Eventually catechinic acid isomerises to 2-(3′,4′-dihydroxyphenyl)-3,9-epoxy-6-oxo-bicyclo[3,3,1]-non-7-en-8,9-diol ( 4 ) via an open chain anion ( 5 ) which is also involved in the epimerisation of catechin. Assignments of structure are given and the equilibria observed are discussed. 相似文献
3.
M. Mukherjee D. Beck K. Blaum G. Bollen J. Dilling S. George F. Herfurth A. Herlert A. Kellerbauer H. -J. Kluge S. Schwarz L. Schweikhard C. Yazidjian 《The European Physical Journal A - Hadrons and Nuclei》2008,35(1):1-29
ISOLTRAP is a Penning trap mass spectrometer for high-precision mass measurements on short-lived nuclides installed at the
on-line isotope separator ISOLDE at CERN. The masses of close to 300 radionuclides have been determined up to now. The applicability
of Penning trap mass spectrometry to mass measurements of exotic nuclei has been extended considerably at ISOLTRAP by improving
and developing this double Penning trap mass spectrometer over the past two decades. The accurate determination of nuclear
binding energies far from stability includes nuclei that are produced at rates less than 100 ions/s and with half-lives well
below 100ms. The mass-resolving power reaches 107 corresponding to 10keV for medium heavy nuclei and the uncertainty of the resulting mass values has been pushed down to below
10-8. The article describes technical developments achieved since 1996 and the present performance of ISOLTRAP. 相似文献
4.
K. Blaum G. Bollen F. Herfurth A. Kellerbauer H.-J. Kluge M. Kuckein E. Sauvan C. Scheidenberger L. Schweikhard 《The European Physical Journal A - Hadrons and Nuclei》2002,15(1-2):245-248
The cyclotron frequencies of singly charged carbon clusters Cn
+ (n ≥ 2) were measured with the Penning-trap mass spectrometer ISOLTRAP at ISOLDE/CERN. The present limit of mass accuracy δm/m = 1.2 . 10-8 and the extent of the mass-dependent systematic shift (δm/m)sys = 1.7(0.6) . 10-10/u
. (m - m
ref) of the setup were investigated for the first time. In addition, absolute mass measurements by use of pure clusters of the
most abundant carbon isotope 12C are now possible at ISOLTRAP.
Received: 21 March 2002 / Accepted: 16 May 2002 / Published online: 31 October 2002
RID="a"
ID="a"Present address: CERN, CH-1211 Geneva 23, Switzerland; e-mail: klaus.blaum@cern.ch 相似文献
5.
Jørgensen LV Amoretti M Bonomi G Bowe PD Canali C Carraro C Cesar CL Charlton M Doser M Fontana A Fujiwara MC Funakoshi R Genova P Hangst JS Hayano RS Kellerbauer A Lagomarsino V Landua R Lodi Rizzini E Macrì M Madsen N Mitchard D Montagna P Rotondi A Testera G Variola A Venturelli L van der Werf DP Yamazaki Y;ATHENA Collaboration 《Physical review letters》2005,95(2):025002
We have developed a new method, based on the ballistic transfer of preaccumulated plasmas, to obtain large and dense positron plasmas in a cryogenic environment. The method involves transferring plasmas emanating from a region with a low magnetic field (0.14 T) and relatively high pressure (10(-9) mbar) into a 15 K Penning-Malmberg trap immersed in a 3 T magnetic field with a base pressure better than 10(-13) mbar. The achieved positron accumulation rate in the high field cryogenic trap is more than one and a half orders of magnitude higher than the previous most efficient UHV compatible scheme. Subsequent stacking resulted in a plasma containing more than 1.2 x 10(9) positrons, which is a factor 4 higher than previously reported. Using a rotating wall electric field, plasmas containing about 20 x 10(6) positrons were compressed to a density of 2.6 x 10(10) cm(-3). This is a factor of 6 improvement over earlier measurements. 相似文献
6.
