排序方式: 共有5条查询结果,搜索用时 0 毫秒
1
1.
本文报道了一种共价有机大环化合物的高效合成方法。利用双咪唑鎓盐H2-L1(BF4)2(L1=A1,B1)和氧化银反应,生成双核银卡宾大环化合物[Ag2(L1)2](BF4)2(L1=A1,B1),其中连接在2个卡宾配体上的端烯取代基分别排列在环的两侧。随后,通过金属卡宾模板导向的烯烃复分解反应进行关环,制备得到闭环的双核银卡宾大环化合物[Ag2(L2)](BF4)2(L2=A2,B2)。最后,移除模板银离子即可得到拥有空腔结构的共价有机大环化合物H4-L2(BF4)4(L2=A2,B2)。此类多咪唑鎓盐大环的尺寸和形状可以通过改变氮杂环卡宾前驱体连接单元的长度或者宽度进行精细调节。初步研究表明,该大环受体在碘离子的传感、检测和识别方面具有潜在的应用前景。 相似文献
2.
The ATF2 project is the final focus system prototype for the ILC and CLIC linear collider projects, with a purpose of reaching a 37 nm vertical beam size at the interaction point (IP). During the initial commissioning, we started with larger-than-nominal β-functions at the IP in order to reduce the effects from higher-order optical aberrations and thereby simplifying the optical corrections needed. We report on the simulation studies at two different IP locations developed based on waist scan, dispersion, coupling and β function multiknobs correction in the large β optics of ATF2, in the presence of two kinds of magnet inaccuracies (quadrupole gradient and roll errors) to generate all possible linear optic distortions at the IP. A vertical beam size which is very close to the nominal beam size is obtained based on the simulation study. 相似文献
3.
The ATF2 project is the final focus system prototype for the ILC and CLIC linear collider projects, with the purpose of reaching a 37nm vertical beam size at the interaction point. In the nanometer beam size regime, higher order multipoles in magnets become a crucial point for consideration. The strength and rotation angle of the ATF2 QEA magnets were reconstructed from the IHEP measurements and compared with the KEK ones to be identical. Based on the study of the skew multipoles sensitivity, we report on the analysis of the possible mitigation of the measured multipoles. A suggestion is given which will benefit the ATF2 present commissioning to reach the goal beam size, and also the reduced β optics in future. 相似文献
4.
5.
The beam halo is a major issue for interaction region (IR) backgrounds at many colliders, for example, future linear colliders, B factories, and also it is an important problem at ATF2. In this paper, we report on the halo propagation along the ATF2 beam line with realistic apertures, the nonlinear optics influence on the increasing number of halo particles input is analyzed, and the transmitted halo particles distribution just before the last BPM is then described, the results from which will benefit the Compton recoil electrons measurement. 相似文献
1