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研究Ti-50.8at%Ni合金在马氏体-奥氏体相变温度附近的电磁性质.由M-H曲线分析了传导电子的顺磁性以及少量局域电子引起的铁磁性.在M-T曲线中,降温曲线在180K附近有突降,升温曲线在230K附近有突升.在电阻率测量中,降温和升温的ρ-T曲线也有类似的突变.升温过程的质量热容cp曲线在230K附近出现了由奥氏体相变引起的跳跃.这些实验结果表明,样品的马氏体相变温度约
关键词:
TiNi合金
电磁性质
马氏体-奥氏体相变
质量热容 相似文献
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通过热重-差热分析(TG-DTA),考察了Mn12-Ac磁性分子晶体从室温到270℃的热失重过程.结合x射线粉末衍射分析,认为在第一个失重阶段,即25—110℃,Mn12-Ac失去了处于团簇分子间隙的结晶乙酸和结晶水,同时失去了团簇分子中与4个Mn3+配位的4个H2O,Mn12-Ac单晶结构被破坏,但是团簇分子的基本结构依然存在;在第二个失重阶段,即180—230℃,Mn12-Ac转变为γ-Mn2O3,其中混有少量Mn3O4.
关键词:
Mn12
分子团簇
热重-差热分析
x射线衍射 相似文献
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CeCu6是一种重费密子系统,采用Ni替代Cu研究磁性原子掺杂的多晶样品CeCu6-xNix(x=0.00,0.05,0.10,0.15,0.20)在极低温下的电阻随温度的变化规律.实验结果表明,随着Ni原子掺杂量的增加,电阻的规律发生变化.在500mK以下,x≈0.1的样品电阻与温度呈线性关系,表现出非费密液体行为,而其他样品皆为典型的费密液体,x≈0.1是其临界掺杂成分.对比用Au替代的情况,临界掺杂成分也是0.1,但Au掺杂是靠体积膨胀来改变合金的基态性质,而Ni掺杂则是因其磁性造成对合金基态性质的影响
关键词:
重费密子
临界掺杂
非费密液体 相似文献
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测量了重电子金属CeCu6-xNix(x=0,005,01,015,02)01K—250K的低温电阻和5K—70K低温比热,发现样品电阻的极大值温度随着掺Ni含量的增大而急剧下降,这一现象反映少数与Ni邻近的Ce离子在极低温下磁矩的加强和整个Ce离子点阵对导电电子相干散射的减弱.与此相反,低温电子比热系数γ在较低温度下近于常数,而在8K附近因有效质量变大而明显上升,但γ明显上升的温度,对Ni的含量却不敏感,表明绝大部分Ce离子的状况并未受到影响
关键词:
重费米子系统
低温比热
低温电阻 相似文献
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液氦减压制冷系统是目前广泛使用的1—4 K制冷装置。文章首先简要分析了液氦减压制冷系统的现状、原理,而后进一步说明各个组成部分的原理、设计和使用时应考虑的内容,并详细描述了液氦制冷系统的关键部件——流阻的现状及发展前景,最后列举了使用中常见的问题及其预防和处理方法。 相似文献
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通过热重 差热分析 (TG DTA) ,考察了Mn1 2 Ac磁性分子晶体从室温到 2 70℃的热失重过程 .结合x射线粉末衍射分析 ,认为在第一个失重阶段 ,即 2 5— 110℃ ,Mn1 2 Ac失去了处于团簇分子间隙的结晶乙酸和结晶水 ,同时失去了团簇分子中与 4个Mn3 配位的 4个H2 O ,Mn1 2 Ac单晶结构被破坏 ,但是团簇分子的基本结构依然存在 ;在第二个失重阶段 ,即 180— 2 30℃ ,Mn1 2 Ac转变为γ Mn2 O3,其中混有少量Mn3O4 . 相似文献
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The ac susceptibility of single crystals of Ni4 single-molecule magnets is measured by a compensation measurement setup. The magnetic relaxation time calculated from the peak of the out-phase component of the susceptibility fits the Arrhenius law well and gives an effective spin-flipping energy barrier of Uefr = 7.2 K. This value is fax below the classical activation energy barrier of U = 14 K, whereas it is close to the energy gap between the Sz= ±4 and S, = ±3 doublets, which indicates that quantum tunneling between the Sz = 3 and Sz = -3 states plays a key role in the magnetic relaxation. Therefore the relaxation process combines thermal activation and quantum tunneling. Also we deduce that the blocking temperature of Ni4 single-molecule magnets is lower than 0.3 K by extrapolating the relaxation time plot, which ensures that this single-molecule magnet material enters a long-range magnetic ordered state instead of a spin glass state at 0.91 K. 相似文献
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We report the discovery that the low-temperature magnetic relaxation in Mn12Ac single crystals strongly depends on the shape of the samples. The relaxation time exhibits a minimum at the phase transition point between ferromagnetic and antiferromagnetie phases. The shape dependence is attributed to the dipolar interaction between molecular magnets. 相似文献
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The anisotropy of two successive transitions of the spin-ladder compound LiCu2O2 is studied by the specific heat ( C) under magnetic fields with H / / c and H / / ab (written as H^c and H^ab in the following) up to 14 T. The peak of specific heat at 24.5 K in zero field shifts to lower temperature when the field is increased and the magnitude of the peak is suppressed by the field. On the contrary, the peak of 22.5 K shifts to higher temperature, especially at 14 T. Its magnitude increases in the field of H^c, whereas it decreases in the field of H^ab. We calculate the entropy change between 21 K and 63 K. The different influence of the spin ordering by fields of different direction is obtained. Our experimental results suggest a mixed state between the long range incommensurate helimagnetic ground state and the higher-T short-range dimer liquid state. The temperature range of mixed state is shrunk with the increasing field. Possible mechanism is discussed. 相似文献
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