Amidoalkylation of mercaptans with glyoxylic acid derivatives

The synthesis of α-alkyl mercaptohippuric acid (3a–d), N-benzyloxycarbonyl-α-methylthioglycine (3e) and their methyl esters (5a–d) by the amido-alkylation of mercaptans with α-hydroxyhippuric acid (2a), α-hydroxy-N-benzyloxycarbonylglycine (2b) and their methoxymethyl ester derivatives 4a and 4b is described. Oxidation with m-chloroperbenzoic acid afforded the corresponding sulfoxides and sulfones and treatment with N-bromosuccinimide in methanol or chlorine in carbon tetrachloride solution exchanged the sulfur containing side chain for a methoxy or a chloro group respectively. (4a, 8).     

Photon-deuteron diffractive scattering

One expects a similarity of the energy dependence of the difference _tot(*p)– _tot(*n) for virtual (deep inelastic scatteringQ ²m ²) and real (Q ²=0) photons. Previous analysis of D structure functions with allowence for nuclear shadowing (NS) in the deuteron has led to conclusion that _tot(*p)– _tot(*n)<0>x<0.015. the=" early=" evidence=" from=" the=" real=" photoproduction=" data="> _tot(p)– _tot(n)<0. we=" critically=" reexamine=" determinations=" of=" the="> _tot(p)– _tot(n), using more accurate calculations of NS correction to _tot(D), and discuss a possibility of _tot(n) _tot(p) at moderately high energies.     

Why breakup of photons and pions into forward dijets is so different: Predictions from nonlinear nuclear <Emphasis Type="Italic">k</Emphasis><Subscript>⊥</Subscript> factorization

Based on an approach to non-Abelian propagation of color dipoles in a nuclear medium, we formulate a nonlinear k_⊥ factorization for the breakup of photons and pions into forward hard dijets in terms of the collective Weizsäcker-Williams glue of nuclei. We find quite distinct practical consequences of nonlinear nuclear k_⊥ factorization for interactions of pointlike photons and nonpointlike pions. In the former case, the large transverse momentum p_⊥ of jets comes from the intrinsic momentum of quarks and antiquarks in the photon, and nuclear effects manifest themselves as an azimuthal decorrelation with an acoplanarity momentum of the order of the nuclear saturation momentum Q _A . In the breakup of pions off free nucleons to the leading order in pQCD, the spectator parton has a small transverse momentum and the hard dijet cross section is suppressed. In the breakup of pions off heavy nuclei, the forward hard jets are predicted to be entirely decorrelated. We comment on the sensitivity of the pionic dijet cross section to the pion distribution amplitude. The predicted distinction between the breakup of photons and pions can be tested by the sphericity and thrust analysis of the forward hadronic system in the COMPASS experiment at CERN.