关于Hopf丛S3的几个论题

本文证明了Hopf主纤维丛S^3的几个相关的命题，指出底流形S^3上的Laplace算子在主丛上的提升是主丛S^3上的Laplace算子，以及主丛的嵌入截面具有不动点性质等。     

玻色─爱因斯坦关联半径和源半径对实验窗口的依赖及它们的差异

研究了１６０ＡＧｅＶＰｂ＋Ｐｂ反应中π源的玻色─爱因斯坦关联半径和源半径（均方根半径）的关系，以及它们对实验窗口的依赖。模型冗源由ＵＲＡＳｉＭＡ生成器产生。研究表明关联半径和源半径不仅数值不等，而且变化行为也不同。     

ON THE STRUCTURE OF CONTINUA AND THE MATHEMATICAL PROPERTIES OF ALGEBRAIC ELASTODYNAMIC OF A TRICLINIC STRUCTURAL SYSTEM

This paper is neither laudatory nor derogatory but it simply contrasts with what mightbe called elastostatic(or static topology),a proposition of the famous six equations.Theextension strains and the shearing strainsfor all i,j,k=1,2,3.which were derived by A.L.Cauchy,are linearly expressed in terms of nine partialderivatives of the displacement function(u_i,u_j,u_k)(?)u(x~i,x~j,x~k)and it is impossiblefor the inverse proposition to sep up a system of the above six equations in expressing thenine components of matrix((?)(u_i,u_j,u_k)/(?)(x~i,x~j,x~k)).This is due to the fact that ourgeometrical representations of deformation at a given point are as yet incomplete .On theother hand,in more geometrical language this theorem is not true to any triangle,exceptorthogonal,for“squared length”in space.The purpose of this paper is to describe some mathematic laws of algebraicelastodynamics and the relationships between the above-mentioned important questions.     

溶剂热还原合成Cr2O3纳米管(英)

Cr₂O₃ nanotubes with diameters of 80 nm and lengths of 550 nm were synthesized in a solvothermal reduction system at 180 ℃. The acetyl acetone (AcAc) and ethylene glycol (EG) were used as the chelate agent and the reductant respectively in the system. An intermediate compound-Cr(Ⅲ)(C₅H₇O₂)₃ was formed to force Cr₂O₃to crystallize along one direction.     

多官能单体TMPTA在LDPE表面光接枝聚合研究

以二苯甲酮(BP)为光引发剂、丙酮和水的混合物为溶剂,研究了室温下多官能单体三羟甲基丙烷三丙烯酸酯(TMPTA)在低密度聚乙烯(LDPE)表面的光接枝聚合(λ>300nm).研究表明,多官能单体的接枝速率较快,接枝聚合易产生交联结构,聚合后仍残留双键;延长聚合反应时间、增加单体用量有利于单体接枝转化率的提高;随引发剂用量增加,单体接枝转化率出现一峰值;在研究范围内,混合溶剂中水含量增加可使单体接枝转化率明显提高.扫描电镜观察到接枝膜表面形成了许多小球,表面粗糙度增加,疏水性提高.     

一维链状锰配位聚合物[Mn(4-CPOA)(2,2-bipy)(H_2O)]_n的合成与晶体结构(英文)

0IntroductionThe solid-state chemistry of manganese!car-boxylate coordination polymers has received growingattention over the past few years,owing to their fasci-nating network topologies and potential application inthe field of molecular magnetism and bi…     

三维网状的4-羧基苯氧乙酸锶(Ⅱ)配位聚合物[Sr2(4-CPOA)2(H2O)5]n的合成、结构与热稳定性研究

A novel coordination polymer of [Sr₂(4-CPOA)₂(H₂O)₅]_n (where 4-CPOA^2- is 4-carboxylphenoxyacetate) has been synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex belongs to monoclinic system with space group C2/c, a=2.563 9(5) nm, b=1.162 7(2) nm, c=0.742 96(15) nm, β=99.64(3)°. V=2.183 5(7) nm³, Z=4, M_r=653.60, D_c=1.988 g·cm^-3, R=0.027 8, wR=0.058 1. The strontium atom has a bicapped triangular prismatic coordination geometry, involving four oxoacetate oxygen atoms, one ether oxygen atom from different 4-CPOA^2- ligands and three water molecules. The strontium(Ⅱ) ions are linked by 4-CPOA^2- ligands and water molecules to form a 3D network structure. CCDC: 223313.     

4-氯酚在TiO2纳米膜上光催化降解及反应动力学特征

氯酚(ＣＰ)化合物被广泛应用于木材防腐、金属防锈及杀虫剂等,因其毒性大、难降解,对环境造成严重污染[1,2]。目前用于ＣＰ的光催化降解的ＴｉＯ2粉体悬浮体系,催化剂不易回收利用。本文采用Ｓｏｌ Ｇｅｌ法制备的负载型ＴｉＯ2纳米粒子膜作为光催化剂,对4 ＣＰ进行了降解实验研究。同时应用ＸＲＤ法表征了不同实验条件下薄膜中ＴｉＯ2的晶相结构和粒度,考察了不同层数ＴｉＯ2膜的光催化活性,并对4 ＣＰ的降解条件及反应动力学特征进行了探讨。1　实验部分1.1　玻璃负载ＴｉＯ2膜的制备与表征[3-5]按照钛酸四丁酯∶无水乙醇∶水=3∶12∶…     

在TM-HgI_2体系中TmI_2生成机理

引言TmI_2的合成早已有报导,一般采用TmI_3与相应的金属(铥)反应制取。但由于TmI_3易吸水,操作不便。而Tm与HgI_2的反应,反应物可以在空气中按化学计算量称量,操作方便。因稀土二价碘化物歧化稳定性不同,不同稀土二价碘化物的制备方法不同。在制备TmI_2时选用Tm与HgI_2反应,但按文献做法总含有TmI_3。为此我们研究了Tm-HgI_2体系间的反应机理,以期得到较纯的产物。     

酸性吸附树脂对2,6-二氯苯酚的吸附热力学和动力学研究

本文以二硫代二苯甲酸、均苯四甲酸酐和没食子酸为修饰剂,通过后交联反应和化学修饰反应制备了3种酸性功能基修饰的超高交联树脂。通过等温吸附实验和吸附动力学实验,探讨了3种酸性吸附树脂对2,6-二氯苯酚(2,6-DCP)的吸附性能和吸附机制。结果表明,3种酸性吸附树脂对2,6-DCP均具有良好的吸附性能,吸附量随着2,6-DCP初始浓度的增大而增加,随着温度的升高而减小。Langmuir和Freundlich等温吸附方程均能够较好地拟合吸附等温线,3种酸性树脂对2,6-DCP的吸附机理较复杂。吸附热力学结果表明,吸附过程主要为放热、自发的物理吸附过程。3种酸性树脂对2,6-DCP的吸附动力学过程符合准一级动力学方程,颗粒内扩散是该吸附过程的主要控制步骤。3种酸性吸附树脂对2,6-DCP的吸附速率常数大小顺序为kGAMRkDSTAMRkPMDAMR。