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分别采用6-31G*,6-31G?*基组对线性ArCN分子的X2∑+,A2∏i,B2∑+,C2∏i,D2∑+和E2∏r 6个电子态进行了从头计算法开壳自旋限制Hartree-Fock(ROHF)计算。计算结果表明线性ArCN分子的电子态具有典型的准分子结构,从而可以肯定CN与稀有气体原子Rg(Ar,Kr,Xe)能够形成自由基准分子。对X2∑+,A2∏i的自旋非限制Hartree-Fock(UHF)计算证实较大的自旋污染不影响势能曲线的形状。
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A method for generating multi-wavelength light source is theoretically investigated by optical parametric oscillation (OPO) in aperiodic optical superlattice (AOS). The effects of domain errors caused by the room-temperature electric poling process are checked. The relationship between the linewidth and the block length is also discussed. 相似文献
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The enhancement of two order-of-magnitudes is observed in surface-enhanced Raman spectroscopy (SERS) of gases (CO, C2H2, C2H4, etc) adsorbed on nitric acid-roughened metal foil. In addition, some Raman lines of gases adsorbed on these active substrates show larger frequency shifts and linewidth broadening, compared with the Raman spectroscopy of free gases. Using the two-oscillator electromagnetic model, we explain this phenomenon. It is related to the large non-regular particles on the active substrate we prepared. It is found that the parameters of the surface-plasmon dispersion, the distance of molecules from the surface and the radius of particles play crucial roles on the relative large Raman shifts. 相似文献
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Theoretical study of quasi-phase-matching fourth harmonic generation in periodically poled lithium tantalate 总被引:1,自引:0,他引:1
The direct fourth harmonic generation (FHG) is theoretically demonstrated based on quasi-phase-matching (QPM) configuration in periodically poled lithium tantalate (PPLT). The wavelength dependence of the period of FHG QPM gratings is calculated. Bandwidths of fundamental wavelength, temperature, and incident angle are also studied. A very wide bandwidth, as large as 119.5 nm, of fundamental wavelength near 3699 nm is found with the QPM period of 9.442 μm and the crystal length of 1 cm. 相似文献
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Optimized Second Harmonic Generation of Femtosecond Pulse by Phase-Blanking Effect in Aperiodically Optical Superlattice 下载免费PDF全文
In order to minimize the effect of the unconsidered frequency components on the generated compression pulse, the phasing-blanking effect is taken into account of designing the one~dimensionai aperiodic domain reversal structure. Hierarchic genetic algorithm for the design of a domain reversal grating to modulate the spectrum and phase of the generated SH pulse simultaneously are presented. Our simulation shows that the quality of an output pulse is fairly improved. 相似文献
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15波长输出的布里渊掺铒光纤激光器 总被引:8,自引:3,他引:5
多波长布里渊掺铒光纤激光器是一种新型的多波长光纤激光器,其原理是利用受激布里渊增益和掺铒光纤的线性增益,可以在常温下得到波长间隔约为0.08nm(~10GHz)的多波长输出。报道的布里渊掺铒光纤激光器,在布里渊抽运功率为1.7mW、980nm抽运功率为300mW的情况下得到稳定的15个波长(间隔~10GHz)的输出,这种激光器用作光传感器、光谱分析仪以及密集波分复用系统的光源。实验发现,输出波长的个数随着980nm抽运功率的增大而增加。另外,布里渊掺铒光纤激光器的信号功率主要来自于掺铒光纤的增益,而布里渊增益对它的影响不大。 相似文献
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宽带准连续光纤激光在周期极化铌酸锂中倍频特性的研究 总被引:1,自引:2,他引:1
双包层光纤激光器和非线性光学材料(如周期性极化的铌酸锂晶体,PPLN)相结合,开辟了实用性非线性光学器件的一个新领域。研究了准相位匹配周期性极化反转铌酸锂晶体对宽带准连续光纤激光倍频的温度特性和频谱特性。在理论上,从准相位匹配相位失配关系出发,推导了晶体温度与抽运源中心波长的关系以及温度响应带宽,并和已报道实验结果进行了比较,二者符合得很好。此外,还推导了倍频周期极化铌酸锂晶体对抽运基频光源的响应谱线带宽。在实验上,采用长度20mm,极化周期6.5μm,厚度0.5mm的周期极化铌酸锂晶体光纤激光器准连续宽带输出进行了倍频,获得了在不同控制温度下的倍频光光谱,并对此进行了详细分析。 相似文献