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The technique of Brownian dynamics is used to model the electrophoretic mobility of spherical and rod-like particles in a three-dimensional cubic gel lattice. In addition to excluded volume interactions between the migrating particle and the gel, direct interactions are also included. The methodology is first applied to spherical particles in the absence of direct interactions and the resulting mobilities are shown to agree with independent studies. The methodology is then applied to rod-like models of short duplex DNA fragments 10-50 base pairs in length. In the absence of direct interactions between gel and DNA, calculated mobilities show a much weaker dependence on gel concentration than observed in experiments of DNA in Tris-acetate buffer and polyacrylamide gels. When an attractive interaction between gel and DNA of approximately -0.3 k(B)T per base pair at contact is included, good agreement between calculated and experimental mobilities is achieved. 相似文献
4.
Chengye Yuan Shusen Li Zhiyi Cheng 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):95-102
Abstract The mass spectra of 2-alkyl-2-oxo-1,3,2-dioxa-phosphorinane and-phosphepane showed that the ring opening was in competition with the cleavage of the P[sbnd]C bond. According to the fragmentation pathway, which was dependent on the structure of exocyclic substituents on phosphorus, the 2-alkyl-2-oxo-1,3,2-di-oxa-phosphorinanes can be classified in two categories. The main process in category A was the ring opening and/or C[sbnd]C bond cleavage. While in category B the cleavage of P[sbnd]C bond was predominant. However, for 2-alkyl-2-oxo-1,3,2-dioxa-phosphepane. no matter how the structure of 2-alkyl group was, the ring opening was a dominant process. 相似文献
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Xue Chen Kunchao Lu Donghai Lin Yan Li Shiyu Yin Zhiyi Zhang Meihua Tang Guosong Chen 《Electroanalysis》2021,33(2):473-482
Hierarchical porous tubular biochar (PTBC) was prepared by selectively removing lignin simply according to reverse the pyrolysis sequence of cellulose. The properties of the PTBC sample were characterized by XRD, SEM, TEM, Raman spectra, cyclic voltammetry and electrochemical impedance spectroscopy. The electrochemical performances of PTBC modified on the screen-printing electrode illustrated excellent detection of lead ions (lead (II)) in water with the linear range (0.5–120 μg/L) and the detection limit (0.02 μg/L) by in-situ bismuth film square wave anode stripping voltammetry. 相似文献
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Summaryof main observation and conclusion A new and intriguing methodology to access various O-difluoromethylation oxime compounds from CICF2H,TBN and indoles is developed under mild reaction conditions.This strategy can suppress N-difluoromethylation of indoles successfully,in which there are two different active species(:CF2and·NO)while indoles are unprotected,featuringsimple operation and radical involvement. 相似文献
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We demonstrate a harmonically pumped femtosecond optical parametric oscillator(OPO)laser using a frequency-doubled mode-locked Yb:KGW laser at a repetition rate of 75.5 MHz as the pump laser.Based on a bismuth borate nonlinear crystal,repetition rates up to 1.13 GHz are realized,which is 15 times that of the pump laser.The signal wavelength is tunable from 700 nm to 887 nm.The maximum power of the signal is 207 m W at the central wavelength of 750 nm and the shortest pulse duration is 117 fs at 780 nm.The beam quality(M^2 factor)in the horizontal and vertical directions of the output beam are 1.077 and 1.141,respectively. 相似文献
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本文研究了环状膦酸酯的合成方法,通过三种方法合成了十五个具有各种烷基结构的六元和七元环膦酸酯,并对这十五个化合物质谱作了分析和归纳,得出了一些有助于鉴定这类膦酸酯的质谱特征。 相似文献
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Interrogating fiber Bragg grating sensors by thermally scanning a demultiplexer based on arrayed waveguide gratings 总被引:2,自引:0,他引:2
We evaluate a wavelength interrogation technique based on an arrayed waveguide grating (AWG). Initial results show that the Bragg wavelength of fiber Bragg grating (FBG) sensors can be precisely interrogated by thermally scanning an AWG-based demultiplexer. The technique potentially offers a low-cost, compact, and high-performance solution for the interrogation of FBG distributed sensors and multisensor arrays. 相似文献
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Y. Paul Handa Zhiyi Zhang Jacques Roovers 《Journal of Polymer Science.Polymer Physics》2001,39(13):1505-1512
tert‐Butyl‐substituted poly(ether ether ketone) (tBuPEEK), which does not undergo crystallization with thermal annealing, crystallizes readily when treated with compressed CO2. The dissolved CO2 causes a reduction in the glass‐transition temperature of the polymer–gas system and enhances the chain mobility of the macromolecules, thereby bringing about crystallization. In the presence of CO2, crystallization is increasingly favored with increasing CO2 pressure and treatment temperature. The melting point of tBuPEEK crystals increases linearly with the CO2 pressure applied in the treatment, indicating an increase in the order and/or size of the crystals. The extent of crystallinity increases when small amounts of methanol or dichloromethane are used as a cosolute with CO2. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1505–1512, 2001 相似文献