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The influences of UV light irradiation (313 nm) and diffused daylight on the polymerization of methyl acrylate initiated by the ceric ammonium nitrate without any reducing agent have been studied both in aqueous nitric acid and in pure water. The rate of polymerization was found to be accelerated and the overall activation energy and the induction time were found to be decreased sharply by the UV light irradiation. Under UV light, the rate of polymerization is 8 times as high as the rate in dark. The rate of polymerization was found to attain a maximum with the increase of nitric acid concentration and the rate of polymerization became less sensitive to UV light in the presence of nitric acid whereas the induction period reduced outstandingly. Based on the experimental results, the mechanism is proposed.  相似文献   
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从二次谐波电场满足的波动方程出发,考虑到介质对二次谐波的吸收以及把完全边界条件应用于基频波和二次谐波在介质的入射面和出射面之间的反射效应,推导出了单光轴非线性薄膜介质中的二次谐波输出功率的计算式.结果表明:当采用复折射率的概念时,可以把非线性无吸收介质的二次谐波输出功率计算式应用到非线性吸收介质二次谐波输出功率计算式中去.  相似文献   
3.
Jianjin Zhou 《中国物理 B》2022,31(5):50702-050702
In recent years, gas electron multiplier (GEM) neutron detectors have been developing towards high spatial resolution and high dynamic counting range. We propose a novel concept of an Al stopping layer to enable the detector to achieve sub-millimeter (sub-mm) spatial resolution. The neutron conversion layer is coated with the Al stopping layer to limit the emission angle of ions into the drift region. The short track projection of ions is obtained on the signal readout board, and the detector would get good spatial resolution. The spatial resolutions of the GEM neutron detector with the Al stopping layer are simulated and optimized based on Geant4GarfieldInterface. The spatial resolution of the detector is 0.76 mm and the thermal neutron detection efficiency is about 0.01% when the Al stopping layer is 3.0 μ m thick, the drift region is 2 mm thick, the strip pitch is 600 μ m, and the digital readout is employed. Thus, the GEM neutron detector with a simple detector structure and a fast readout mode is developed to obtain a high spatial resolution and high dynamic counting range. It could be used for the direct measurement of a high-flux neutron beam, such as Bragg transmission imaging, very small-angle scattering neutron detection and neutron beam diagnostic.  相似文献   
4.
中子敏感微通道板(Neutron sensitive microchannel plate,nMCP)因其具有高探测效率和位置分辨,配合先进的读出电子学可作为能量分辨中子成像探测器的优先选择.相比于基体掺杂型的nMCP,基于原子层沉积技术(Atomic Layer Deposition,ALD)的nMCP具有原材料消耗...  相似文献   
5.
A time-of-flight polarized neutron imaging setup was realized by integrating an in situ pumped polarized 3He spin filter and energy dispersive neutron camera on the neutron technique development beamline(BL-20) of the China Spallation Neutron Source(CSNS). Test experiments were performed with a solenoid with aluminum wire as a sample. These demonstrated that polarized radiography with a field of view in diameter 2.0 cm at different wavelengths can be obtained. The wavelength-dependent...  相似文献   
6.
微束斑X射线源LaB_6阴极电子枪的设计   总被引:1,自引:0,他引:1  
LaB6阴极电子枪是微束斑X射线源的关键组成部件之一。详细的讨论了电子枪的各组成电极 ,即LaB6阴极、Wehnelt栅极和阳极的设计。采用边界元法 (BEM )对电子枪内部电场电位和场强分布进行了有效的数值计算 ,并从阴极开始起利用四阶Runge Kutta法追踪电子的运动轨迹。给出了当阳极端口处电子束半径为设计值时各电极电压、电极结构等工作参量 ,利用该LaB6阴极电子枪可以满足微束斑X射线源需要高亮度、微细电子束发射的要求。  相似文献   
7.
从二次谐波电场满足的波动方程出发,考虑到介质对二次谐波的吸收以及把完全边界条件应用于基频波和二次谐波在介质的入射面和出射面之间的反射效应,推导出了单光轴非线性薄膜介质中的二次谐波输出功率的计算式.结果表明:当采用复折射率的概念时,可以把非线性无吸收介质的二次谐波输出功率计算式应用到非线性吸收介质二次谐波输出功率计算式中去. 关键词: 非线性 倍频 二次谐波功率  相似文献   
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