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排序方式: 共有311条查询结果,搜索用时 15 毫秒
1.
Journal of Structural Chemistry - Atomic and electronic structures of cyclic organosilicon compound 9,9,10,10-tetraethynyl-9,10-dihydrodisilaanthracene are studied by the density functional theory.... 相似文献
2.
E. S. Zhukova A. S. Prokhorov I. E. Spektor V. A. Karavanskiĭ N. N. Mel’nik T. N. Zavaritskaya B. P. Gorshunov 《Physics of the Solid State》2007,49(12):2242-2250
The dielectric response (conductivity and permittivity) spectra of a series of nanoporous silicon samples prepared by anodization of low-resistivity single-crystal silicon are measured, for the first time, using terahertz and IR spectroscopy in the frequency range 7–4000 cm?1 at room temperature. The spectra obtained are analyzed in terms of the effective medium theory with a size-dependent dielectric response function of nanoinclusions and averaged dielectric characteristics of the surrounding medium. The geometric and dielectric characteristics of silicon nanoinclusions are determined. The dielectric properties of inclusions are found to be affected by nanosize effects, namely, carrier scattering at crystallite boundaries and a broadening of the band gap due to quantum confinement. The spectra of the samples prepared by adding iodine to the electrolyte exhibit a resonance at frequencies of 150–300 cm?1. The nature of the resonance can be associated with the presence of chemisorbed iodine on the surface of porous silicon. Possible mechanisms responsible for the changes in broadband conductivity and permittivity spectra of single-crystal silicon upon transformation into a nanoporous structure are discussed. 相似文献
3.
4.
Rastislav Varga Arcady Zhukov Michail Ipatov Juan Maria Blanco Julian Gonzalez Valentina Zhukova Pavol Vojtanik 《Journal of magnetism and magnetic materials》2006
The effect of the glass coating on the single domain wall potential in amorphous glass-coated Fe-based microwire has been studied by the switching field distribution technique. The thermoactivated mechanism model is used to describe the thermally activated switching through the complex energy barrier in amorphous FeSiB microwires. Glass removal leads to the increase of the probability of the thermally activated switching pointing to the decrease of the energy barrier. 相似文献
5.
G. Z. Zhukova 《Ukrainian Mathematical Journal》1990,42(10):1262-1266
Solutions with asymptotics in integral and fractional powers of the parameter ? are constructed for the vector differential equation $$\varepsilon ^h \dot X = A(t,\varepsilon ) X + \varepsilon ^{\alpha _1 } p(t,\varepsilon ) \exp \left( {\varepsilon ^{ - h} \int\limits_0^t {\lambda (\tau )d\tau } } \right)$$ in the case of resonance and multiple spectrum of the limit matrix. $$\varepsilon ^h \dot X = A(t,\varepsilon ) X + \varepsilon ^{\alpha _1 } p(t,\varepsilon ) \exp \left( {\varepsilon ^{ - h} \int\limits_0^t {\lambda (\tau )d\tau } } \right)$$ 相似文献
6.
A. V. Tvardovskii A. A. Fomkin Yu. I. Tarasevich A. I. Zhukova 《Russian Chemical Bulletin》1995,44(8):1419-1421
The hysteresis of sorptive deformation of sorbents has been studied for the first time. Based on the results obtained, it is assumed that the deformation of sorbents could be the universal reason for the sorptive hysteresis.For Part 1, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1477–1479, August, 1995. 相似文献
7.
Tarasevich Yu. I. Bondarenko S. V. Zhukova A. I. 《Theoretical and Experimental Chemistry》2004,40(2):125-129
We have used gas chromatography to study the interaction of water and methanol molecules with active hydrophilic centers on the surface of thermally expanded graphite and graphitized thermal carbon black. We have determined the concentration of carboxyl and phenol hydroxyl groups on the surface of the sorbents and the heats of adsorption for adsorption of the studied substances on these groups. We have shown that water molecules are adsorbed as clusters on the hydrophilic centers of the studied sorbents at very low relative pressures, with n = 2 molecules in the cluster. 相似文献
8.
The gas-chromatographic method is used to study the interaction of water and methanol molecules with active hydrophilic centres
existing at the surface of thermally exfoliated graphite and graphitized thermal carbon black. The concentration of carboxyl
and phenol hydroxyl groups at the surface of these sorbents is determined, and heats of adsorption of the studied molecules
are shown to be
and 28−25 kJ/mol, respectively. It is also shown that adsorption of water at the hydrophilic centres at lowest relative pressure
values takes place with formation of clusters consisting of n = 2 water molecules. 相似文献
9.
V. A. Mamedov N. A. Zhukova T. N. Beschastnova Ya. A. Levin A. T. Gubaidullin I. A. Litvinov 《Russian Chemical Bulletin》2007,56(11):2308-2314
The condensation of methyl phenylchloropyruvate with 1-phenyl-3-(2-pyridyl)thiourea and its 3-and 4-picolyl homologs affords
the corresponding 4-hydroxythiazolidines, which react with o-phenylenediamine to give one of two possible thiazolo[3,4-a]quinoxalines containing the pyridyl-or picolylimine substituents at position 1. 3a-Hydroxy-3-phenylimino-1-(2-pyridyl)thiazolo[3,4-a]quinoxalin-4-(3H,5H)-one, which is a covalent hydrate of the final product, was isolated as an intermediate in this reaction. 相似文献
10.
Kashparova V. P. Kagan E. Sh. Kashparov I. S. Zhukova I. Yu. 《Russian Journal of Applied Chemistry》2002,75(4):667-668
Diazotization of 4-amino-2,2,6,6-tetramethylpiperidine in acetic or sulfuric acid affords 2,2,6,6- tetramethyl-1,2,3,6-tetrahydropyridine in high yield. Under the same conditions, the corresponding nitroxyl radical transforms into 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl. 相似文献