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1.
我们在本文中制作了五种不同SrAl2O4:Eu^2+和Dy^3+的样品。样品分别是SrAl2O4基质的α相和β相的粉末和片状样品,以及单晶样品。我们对所有样品进行了形貌的SEM研究。我们还对α相和β相粉末样品及片状样品以及α相单晶样品的荧光发射谱进行了测量。它们的荧光发射的中心波长为520nm,对应于SrAl2O4基质中的Eu^2+的4f^65d^1的^2eg激发态到4f^7的^8S7/2的跃迁发 相似文献
2.
CaxSr1—xS:Bi,Tm,Cu和CaS:Eu荧光材料的研究 总被引:11,自引:0,他引:11
所作的一部分工作是对长余辉的荧光材料CaxSr1-xSBi,Tm,Cu(x=0,0.75,1)进行了研究.CaS和SrS两种基质材料高温互溶后,因为基质的晶体微结构上的变化引起Bi3+离子荧光效应的变化,即发光的发射波数发生改变.另一部分工作是对CaSEu加入陷阱机制后发光效应的研究.新的陷阱机制的引进,使得其余辉效应有较大的延长. 相似文献
3.
在本文中制作了CaAl4 O7:Tb3+,Ce3+新荧光材料。烧结温度为 130 0℃ ,烧结环境为N2 + 5 %H2还原气。TEM实验结果表明样品的粒度小于 1μm。X 射线和HRTEM实验证实 ,样品的晶格点阵十分规则 ,而且没有发现掺杂和助溶剂对基质结构的影响 ,表现出十分好的材料质量。光学实验观测到对应于Tb3+离子的 5D4 到7FJ(J=6 ,5 ,4,3) 的跃迁发射峰在 485 ,5 45 ,5 90和 6 2 0nm。CaAl4 O7:Tb3+,Ce3 +降低了基质结构的不确定性 ,同时保持了Tb3+发光中心的特性。 相似文献
4.
In this work, double-center.doped luminescent material CaS:Bi3+, Eu2+ was made via flux NH4Cl by sintering in excess sulfur environment. The sample had a purplish red net luminescent color. Excitation spectra at both red, 650 nm and blue, 487 nrn were taken. The red emission from Eu2+ center was mainly come from the 4f65d1 absorption in the CaS host. The blue emission from the Bi3+ center on the other hand showed no big difference from the singly doped CaS:Bi3+ materials in excitation spectrum. Emission spectra were obtained at excitaton of 270nm and 300nm. Stokes shift was moved about 20-30nm, under different point excitation. Emission peaks of both Bi3+ and Eu2+ centers appeared at 463nm, 642.5nm by 270nm excitation and 487 nm, 620 nm by 300 nm excitation respectively. After-glow decay cures were also obtained and the shapes of decay curves are similar and it is due to the single hole-trap system by lattice defects. 相似文献
5.
In this work, we made five samples of SrAl2O4: Eu2+, Dy3+, the α phase and β phase SrAl2O4:Eu2+,Dy3+ powder and pellet samples, and α phase single crystal. We have measured the emission spectra of all the samples. All the emission peaks are around 520 nm, which correspond to the transition from 4f65d1(2Eg) to 4f7(8S7/2) of Eu2+ in SrAl2O4 host. The intensity of emission of the β phase is stronger than that of the α phase. We believe that it is because the Eu2+ ions have occupied the two types of sites in the α phase SrAl2O4 host and the lifetime of the transition of Eu2+ in the A site is longer than that in the B site. This result also proves that the β phase of the material is brighter than the α phase. In addition, the β phase can be achieved by quenching technique. 相似文献
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7.
Ishai等人首先提出了批处理码的概念,Peterson等人从纯组合的观点定义了(n,N,k,m)-组合批处理码:即是一个n元集和它的m个子集组成的集合系统,对于整数尼,满足任意k个元素都能从每个子集中至多读取1个元素(可以一般化为t个元素)来取得,此时m个子集中元素的总数为N.对给定的参数n,k,m,确定N的最小值N(n,k,m)是该问题研究的中心内容,它不仅具有理论意义,而且有着重要的使用价值.到目前为止,除了一些极特殊的参数以外,当k≥5,m+3≤n(m k-2)时,N(n,k,m)的值还没有被确定.本文给出了N(m+3,5,m)=m+11(m≥7),N(9,5,6)=18,N(m+3,6,m)=m+13(m≥8),N(10,6,7)=21.得到的结果部分解决了:Peterson等人提出的未解决问题. 相似文献
8.
在本文中制作了CaAl4O7:Tb^3 ,Ce^3 新荧光材料。烧结温度为1300℃,烧结环境为N2+5%H2还原气。TEM实验结果表明样品的粒度小于1μm。X-射线和HRTEM实验证实,样品的晶格点阵十分规则,而且没有发现掺杂和助溶剂对基质结构的影响,表现出十分好的材料质量。光学实验观测到对应于Tb^3 离子的^5D4到^7FJ(J=6,5,4,3)的跃迁发射峰在485,545,590和630nm。CaAl4O7:Tb^3 ,Ce^3 降低了基质结构的不确定性,同时保持了Tb^3 发光中心的特性。 相似文献
9.
In this work, double-center.doped luminescent material CaS:Bi3+, Eu2+ was made via flux NH4Cl by sintering in excess sulfur environment. The sample had a purplish red net luminescent color. Excitation spectra at both red, 650 nm and blue, 487 nrn were taken. The red emission from Eu2+ center was mainly come from the 4f65d1 absorption in the CaS host. The blue emission from the Bi3+ center on the other hand showed no big difference from the singly doped CaS:Bi3+ materials in excitation spectrum. Emission spectra were obtained at excitaton of 270nm and 300nm. Stokes shift was moved about 20-30nm, under different point excitation. Emission peaks of both Bi3+ and Eu2+ centers appeared at 463nm, 642.5nm by 270nm excitation and 487 nm, 620 nm by 300 nm excitation respectively. After-glow decay cures were also obtained and the shapes of decay curves are similar and it is due to the single hole-trap system by lattice defects. 相似文献
10.