Van Roosbroeck J Guénaut C Audi G Beck D Blaum K Bollen G Cederkall J Delahaye P De Maesschalck A De Witte H Fedorov D Fedoseyev VN Franchoo S Fynbo HO Górska M Herfurth F Heyde K Huyse M Kellerbauer A Kluge HJ Köster U Kruglov K Lunney D Mishin VI Mueller WF Nagy S Schwarz S Schweikhard L Smirnova NA Van de Vel K Van Duppen P Van Dyck A Walters WB Weissman L Yazidjian C 《Physical review letters》2004,92(11):112501
Using resonant laser ionization, beta-decay studies, and for the first time mass measurements, three beta-decaying states have been unambiguously identified in 70Cu. A mass excess of -62 976.1(1.6) keV and a half-life of 44.5(2) s for the (6-) ground state have been determined. The level energies of the (3-) isomer at 101.1(3) keV with T(1/2)=33(2) s and the 1+ isomer at 242.4(3) keV with T(1/2)=6.6(2) s are confirmed by high-precision mass measurements. The low-lying levels of 70Cu populated in the decay of 70Ni and in transfer reactions compare well with large-scale shell-model calculations, and the wave functions appear to be dominated by one proton-one neutron configurations outside the closed Z=28 shell and N=40 subshell. This does not apply to the 1+ state at 1980 keV which exhibits a particular feeding and deexcitation pattern not reproduced by the shell-model calculations. 相似文献
7.
J. Dilling F. Herfurth A. Kellerbauer G. Audi D. Beck G. Bollen H. -J. Kluge R. B. Moore C. Scheidenberger S. Schwarz G. Sikler 《The European Physical Journal A - Hadrons and Nuclei》2004,22(2):163-171
The masses of the noble-gas Xe isotopes with
have been directly measured for the first time. The experiments were carried out with the ISOLTRAP triple trap spectrometer at the on-line mass separator ISOLDE/CERN. A mass resolving power of the Penning trap spectrometer of
of close to a million was chosen resulting in an accuracy of
keV for all investigated isotopes. Conflicts with existing, indirectly obtained, mass data by several standard deviations were found and are discussed. An atomic mass evaluation has been performed and the results are compared to information from laser spectroscopy experiments and to recent calculations employing an interacting boson model.PACS:
07.75. + h Mass spectrometers - 21.10.Dr Binding energies and masses - 27.60. + j
- 32.10.Bi Atomic masses, mass spectra, abundances, and isotopes 相似文献
8.
Mukherjee M Kellerbauer A Beck D Blaum K Bollen G Carrel F Delahaye P Dilling J George S Guénaut C Herfurth F Herlert A Kluge HJ Köster U Lunney D Schwarz S Schweikhard L Yazidjian C 《Physical review letters》2004,93(15):150801
Mass measurements with a relative precision of better than 1.5 x 10(-8) were performed on 22Mg and its reaction partners 21Na and 22Na with the ISOLTRAP Penning trap mass spectrometer at CERN, yielding the mass excesses D(22Mg)=-399.92(27) keV, D(21Na)=-2184.71(21) keV, and D(22Na)=-5181.56(16) keV. The importance of these results is twofold. First, a comparative half-life (Ft value) has been obtained for the superallowed beta decay of 22Mg to further test the conserved-vector-current hypothesis. Second, the resonance energy for the 21Na proton capture reaction has been independently determined, allowing direct comparisons of observable gamma radiation in nova explosions with the yield expected from models. 相似文献
9.
The directionality patterns of sound emission in domestic dogs were measured in an anechoic environment using a microphone array. Mainly long-distance signals from four dogs were investigated. The radiation pattern of the signals differed clearly from an omnidirectional one with average differences in sound-pressure level between the frontal and rear position of 3-7 dB depending from the individual. Frequency dependence of directionality was shown for the range from 250 to 3200 Hz. The results indicate that when studying acoustic communication in mammals, more attention should be paid to the directionality pattern of sound emission. 相似文献
10.
G. Bollen F. Ames G. Audi D. Beck J. Dilling O. Engels S. Henry F. Herfurth A. Kellerbauer H.-J. Kluge A. Kohl E. Lamour D. Lunney R. B. Moore M. Oinonen C. Scheidenberger S. Schwarz G. Sikler J. Szerypo C. Weber 《Hyperfine Interactions》2001,132(1-4):213-220
Penning trap mass spectrometry has reached a state that allows its application to very short-lived nuclides available from
various sources of radioactive beams. Mass values with outstanding accuracy are achieved even far from stability. This paper
illustrates the state of the art by summarizing the status of the ISOLTRAP experiment at ISOLDE/CERN. Furthermore, results
of mass measurements on unstable rare earth isotopes will be given.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献