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The first thermodynamic dissociation constants of o-phthalic acid were determined at five temperatures from 278.15 to 318.15 K in 10, 14.93 and 20 wt% isopropanol-water solvent mixtures, by precise e. m. f. measurements of hydrogen-silver chlorld electrodes in cells without liquid junction. On the basis of Pitzer's theory, the method of polynomial approximation was used to determine the dissociation constants of H_2P and the results obtained were compared with traditional extrapolation according to the extended Debye-Huckel equation Results obtained from both methods agree within experimental error. The dependence of the first thermodynamic dissociation constant on temperature was given as a function of the thermodynamic temperature T by the empirical equation: pK_1=A_0+A_1/T+A_2/T. The thermodynamic quantities of dissociation in the mixed solvents have been calculated, and the results have been discussed. 相似文献
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测量电池Pt,H_2(g,1atm)|HCl(I_A),CoCl_2(I_B)|AgCl-Ag的电动势,确定了HCl(A) CoCl_2(B) H_2O体系中HCl在总离子强度I=0.5到5.0mole kg~(-1)和温度5—45℃下的活度系数γ_A,其中I_A和I_B分别是HCl和CoCl_2的离子强度。本体系中HCl活度系数为 lgγ_A=(E~0-E)/2k-0.5lg[(1-y_B)(1-y_B/3)I~2] (1)式中k=(RTln10/F),E和E~0分别是电池电动势和标准电动势,y_B是CoCl_2的离子强度分数。测定每种溶液电池在不同温度的电动势顺序,首先测定25℃,然后依次测定15° 相似文献
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基于VirtualLab虚拟仿真软件建立了粒径在几十到几百微米内不同大小和形状的气泡模型。对其在平面光照射下的散射进行了仿真模拟,得到了气泡的前向、后向光散射特征分布,将结果与水粒的光散射特征进行比较分析,发现:同一气泡前向散射远大于后向散射,但两者拥有十分相近的变化趋势。光源和气泡大小影响气泡远场散射幅值的大小、振荡频率、角宽度及次极大与主极大的比值。气泡结构的对称性影响着气泡远场散射的对称性。气泡与水粒的远场散射特性既联系又区别。该研究的结果可以为气泡的分析检测提供了一定的理论依据。 相似文献
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In this paper, under assumption that tempeature is linearly distributed along the thickness of the shell, we deal with problems as indicated in the title and obtain general solutions of them which are expressed in analytic form.In the first part, we investigate free vibration of circular shallow spherical shells with circular holes at the center under usual arbitrary boundary conditions. As an example, we calculate fundamental natural frequency of a circular shallow spherical shell whose edge is fixed (m=0). Results we get are expressed in analytic form and check well with E. Reissner’s [1]. Method for calculating frequency equation is recently suggested by Chien Wei-zang and is to be introduced in appendix 3.In the second part, we investigate forced vibration of shells as indicated in the title under arbitrary harmonic temperature field and arbitrary harmonic dynamic normal load.In the third part, we investigate forced vibration of the above mentioned shells with initial conditions under arbitrary unsteady temperature field and arbitrary normal load.In appendix 1 and 2, we discuss how to express displacement boundary conditions with stress function and boundary conditions in the case m=1. 相似文献
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对于半正态探知函数,使用两个最佳带幅宽和六个属于相同的函数族、不同的核函数(其中3个是经常被使用、著名的核函数,另外3个是我们作成的核函数)来进行密度推定,通过计算机数值模拟产生测线调查样本;用统计量RRMSE和RB对密度推定值进行评价,来验证核函数的优劣。 相似文献
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