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溶剂热合成具有纳米孔结构的γ-Al2O3 总被引:2,自引:0,他引:2
0引言γ-Al2O3又称活性氧化铝,一般具有较高的比表面积,在工业生产中被广泛用作吸附剂和催化剂载体[1],尤其是可作为负载贵金属催化剂的载体[2 ̄4]。纳米级的γ-Al2O3由于颗粒粒径小而在其颗粒表面形成了丰富的失配键和欠氧键,以此制成多孔薄膜作为催化剂及催化剂载体,其性能比目前使用的同类产品性能要优越许多[5]。但纳米级的γ-Al2O3也存在一些缺点,如由于纳米颗粒的表面能较高导致了颗粒的团聚较严重,分散性较差;由于γ-Al2O3活性较高,所以其高温热稳定性不太好,这些缺点极大地限制了γ-Al2O3的应用范围。因此合成具有良好分散性和… 相似文献
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非水体系模板法合成新颖形貌氮化硅基材料 总被引:4,自引:0,他引:4
以乙腈为溶剂, 十八胺为模板剂通过非氧化物溶胶-凝胶过程合成了新颖形貌的氮化硅基材料. 通过X射线衍射(XRD), 透射电子显微镜(TEM), 扫描电子显微镜(SEM), N2吸附-脱附和电子能谱(EDS)对样品进行了表征. 结果显示, 材料呈现出由薄膜组成的花瓣状和树叶状新颖形貌, 且具有很高的比表面积和孔径分布很窄的纳米孔, 同时证明了在非水体系中表面活性剂也存在自组装现象, 从而可以作为模板剂来合成具有特殊介观结构和形貌的材料. 相似文献
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Nanoporous gamma aluminum oxide (γ-Al2O3) was synthesized by solvothermal method in the presence of AlCl3·6H2O, urea and alcohol. The calcined sample was characterized by XRD, FTIR, TEM, and Nitrogen adsorption-desorption measurement. Results show that the obtained γ-Al2O3 is well-dispersed nanoparticles with particle size of 4~7 nm and the product has nano-pore structure with a narrow pore size distribution of 5~20 nm. 相似文献
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Recently experiments and theories show that the tunnel magnetoresistance (TMR) does not only depend on the ferromagnetic metal electrodes but also on the insulator. Considering the rough-scattering effect and spin-flip effect in the insulator, this paper investigates the TMR ratio in a ferromagnet/insulator/ferromagnet (FM/I/FM) tunnelling junction by using Slonczewsik's model. A more general expression of TMR ratio as a function of barrier height, interface roughness and spin-flip effect is obtained. In lower barrier case, it shows that the TMR ratio depends on the roughscattering effect and spin-flip effect. 相似文献
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