钛柱撑蒙脱石去除亚甲基蓝的性能研究

采用溶胶-凝胶法,以钙基蒙脱石(Ca-MMT)作基质材料、钛酸四丁酯为钛源,制备了钛柱撑蒙脱石(Ti-MMT).采用XRD、FTIR、SEM、TEM和UV-vis等手段表征了Ti-MMT样品的结构、形貌和化学组成;将所制Ti-MMT用于吸附和协同光催化去除水体中有机污染物亚甲基蓝(MB);考察了Ti-MMT对MB的脱除性能.结果表明:聚合羟基阳离子Ti4+成功柱撑进入蒙脱石(MMT)层间,层间的 TiO2主要以锐钛矿晶相存在,柱撑过程改变了 MMT的形貌,使Ca-MMT的光吸收带边发生一定的红移,拓宽了Ca-MMT的光响应范围,提高了Ca-MMT的响应波长;在去除MB的实验中,Ti-MMT表现出对MB较佳的去除效果,动力学研究表明去除过程受到时间、初始质量浓度及pH的直接影响,去除率随时间、初始质量浓度和pH的增加而增加;暗吸附30 min,光照180 min,对于50 mg/L的MB溶液投加5g/L的Ti-MMT,MB去除率可达95.42;.     

Exact Solutions of the Two-Dimensional Cubic-Quintic Nonlinear Schrdinger Equation with Spatially Modulated Nonlinearities

Applying the similarity transformation,we construct the exact vortex solutions for topological charge S ≥ 1 and the approximate fundamental soliton solutions for S = 0 of the two-dimensional cubic-quintic nonlinear Schrdinger equation with spatially modulated nonlinearities and harmonic potential.The linear stability analysis and numerical simulation are used to exam the stability of these solutions.In different profiles of cubic-quintic nonlinearities,some stable solutions for S ≥ 0 and the lowest radial quantum number n = 1 are found.However,the solutions for n ≥ 2 are all unstable.