全文获取类型
收费全文 | 78篇 |
免费 | 2篇 |
专业分类
化学 | 28篇 |
晶体学 | 1篇 |
力学 | 10篇 |
数学 | 13篇 |
物理学 | 28篇 |
出版年
2023年 | 2篇 |
2022年 | 6篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 3篇 |
2010年 | 6篇 |
2009年 | 4篇 |
2008年 | 2篇 |
2007年 | 1篇 |
2005年 | 2篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 8篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有80条查询结果,搜索用时 15 毫秒
1.
Two series (S and F) of poly p-isopropyl α-methylstyrene were characterized by viscometry, light scattering (LS), osmometry and gel permeation chromatography (GPC). S-samples were prepared by bulk anionic polymerization whereas F-samples were obtained on fractionation by preparative GPC of a polymer also prepared in bulk but with a different initiator. The K parameter in the Mark-Houwink relation was 5.55 × 10?4 for series-S and 4.50 × 10?4 for series-F, whereas the exponent a was 0.55 for both series. The Mark-Houwink equations for series-S and -F hold good at 25 and 30° for both toluene and tetrahydrofuran as solvents and have been corrected for polydispersity. The chain dimensions obtained with LS were much higher than those computed from the viscosity data indicating that the hydrodynamic theories in their present state should not be used for the calculation of chain dimensions. The deviations from the GPC universal calibration curve of polystyrene observed with some samples were attributed to structural differences among the polymers and to their high polydispersity. 相似文献
2.
3.
Wijkens P Jastrzebski JT van Der Schaaf PA Kolly R Hafner A van Koten G 《Organic letters》2000,2(11):1621-1624
A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction. 相似文献
4.
Mansoori Arsalan Zahednezhad Fahimeh Bavili Tabrizi Ahad Shahbazi Mojarrad Javid 《Journal of the Iranian Chemical Society》2020,17(1):89-101
Journal of the Iranian Chemical Society - In the present study, we aimed to optimize the synthesis stages of S-pregabalin ((S)-3-(aminomethyl)-5-methylhexanoic acid), a well-known anticonvulsant... 相似文献
5.
6.
Gordeev SN Zhukov AA de Groot PA Jansen AG Gagnon R Taillefer L 《Physical review letters》2000,85(21):4594-4597
We report on transport measurements of YBa 2Cu 3O (7-delta) single crystals with different oxygen contents in the geometry B, J ||ab (J perpendicularB). Our data show that the vortices become confined between the Cu-O planes below a well-defined temperature at which the effective size 2xi of the vortex core is approximately equal to the period of the Cu-O layers. This confinement strongly increases the vortex liquid freezing temperature. A new melting line is found separating a vortex liquid and a smectic phase, which shows an oscillatory field dependence reflecting differences between commensurate and incommensurate smectic states. 相似文献
7.
Ming Xia LI Yan Ming WANG Ru Ru CHEN* Research Institute of Elemento-Organic Chemistry Nankai University Tianjin Pittsburgh University Medical Center Pittsburgh PA U. S. A 《中国化学快报》2001,(6)
The chiral diols ((,(,((,((-Tetraaryl-1,3-dioxolane-4,5-dimethanols) have been used for the formation of cyclic titanates and similar derivatives of Mg, Al and Zr. These complexes of oxophilic metal centers were employed in catalytic and stiochiometric enantioselective reactions such as enantioselective addition reactions of carbon-centered nucleophiles to aldehydes1, [2+2] cycloadditions2, and Diels-Alder reactions3. So far, the two hydrogen atoms of all this type of diols are in trans form… 相似文献
8.
We consider diffraction by a semi-infinite crack located alonga fusion interface between two differing elastic media. Twotypes of crack, namely open and partially closed cracks, areinvestigated. An open crack is modelled by a stress-free contactboundary condition and a partially closed crack is modelledby a spring contact boundary condition. For the latter, thejump in the stress across the crack is assumed to be proportionalto the jump in the displacement across the crack. This situationarises in, for example, a K-weld where the fine grain of theparent material (for example, ferritic or forged austeniticsteel) is in stark contrast with the coarse-grained weld metal(for example, austenitic weld metal). In the metal weld thedirection of the grain axis varies through the metal. However,diffraction is a local phenomenon and so the austenitic steelis assumed to have a zonal axis so that it may be modelled bya transversely isotropic composite. The ferritic or forged austeniticsteel will be modelled as an isotropic material. 相似文献
9.
Ahad Rahimi 《Journal of Pure and Applied Algebra》2007,211(1):83-93
In this paper we consider the local cohomology of monomial ideals with respect to monomial prime ideals and show that all these local cohomology modules are tame. 相似文献
10.
In this paper, we consider the problem of making inferences on the common mean of several normal populations when sample sizes and population variances are possibly unequal. We are mainly concerned with testing hypothesis and constructing confidence interval for the common normal mean. Several researchers have considered this problem and many methods have been proposed based on the asymptotic or approximation results, generalized inferences, and exact pivotal methods. In addition, Chang and Pal (Comput Stat Data Anal 53:321–333, 2008) proposed a parametric bootstrap (PB) approach for this problem based on the maximum likelihood estimators. We also propose a PB approach for making inferences on the common normal mean under heteroscedasticity. The advantages of our method are: (i) it is much simpler than the PB test proposed by Chang and Pal (Comput Stat Data Anal 53:321–333, 2008) since our test statistic is not based on the maximum likelihood estimators which do not have explicit forms, (ii) inverting the acceptance region of test yields a genuine confidence interval in contrast to some exact methods such as the Fisher’s method, (iii) it works well in terms of controlling the Type I error rate for small sample sizes and the large number of populations in contrast to Chang and Pal (Comput Stat Data Anal 53:321–333, 2008) method, (iv) finally, it has higher power than recommended methods such as the Fisher’s exact method. 相似文献