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Superconductivity of Lanthanum Superhydride Investigated Using the Standard Four-Probe Configuration under High Pressures 下载免费PDF全文
Recently,the theoretically predicted lanthanum superhydride,LaH10±δ,with a clathrate-like structure was successfully synthesized and found to exhibit a record high superconducting transition temperature Tc≈250 K at~170 GPa,opening a new route for room-temperature superconductivity.However,since in situ experiments at megabar pressures are very challenging,few groups have reported the ~250 K superconducting transition in LaH10±δ.Here,we establish a simpler sample-... 相似文献
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A-site ordered perovskite CaCu_3Cu_2Ir_2O_(12-δ) with square-planar and octahedral coordinated Cu ions 下载免费PDF全文
A novel CaCu_3Cu_2Ir_2O_(12-δ) polycrystalline sample was synthesized at 8 GPa and 1373 K.Rietveld structural analysis shows that this compound crystallizes in an AA'_3B_4O_(12)-type A-site ordered perovskite structure with space group Im-3.Xray absorption spectra reveal a +2-charge state for both the square-planar and octahedral coordinated Cu ions,and the valence state of Ir is found to be about +5.Although the A-site Ca and the A'-site Cu~(2+) are 1:3 ordered at fixed atomic positions,the distribution of B-site Cu~(2+) and Ir~(5+) is disorderly.As a result,no long-range magnetic ordering is observed at temperatures down to 2 K.Electrical transport and heat capacity measurements demonstrate itinerant electronic behavior.The crystal structure is stable with pressure up to 35.7 GPa at room temperature. 相似文献
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