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荧光猝灭法研究苯乙烯氧化物与DNA的相互作用 总被引:1,自引:0,他引:1
荧光猝灭法是一种可以研究苯化合物与DNA相互作用的动态过程的方法。研究结果表明,苯乙烯氧化物与DNA的相互作用与苯乙烯氧化物浓度的关系服从动力学一级方程。 相似文献
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The cationic polymerization of 1,3-pentadiene (PD) initiated by AlCl_3 in n-hexane was carried out. Effects of arenes, alkyl halides and ethers on the gel formation resulting from crosslinking reaction were investigated. The erosslinking was reduced by various arenes through a chain transfer mechanism. Alkyl halides such as tert-butyl chloride and allyl chloride could complex with AlCl_3 to generate an initiating system giving rise to a gel-free polymerization, while benzyl chloride reduced the formation of gel by chain transfer. Ethers exerted two effects on the polymerization system: giving a complex initiating system with AlCl_3 to produce a relatively high molecular weight polymer, or reducing crosslinking by lowering activity of carbocations. 相似文献
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