全文获取类型
收费全文 | 1211篇 |
免费 | 50篇 |
国内免费 | 4篇 |
专业分类
化学 | 1003篇 |
晶体学 | 11篇 |
力学 | 16篇 |
数学 | 61篇 |
物理学 | 174篇 |
出版年
2023年 | 10篇 |
2022年 | 10篇 |
2021年 | 16篇 |
2020年 | 22篇 |
2019年 | 29篇 |
2018年 | 21篇 |
2017年 | 14篇 |
2016年 | 32篇 |
2015年 | 33篇 |
2014年 | 37篇 |
2013年 | 42篇 |
2012年 | 91篇 |
2011年 | 105篇 |
2010年 | 61篇 |
2009年 | 49篇 |
2008年 | 57篇 |
2007年 | 87篇 |
2006年 | 81篇 |
2005年 | 70篇 |
2004年 | 53篇 |
2003年 | 71篇 |
2002年 | 59篇 |
2001年 | 19篇 |
2000年 | 20篇 |
1999年 | 19篇 |
1998年 | 8篇 |
1997年 | 13篇 |
1996年 | 10篇 |
1995年 | 14篇 |
1994年 | 13篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有1265条查询结果,搜索用时 0 毫秒
1.
2.
3.
Kazuhiko Nakano Toshihiro Nakamura Izumi Nakai Akira Kawase Makoto Imai Mikio Hasegawa Yohichi Ishibashi Isamu Inamoto Kazuhuyu Sudou Masaru Kozaki Akira Tsuruta Akihiro Ono Kazutoshi Kakita Mamoru Sakata 《Analytical sciences》2006,22(9):1265-1268
The Japan Society for Analytical Chemistry has developed some new plastic certified reference materials (CRMs) for the analysis of mercury in polyester disks using XRF analysis. These CRMs (named as JSAC 0621-0625) were prepared by casting polyesters including a toluene solution of organometallic compounds as a standard. Concentrations of the five levels of mercury ranged from 0 to 250 mg/kg. Homogeneity tests of prepared disks had shown excellent results. Interlaboratory comparison study for the certification was performed by 15 laboratory participants. The z-scores in robust statistical method was applied for the evaluation of outliers. The certified values were assigned after discarding outliers. The uncertainties of certified values were determined as the confidence levels of 95%. 相似文献
4.
5.
The reaction of N-aryl-substituted ketenimines with N,N-disubstituted cyanamides or (MeS)2C=N-CN under high pressure afforded 4-(N,N-disubstituted amino) or 4-(MeS)2C=N-substituted quinazoline derivatives, respectively. These products were formed by [4+2] cycloaddition between the aza-diene moieties of the N-arylsubstituted ketenimines and cyano groups. A 4-(unsubstituted amino)quinazoline derivative was synthesized by hydrolysis of the latter product. 相似文献
6.
A variety of diaryl acetylenes were obtained in good yields when lithium hexamethyldisilazide was added to a solution of arylmethyl sulfone, aryl aldehyde, and chlorodiethylphosphate in THF. In this one‐shot process, a number of transformations such as aldol reaction, phosphorylation of aldolate, and double elimination of the resulting β‐substituted sulfone proceeded successively to afford the desired acetylenes. The one‐shot process was accelerated by the substitution of halogen atoms on the phenyl groups, and unsymmetrically substituted diaryl acetylenes were obtained without contamination of the dehalogenated products. Diaryl acetylenes with other substituents such as CF3, ethoxycarbonyl, dimethylamino, TMS‐acetylene groups, as well as pyridinyl and thienyl moieties were also accessible with this method. However, methoxy‐substituted compounds were obtained in moderate yields under the same conditions, but the yields were increased when lithium diisopropylamide was used instead. 相似文献
7.
Morita A 《Journal of computational chemistry》2002,23(15):1466-1471
The polarizability of a water molecule in liquid is evaluated via ab initio and density functional calculations for water clusters. This work has considerably improved our previous effort [J Chem Phys 1999, 110, 11987] to attain quantitative accuracy for polarizability. The calculations revealed that the water polarizability in the liquid is reduced from that in the gaseous phase by 7-9%. These results suggest significant implications for polarizable water models. 相似文献
8.
Hirokazu Morisawa Takashi Utagawa Takeshi Miyoshi Fumihiro Yoshinaga Akihiro Yamazaki Koji Mitsugi 《Tetrahedron letters》1980,21(5):479-482
An enzymatic transarabinosylation between 2-chlorohypoxanthine and 1-β--arabinofuranosyluracil gave 9-β--arabinofuranosyl-2-chlorohypoxanthine which was chemically converted to 9-β--arabinofuranosylguanine and its derivatives. 相似文献
9.
Jingye Li Fumihiro Muto Akihiro Oshima Masakazu Washio Shigetoshi Ikeda Yoneho Tabata Chihiro Matsuura 《European Polymer Journal》2006,42(6):1222-1228
New proton exchange membranes (PEMs) were prepared by pre-irradiation induced grafting of α-methylstyrene (AMS)/styrene (STY)/divinylbenzene (DVB) into the crosslinked polytetrafluoroethylene (RX-PTFE) films and successively sulfonated. The new PEMs showed the improved glass transition temperature and chemical stability as compared with the PEMs prepared by pre-irradiation induced grafting of STY/DVB. The balance of the cost, grafting kinetic, thermal properties and the properties of the resulted proton exchange membrane is the key point of this work. 相似文献
10.
A simple model is presented in which the statevector evolves every seconds in one of two ways, according to a particular probability rule. It is shown that this random walk in Hilbert space results in reduction of the statevector. It is also shown how the continuous spontaneous localization (CSL) theory of statevector reduction is achieved as a limiting case of this model, exactly as Brownian motion is a limiting case of ordinary random walk. Finally, a slightly different but completely equivalent form of the CSL equations suggested by the simple model given here is discussed. 相似文献