FREQUENCY-MODULATION OPTICAL-OPTICAL TRIPLE-RESONANCE OPTICAL HETERODYNE SPECTROSCOPY

We propose new frequency-modulation optical-optical triple-resonance (FM-OOTR) op-tical heterodyne spectroscopy, which can eliminate the Doppler-background in the recently developed optical-optical triple-resonance (OOTR) spectroscopy and provide improved reso-lution and sensitivity. Theoretical considerations and line shape calculations are presented. The potential applications of FM-OOTR technique to laser frequency stabilization with sig-nificant advantages can be expected.     

偏振调制双光子光谱理论计算

本文从密度矩阵运动方程出发,推导出当各种不同偏振调制激光场与三能级粒子系统相互作用时,同核双原子分(具近共振中间能波)单重电子态之间的双光子跃迁所产生的荧光信号强度和线型.对比偏振调制的与光子强调制的信号强度和线型时,表明:偏振调制双光子光谱(PMTPS)不仅能消除由吸收同一光束的同向双光子所产生的多普勒加宽背景,极大地提高光谱分辨率;而且不同电子态之间跃迁的O、P、Q、R、S支谱线强度与激光偏振状态有关,可借以标识分子的高激发电子终态和转动能级,有选择地简化复杂的分子光谱.可以预期,PMTPS是研究分子光谱和高分辨率激光光谱极有用的一种技术.     

SQUEEZED COHERENT THERMAL STATE AND ITS PHOTON NUMBER DISTRIBUTION

The squeezed coherent thermal state is considered. Its various coherent representations, including Q-,P-and Bargmann representations are introduced. The analytic formula for the photon number distribution of such a quantum state is obtained directly from the Bargmann representation. The effects of the squeezing and the thermal noise on the photon distribution are discussed.     

双光子共振相互作用的调频外差光谱特征

计算了以5种不同方式作频率调制时,反向传输激光场与量子系统在双光子共振四波混频相互作用过程中的光外差探测光谱。文中建议的调制方式具有新奇的光谱特征,它们甚至在计及二级边带作用时也成立,该光谱技术有重要的潜在应用前景。     

偏振三光子跃迁讯号的理论计算

本文从密度矩阵运动方程出发,对四能级阶跃型及折迭型能级结构的分子系综与不同性质偏振激光场作用时,可能发生的五种近共振增强三光子电子跃迁分别作了具体推导,获得了以第三跃迁为探测跃迁时的实验讯号强度及光谱特征解析式。通过与三能级系统作比较,发现其线型因子、谱线强度因子均有不同程度的增大,使讯号相对强度有数量级的提高。最后还讨论了所得讯号在分子光谱分析中的应用前景。 关键词：     

STUDY OF THE DOPPLER-FREE OPTICAL-OPTICAL TRIPLE-RESONANCE(DF-OOTR) SPECTROSCOPY AND ITS LINESHAPES

The Doppler-free optical-optical triple-resonance(DF-OOTR) spectroscopy and its line-shapes have been studied in detail theoretically and experimentally. The line center, linewidth and lineshape of an isolated DF-OOTR spectra component have been derived by using density matrix motion equation describing the interaction of a three-level system with three optical fields. The variations of the lineshape symmetry, the relative position and the strength of the Doppler-free Lorentzian dip to its background are comparable to the experimental traces varying with the relative intensities of the two mutual-saturating probe laser beams, as well as with the detuning of the first pumping laser from the intermediate level. The DF-OOTR technique shows a distinguished advantage especially in the labeling of the transitions and in the determination of absolute position of the upper level affected by perturbation shift, as these happened often in the dense molecular highly excited states.     

钠分子里德堡能级的无多普勒加宽光光三共振光谱以及能级宽度和谱线位移

首次报道了钠分子一系列里德堡能级的无多普勒加宽光光三共振（ＤＦ－ＯＯＴＲ）激发荧光光谱，测量了其谱线宽度和其谱线位置随温度、外加气体压力的变化情况。结果表明，钠分子里德堡能级（ｎ＝５～８）的自然宽度（含均匀加宽）在６０～１３０ＭＨｚ之间，其大小主要与主量子数ｎ有关。随钠原子浓度增大（温度升高），或外加Ａｒ气压力增大时，钢分子各个里德堡能级谱线均出现红移，数量在１００ＭＨｚ／τ之内，但位移速率大小不一。