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A novel Mn(Ⅱ)coordination polymer(CP),[Mn(BBA)_(0.5)(BIYB)]_n(1),was gained by the 1,2,4,5-benzenetetracarboxylic acid(H_4BBA),4,4-bis(imidazol-1-ylmethyl)biphenyl(BIYB),and Mn(CH_3COO)_2·4H_2O under hydrothermal reaction.CP 1 was characterized and structurally determined by elemental analyses,PXRD,IR spectra,thermal behaviors,and X-ray single-crystal diffraction.The framework structure of 1 shows a novel(2,5,6)-connected 3Dnetwork with a Schlafli symbol of(4~3.6~6.8)~2(4~6.6~9)(6)~2.It crystallizes in triclinic system,space group ■,with a=7.5898(5),b=9.8201(6),c=14.1307(9)?,α=97.5850(10),β=99.6810(10),γ=111.6580(10)o,V=943.01(10)?~3,Z=2,C_(23)H_(15)MnN _4O_4,M_r=466.33,D_c=1.462 g/cm~3,F(000)=476,S=1.082,R=0.0361 and wR=0.1008.The magnetic property of CP 1 was investigated.The weak antiferromagnetic interactions are observed between the Mn(Ⅱ)ions. 相似文献
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