Li2O-B2O3-P2O5系统非晶态混合骨架效应的NMR研究

用核磁共振对非晶态中B³⁺离子的微观结构进行了测定,结合Raman光谱的研究,对Li₂O-B₂O₃-P₂O₅系统非晶态的性能(电导率、密度等)在P₂O₅/B₂O₃比约等于1时产生极值的原因从理论上作了阐明。     

粉煤灰与复合添加剂的固相反应过程分析

煤灰分中主要矿物质之间的反应对灰分特性有着重要影响。本文在具有温控的小型高温反应器中对粉煤灰和复合添加剂所组成的混合灰样进行了静态煅烧试验，并对煅烧后的灰样进行了X射线衍射分析（XRD），着重讨论了温度和时间以及复合添加剂量对灰分矿相组成特性的影响。试验结果表明：当温度低于1200℃时，灰色中主要是游离态的氧化物和部分新生成的矿物如钙黄长石，硅酸二钙；当温度在1200℃-1300℃时，灰分中的主要矿物是钙黄长石，当温度在1320℃－1350℃时，灰分主要矿物是硅酸二钙，同时存在一定量的硅酸三钙、铝酸三钙、铁铝酸四钙以及硫铝酸钙。随着灰分中氧化钙的含量增加，高碱性矿物含量逐渐增大，同时高温下加热持续时间过长，部分新生成的矿物将发生分解。     

Structural Change in Au^3＋-Doped BK7 Glass Irradiated by Femtosecond Laser

We report on structural change in an Au^3＋-doped BK7 glass irradiated by an infrared femtosecond laser at 800 nm. A grating structure is inscribed in the glass sample. The glass sample is then annealed at various temperatures. Structural change of the grating is observed by an optical microscope. Absorption spectra indicate that colour centres are induced after the laser irradiation, and they decrease with increasing annealing temperature. Au nanoparticles are precipitated at high temperatures （≥ 600℃）. The mechanisms of the phenomena are discussed.     

氧燃烧方式下痕量元素形态转化的试验和模拟研究

结合热重试验及XRF测量,采用化学热平衡分析方法对煤中易挥发的有毒痕量元素砷、铬、锑和汞在不同燃烧方式下的化学形态及分布进行了研究。计算表明,在常规燃烧方式下,痕量元素在400-1800 K的温度范围内容易蒸发,生成气相单质或氧化物。富氧燃烧条件下,高浓度的CO2(g)以及碳颗粒温度的降低在一定程度上会抑制痕量元素的蒸发,同时CO2(g)也会抑制痕量元素向气相次氧化物及单质的转化。     

混煤煤灰熔融特性及矿物质形态的研究

本文对混煤熔融特性温度进行测定，并利用X-射线衍射分析对混煤煤灰的矿物组成进行试验分析，结果表明：混煤可改变原煤的结渣程度；混煤灰熔点与混煤比不成线性关系变化是混煤煤灰的低温共熔现象所致；在变形温度T1下煤灰中矿物质莫来石对煤灰熔融特性温度影响较大，莫来石含量越高，灰熔点越高．     

Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^＋-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation

The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3＋-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3＋ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.     

Blue-to-Orange Tunable Luminescence from Europium Doped Yttrium--Silicon--Oxide--Nitride Phosphors

Europium-doped yttrium-silicon-oxide-nitride phosphors are synthesized by carbothermal reduction and nitridation method. The crystal structure of the phosphors changed gradually from oxide Y2Si2O7 to nitride YSi3N5 state with increasing dosage of Si3N4 and carbon powder. The Y2Si2O7：Eu phosphor shows a blue emission at 465 nm with 300 nm excitation and a characteristic red emission of Eu^3＋ at 612 nm with 230 nm excitation. The YSi3N5：EU phosphor shows a broad emission band centred at 595nm with some sharp peaks of Eu^3＋ with 325nm excitation. The absorption of the studied phosphors increases from 450 to 700hm with an increment in nitrogen content. Blue-to-orange tunable luminescence is observed with 390 nm excitation.     

Gd和Ti共掺杂对BiFeO_3矫顽力和剩余磁矩的影响(英文)

通过快速液相烧结法制备了BiFeO3、Bi0.9Gd0.1FeO3和Bi0.9Gd0.1Fe0.95Ti0.05O3(BGFTO)块材.x射线衍射和拉曼散射光谱表明Gd和Ti共掺杂后的BGFTO样品产生结构相变.共掺杂样品BGFTO室温下的铁磁性得到显著提高,矫顽力达到1.51T,剩余磁矩为0.175emu/g.磁性得到显著提高的根本原因是共掺杂引起元素替换导致了体系中的螺旋磁结构被抑制.A位和B位共掺杂是引发BiFeO3自发磁化的最有效的方法.     

3d金属离子Bi位替代对新型层状超导体Bi_4O_4S_3超导电性的影响

文章报道了3d金属离子X(X=Fe3+,Co3+,Mn4+)少量掺杂对新近发现的超导体Bi4O4S3结构及超导电性的影响.粉末X射线衍射数据表明,少量3d金属离子X的掺杂对晶格结构几乎没有影响.观察发现随着掺杂离子X半径的减少,超导转变宽度△Tc变窄,也就是少量3d金属离子X的掺入提高了Bi4O4S3的超导电性.3d金属离子X的部分掺入提高了Bi4O4S3超导转变温度是一个非常值得关注的现象.     

ErFeO3单晶反常负磁化和补偿温度点性研究

通过光学浮区法生长了直径为6mm,长度约为75mm的晶体,结构分析表明实验样品呈单相的正交钙钛矿结构,并通过劳厄定向仪对ErFeO3晶体进行了定向.系统测量了ErFeO3晶体a,c方向的热磁曲线和不同温度下的磁化曲线.结果表明,随着温度的降低,在98～86K范围该体系经历了从Г4(Gx,Fz)相到Г2(Gz,Fx)相的自旋重取向转变.在ErFeO3体系中,由于Er离子磁矩反平行于Fe离子磁矩分子场,在46K附近,在a方向上Er的反向磁矩大于Fe离子磁矩,导致出现负磁化和磁化补偿点现象.随着外加测量场的增强,a轴向上的负磁化被抑制,补偿温度点向高温移动.