将铂(Ⅱ)-四(4-羧基苯基)卟啉组装到光捕获金属有机框架中增强可见光驱动的产氢效能

氢气析出反应的分子催化剂因能够将其整合到用于光催化水分解的光捕集复合物中而受到广泛关注.研究者期望通过构建吸光网络,提高分子催化剂的光催化产氢效能.本文报道了以[(TCPP)PtⅡ][TCPP=meso-四(4-羧基苯基)卟啉]络合物作为光催化产氢的分子催化剂.采用氯冉酸(CA)作为电子牺牲剂可以很好地稳定光催化剂,使...     

Theoretical Analysis and New Formulae for Half-Lives of Proton Emission

The proton radioactivity hMf-lives of spherical proton emitters are calculated by the cluster model with the con- tribution of a centrifugal potential barrier considered separately. The results are compared with the experimental data and other theoretical data, and good agreement is found for most nuclei. In addition, two formulae are pro- posed for the proton decay half-life of spherical proton emitters through the least squares fit to the experimental data available, and could reproduce the experimental half-lives successfully.     

Half-Lives for Alpha Radioactivity of Elements with 104 ≤ Z ≤ 120 within Unified Fission Model

α decay half-lives are calculated using the Qα values obtained by Semi-empirical Shell Model in the framework of the Unified Fission Model (UFM) with the Coulomb repulsion, nuclear attraction due to proximity potential, and rotational energy due to angular momentum transfer of α particle. In addition, the calculated and experimental half-lives of 425 nuclei are compared to check the validity of the model applied on α decay. The calculated half-lives of α decay are in good agreement with the experimental data. Finally, some usefulpredications on the α decay half-lives are provided for future experiments.