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PSA分散固相萃取和高效液相色谱-质谱法测定蔬菜中多杀菌素的残留量 总被引:3,自引:0,他引:3
建立了用高效液相色谱-质谱联用(HPLC-MS)技术测定蔬菜中多杀菌素残留量的方法。样品经乙腈提取并用无水硫酸镁和氯化钠混合盐盐析后,上层乙腈经分散固相萃取净化,采用HPLC-MS测定。结果表明:多杀菌素A在0.1μg/L~1 mg/L范围内线性良好,相关系数达0.9999;多杀菌素D在1μg/L~5 mg/L范围内线性良好,相关系数为0.9996;在青椒、萝卜、甘蓝等样品中4个加标水平的平均回收率(n=6)为83.2%~111.9%,相对标准偏差为0.6%~9.1%;多杀菌素A和多杀菌素D的方法检测限分别为0.04μg/L和0.2μg/L。 相似文献
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液相色谱-串联质谱法测定蔬菜和水果中6种新型酰胺类杀菌剂的残留量 总被引:1,自引:0,他引:1
建立了蔬菜、水果中啶酰菌胺、氟啶酰菌胺、环氟菌胺、嘧菌胺、双炔酰菌胺和硅噻菌胺6种新型酰胺类杀菌剂残留量的液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry, LC-MS/MS)检测方法。试样经乙腈提取、Florisil固相萃取柱净化、以乙腈和水为流动相梯度洗脱、结合新型核壳型填料色谱柱(Poroshell 120 EC-C18)分离,采用电喷雾正离子扫描、多反应监测模式质谱检测,外标法定量。结果表明:固相萃取结合新型色谱柱分离解决了酰胺类农药分析中基质效应强的难点问题。6种杀菌剂在0.5~100 μg/L范围内线性关系良好,相关系数(r)≥0.9990;对7种蔬菜及3种水果进行0.5、5和50 μg/kg 3个加标水平的回收试验,回收率为65%~124%,相对标准偏差(RSD, n=5)为1%~18%; 6种杀菌剂的方法检出限(S/N≥3)为0.10~0.17 μg/kg。该净化、分离模式显著降低了蔬菜、水果中6种新型酰胺类农药的基质效应,方法简单准确,可满足蔬菜和水果中啶酰菌胺等6种新型酰胺类杀菌剂残留检测的要求。 相似文献
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The binary alloy/ferromagnetic metal heterostructure has drawn extensive attention in the research field of spin–orbittorque(SOT)due to the potential enhancement of SOT efficiency via composition engineering.In this work,the magneticproperties and SOT efficiency in the Pt100?xNix/Ni78Fe22 bilayers were investigated via the spin-torque ferromagneticresonance(ST-FMR)technique.The effective magnetic anisotropy field and effective damping constant extracted by analyzing the ST-FMR spectra show a weak dependence on the Ni concentration.The effective spin-mixing conductanceof 8.40×1014??1·m?2and the interfacial spin transparency Tin of 0.59 were obtained for the sample of Pt70Ni30/NiFebilayer.More interestingly,the SOT efficiency that is carefully extracted from the angular dependence of ST-FMR spectrashows a nonmonotonic dependence on the Ni concentration,which reaches the maximum at x=18.The enhancement ofthe SOT efficiency by alloying the Ni with Pt shows potential in lowering the critical switching current.Moreover,alloyingrelatively cheaper Ni with Pt may promote to reduce the cost of SOT devices. 相似文献
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以一阶微分散射理论为基础,从理论和模拟两个方面对超光滑基片表面的散射电磁场进行了数值研究.分析了s偏振光和p偏振光的微分散射随入射角和散射角的分布情况.研究发现,当入射角较大时,p偏振光在某个散射方向的微分散射为0,而无论入射角和散射角如何变化,s偏振光的微分散射均大于0.当用光散射法对超光滑基片进行表面测试时,相对于... 相似文献
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Given a topological dynamical system(X,T) and a T-invariant measure μ,let B denote the Borel σ-algebra on X.This paper proves that(X,B,μ,T) is rigid if and only if(X,T) is μ-A-equicontinuous in the mean for some subsequence A of N,and a function f ∈L2(μ) is rigid if and only if f is μ-A-equicontinuous in the mean for some subsequence A of N.In particular,this gives a positive answer to Question 4.11 in [1]. 相似文献
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建立了高效液相色谱(HPLC)测定仲丁胺的分析方法。试样采用全自动凯氏定氮仪蒸馏,蒸馏液经碱中和,以9-氯甲酸芴甲酯(FMOC)为衍生剂在碱性条件下衍生,衍生产物经C18柱分离,紫外检测器(265nm)检测。实验考察了衍生剂浓度、硼酸盐缓冲溶液的p H值、反应温度与时间等因素对衍生反应的影响,结果表明,最优的衍生剂浓度为0.50 g/L,缓冲溶液p H值为8.0,反应温度为室温,反应时间为15 min。在此条件下,仲丁胺在0.001~1.000 mg/L浓度范围内与其响应信号呈良好的线性关系,相关系数为0.999 8,加标回收率为82.4%~95.2%,相对标准偏差为1.3%~6.8%,方法检出限为0.1μg/kg,定量下限为0.5μg/kg。该方法快速、简便、安全、灵敏度高、重现性好,可用于果蔬中仲丁胺残留的测定。 相似文献