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用正电子湮没技术、1000kV超高压电子显微镜结合磁测量研究了SmCo5永磁合金在回火中相析出和矫顽力机制。得出:从SmCo5析出的Sm2Co17相本身不是反磁化形核中心,析出的Sm2Co17相中存在的某些多缺陷区域可以具有很低的磁各向异性,从而成为反磁化形核中心,使内禀矫顽力下降。实验中发现:SmCo5从25℃到900℃回火,750℃出现最大磁不可逆损失。各种近邻Sm3+分布的中心Sm3+的磁各向异性随温度变化,越接近Sm2Co17结构,Sm3+为负磁各向异性的可能性越大。
关键词: 相似文献
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In this paper the values of the crystalline-electric-field
parameters Anm for R2Fe17 and
R2Fe17H3 (R=Tb,Ho,Er) are evaluated by fitting
calculations to the magnetization curves measured on the single
crystal at several temperatures. The fitted Anm for
R2Fe17 are strikingly different from those for the
corresponding R2Fe17H3. The energy gaps between the
lowest four energy levels for Ho ions in Ho2Fe172 can be
reproduced by using the fitted Anm and exchange field
2μBHex, which estimated from the fit of the
temperature dependence of the spontaneous magnetization combined
with inelastic neutron scattering experiment. 相似文献
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(Nd1-xYx)3Fe27.31Ti1.69化合物的结构与磁性研究 总被引:2,自引:0,他引:2
制备了(Nd1-xYx)3Fe27.31Ti1.69(0≤x≤0.6)系列化合物,通过X射线衍射和磁性测量等手段研究了它们的结构和磁性.这些化合物均为Nd3(Fe,Ti)29型结构,A2/m空间群.化合物晶胞体积随Y含量增加而单调减少,居里温度Tc随Y含量增加略有降低,说明化合物的居里温度主要由Fe-Fe之间的交换相互作用所决定.温度为5K时,饱和磁化强度Ms随Y含量的增加而单调降低,与一个简单的稀释模型预期结果一致.所得化合物在低温下均发生自旋重取向,自旋重取向温度Tsr随Y含量增加而单调降低,从x=0时的232K减小到x=0.6时的121K.基于磁晶各向异性的研究结果确定了所得化合物的自旋相图. 相似文献
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通过X射线衍射和磁性测量研究了Sm-Co-Ti三元体系富Co区固相线下的相关系,并探索了Co基3:29型化合物存在的可能性,进而研究了某些单相化合物的结构和磁性.实验表明,该体系中存在三个三元化合物SmCo7-xTix,Sm2Co17-xTix和SmCo12-xTix,其固溶区分别为0.32≤x≤0.54,0≤x≤1.13和1.45≤x≤1.95.按Sm9.31Co90-xTix(3≤x≤15)成分配料,Sm按其质量的15%,20%,25%三个比例过量加入,在1303—1403K温度范围内退火,均未发现3∶29相.在制备出的SmCo12-xTix,和Sm2Co17-xTix两个系列化合物中,随着Ti含量的增加,它们的居里温度和饱和磁化强度都单调降低.Sm2Co17-xTix化合物在居里温度以下表现为单轴各向异性,而SmCo12-xTix化合物表现为面各向异性.SmCo12-xTix和Sm2Co17-xTix化合物1.5K下的磁晶各向异性场随Ti含量的变化都呈现一个极大值,这可能与Ti原子的择优占位有关
关键词:
稀土过渡族化合物
X射线衍射
相图
磁晶各向异性 相似文献
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ELECTRONIC STRUCTURE AND CRYSTALLINE ELECTRIC FIELD IN Rco5(R= Y,La, Ce,Pr, Nd,Sm, Gd,and Tb) 下载免费PDF全文
Self consistent charge and spin polarized local spin-density approximation functional theory calculations based on the discrete variational method have been performed for RCo5(R=Y, La, Ce, Pr, Nd, Sm, Gd, and Tb) compounds. The partial density of states of the Pr atom in the PrCo6Co12 cluster is established to be strikingly similar to that of the Ce atom in the CeCo6Co12 cluster, supporting the suggestion that the Pr atom is valence fluctuating. The radii <r4f> and <r4f2> of the 4f electrons of the R atom from La to Tb, except Ce, show the lanthanide contraction. The crystalline electric field (CEF) parameter A02 at the R site is calculated using a real charge distribution ρ(R) in the cluster, except for Pr and Nd, and is in agreement with that evalu ated based on the single-ion model. This result shows that the CEF parameter A02 is mainly determined by the near electronic structure. There exists a hybridization in a certain degree between the light rare-earth R-4f and Co-3d orbitals in some single-electron-molecular-orbitals, which are n ear the Fermi energy level and occupied by electrons. For light rare-earths the R-4f electrons in R Co6Co12(R=Y, La, Ce, Pr, Nd, and Sm) clu sters are not localized entirely and a small amount of the R-4f electrons have itinerant properties. 相似文献
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The crystalline-electric-field parameters Anm for RFe11Ti and RFe11TiH (R=Sm, Tb, Ho) are evaluated by fitting calculations to the magnetization curves measured on the single crystals or on magnetically aligned powder samples at 4.2K and higher temperatures. Interstitial hydrogen atom in RFe11Ti has been found to have a significant effect on crystalline-electric-field parameters Anm. By using the parameters of exchange field 2μBHex estimated from inelastic neutron scattering experiments and the fitted Anm, the calculations can reproduce the experimental curves well. 相似文献
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INTER-GRAIN EXCHANGE INTERACTION FOR SINGLE-PHASE NANOCRYSTALLINE Nd-Fe-B MAGNETS 总被引:1,自引:0,他引:1 下载免费PDF全文
The demagnetization curve as a function of intensity of the inter-grain exchange interaction was calculated for single-phase nanocrystalline Nd-Fe-B magnets by use of the finite-element technique of micromagnetics. Also, the strength of the exchange interaction was estimated as a function of the Nd content x for the nanocrystalline NdxFe94-xB6 magnets by comparing the above result with the experimental relation between iHc and x for the magnets. We found that the inter-grain exchange interaction decreases with the increase of x, are ≈70% and ≈60% of the inter-grain exchange interaction for x=15.5(μ0iHc≈2.0T) and x=19(μ0iHc≈2.3T), respectively. 相似文献