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Mohamed Afqir Amina Tachafine Didier Fasquelle Mohamed Elaatmani Jean-Claude Carru Abdelouahad Zegzouti Mohamed Daoud 《Chinese Journal of Physics (Taipei)》2018,56(3):1158-1165
SrBi2-xHoxNb2O9 (0?≤?x?≤?0.5) ceramics were prepared through the conventional solid state route. The materials have been characterized by XRD, FTIR and SEM. All compounds were pure and well crystallized. In FTIR spectroscopy, the spectral patterns of the crystal structures of these polyphases are unique and smoothly different from each other. The grains were prone to become spherical with increasing x. Dielectric and electrical properties of these materials as a function of temperature at different frequencies have been carried out. The dielectric constant and dielectric loss were found to decrease with an increase of the holmium concentration at room temperature. Reaching up to x?=?0.4 and x?=?0.5, the diffusivity increases, leading to the occurrence of relaxor behavior. 20–30 at.% Ho doping on the Bi-site can fill up the oxygen vacancies and decrease the AC conductivity. However, at higher doping levels greater than 40% holmium oxide, the AC conductivity is found to increase. 相似文献
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Mohamed Afqir A. Tachafine D. Fasquelle M. Elaatmani J. C. Carru A. Zegzouti M. Daoud 《Moscow University Physics Bulletin》2017,72(2):196-202
The SrBi2 – x Sm x Nb2O9 (x = 0, 0.4, 0.5) structure were synthesized by a conventional solid-state method. The X-ray diffraction shows an orthorhombic at room temperature. Dielectric constant, loss tangent and Ac conductivity of Sm-doped SrBi2Nb2O9 were carried out, as well. A higher concentration of samarium (x = 0.4 and 0.5) doping leads to a significant reduction in dielectric constant and in Curie temperature. Rather relaxor type of behaviour took place. 相似文献
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Salah Bouhroum Joseph A. Grondin Stephan Houdier Hassan Lazrek Mohamed Rhazi Abdelouahad Tolaimate 《Journal of carbohydrate chemistry》2013,32(3):309-314
ABSTRACT Hydrazine acetate is shown to effect selective deacetylation on peracetylated glycals like D-xylal, D-glucal, D-galactal and L-rhamnal. It is demonstrated that the observed selectivity on the -4 position cannot be explained by acetyl migration during the reaction. 相似文献
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Rajia Ait Benhamou Gilles Wallez Pascal Loiseau Mohamed Elaatmani Abdelwahed Zegzouti 《Journal of solid state chemistry》2010,183(9):2082-2086
Novel phase RbMgPO4, synthesized by solid state reaction, sustains phase transitions at 169 and 184 °C. The medium (β)- and high- (γ) temperature forms (orthorhombic, respectively Pna21 and Pnma, Z=4) are typical stuffed tridymites but the ambient form (α) exhibits an unusual three-fold Pna21 superstructure that results from the change of coordination of one third of the Mg atoms. Cell parameters are as follows: for α: a=26.535(1) Å, b=9.2926(3) Å, c=5.3368(2) Å; for β: a=8.7938(3) Å, b=9.3698(3) Å, c=5.3956(1) Å; for γ: a=8.7907(3) Å, b=5.4059(1) Å, c=9.3949(3) Å. 相似文献
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F. Capitelli M. Rossi M. Elaatmani A. Zegzouti 《Crystal Research and Technology》2010,45(11):1204-1208
Crystals of Pb0.91K1.72Li1.46Nb5O15, belonging to tetragonal tungsten bronze materials, were grown by the slow cooling technique, and characterized by means of single crystal X‐ray diffraction: the structure was solved in the P4bm tetragonal space group, with the following unit cell parameters: a = 12.548(5), c = 4.042(5) Å, V = 636.4(9) Å3. The three‐dimensional framework can be described as a layered structure down crystallographic axis c, with arrays of NbO6 octahedra, whose corner sharing makes up the formation of tunnels filled up by Li, Pb and K displaying complex cation‐oxygen coordinations. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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M. Oualla M. Elaatmani M. Daoud D. Mezzane I. Luk''yanchuk A. Zegzouti 《Solid State Communications》2004,130(12):777-781
A new ferroelectric rare earth family Pb1.6K1.2R0.2Nb5O15 with R=La, Nd, Sm, Eu and Gd (PKRN) of tetragonal tungsten bronze type ferroelectrics was synthesized. The ferroelectric transition with nonuniform distribution of critical temperature over a ceramic sample was found from dielectric measurements. According to X-ray diffraction measurements, the ferroelectric phase has an orthorhombic symmetry. The transition temperature was shown to decrease weakly with increasing radius of the rare earth ion R. 相似文献
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M. Khachane P. Nowakowski J.R. Gavarri Ch. Muller A. Outzourhite A. Zegzouti 《Applied Surface Science》2007,254(5):1399-1404
Catalytic ruthenium dioxide films were deposited by spin-coating process on ferroelectric films mainly constituted of SrBi2Ta2O9 (SBT) and Ba2NaNb5O15 (BNN) phases. After thermal treatment under air, these ferroelectric-catalytic systems were characterized by X-ray diffraction and scanning electron microscopy (SEM). SEM images showed that RuO2 film morphology depended on substrate nature. A study of CH4 conversion into CO2 and H2O was carried out using these catalytic-ferroelectric multilayers: the conversion was analyzed from Fourier transform infrared (FTIR) spectroscopy, at various temperatures. Improved catalytic properties were observed for RuO2 films deposited on BNN oxide layer. 相似文献
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Rajia Ait Benhamou Aurlie Bessire Gilles Wallez Bruno Viana Mohamed Elaatmani Mohamed Daoud Abdelwahed Zegzouti 《Journal of solid state chemistry》2009,182(8):2319-2325
The double phosphate Ca9Eu(PO4)7, obtained by solid state reaction, was found to be isotypic with Ca3(PO4)2, with space group R3c and unit cell parameters a=10.4546(1) Å, c=37.4050(3) Å, V=3540.67(9) Å3, Z=6. The structure parameters refined using the Rietveld method showed that europium shares positions M1, M2 and M3 with calcium, contradicting previously published Mössbauer results. Low temperature luminescence under selective excitation of Eu3+ in Ca9Y1−xEux(PO4)7 and in Ca9Eu(PO4)7 samples was studied, confirming the Eu3+ distribution into these sites. At 10 K, 5D0→7F0 emission lines of Eu3+ were observed at 578.5, 579.5, 580.1 nm for the M3, M1 and M2 sites, respectively. High temperature X-ray powder diffraction evidenced a second-order phase transition around 573 °C. 相似文献