全文获取类型
收费全文 | 728篇 |
免费 | 19篇 |
国内免费 | 6篇 |
专业分类
化学 | 509篇 |
晶体学 | 11篇 |
力学 | 40篇 |
数学 | 26篇 |
物理学 | 167篇 |
出版年
2023年 | 5篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2016年 | 5篇 |
2015年 | 14篇 |
2014年 | 21篇 |
2013年 | 38篇 |
2012年 | 33篇 |
2011年 | 30篇 |
2010年 | 22篇 |
2009年 | 27篇 |
2008年 | 41篇 |
2007年 | 29篇 |
2006年 | 39篇 |
2005年 | 44篇 |
2004年 | 33篇 |
2003年 | 37篇 |
2002年 | 28篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 16篇 |
1996年 | 16篇 |
1995年 | 9篇 |
1994年 | 6篇 |
1993年 | 15篇 |
1992年 | 14篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 10篇 |
1988年 | 13篇 |
1987年 | 16篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 8篇 |
1975年 | 8篇 |
1974年 | 7篇 |
1973年 | 3篇 |
1972年 | 3篇 |
排序方式: 共有753条查询结果,搜索用时 15 毫秒
1.
Minoru Koyama Dr. Takafumi Kawakami Dr. Takashi Okazoe Prof. Dr. Kyoko Nozaki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(46):10913-10917
Methacrylic esters, represented by methyl methacrylate (MMA), are widely used as commodity chemicals. Here, the one-pot synthesis of methacrylic esters from acetone, a haloform and alcohols in the presence of an organic base is described. Using DBU as the organic base for the reaction of acetone, chloroform and methanol in acetonitrile afforded MMA in 66 % yield. When the solvent was replaced by benzonitrile, the product MMA was successfully purified by distillation. Applicability of this process to various alcohols was also investigated to show ethyl, phenyl, CF3CH2, and n-C6F13CH2CH2 esters were obtained in moderate yields. The use of bromoform instead of chloroform resulted in the improvement of the yield, for example, methyl and n-C6F13CH2CH2 esters up to 81 and 70 %, respectively. The reaction with deuterated starting materials acetone-d6 and MeOH-d4, with DBU in acetonitrile afforded deuterated MMA (MMA-d8) in 70 % yield. 相似文献
2.
By optimizing pump power ratio between 1st order backward pump and 2nd order forward pump on discrete Raman amplifier, we demonstrated over 2dB noise figure improvement without excessive non-linearity degradation. 相似文献
3.
We present the spot size dependence of dielectric multilayer filters for use in dense WDM systems. We found large dependences of filter performances on the spot size and the incident angle of input light, which should be important for miniaturizing multi-channel add/drop filters. 相似文献
4.
5.
Takuya Hashimoto Koichi Kitazawa Masaaki Nakabayashi Tadashi Shiraishi Youichi Suemune Takakazu Yamamoto Hideomi Koinuma 《应用有机金属化学》1991,5(4):325-330
For low-temperature deposition of oxide films relating to Bi-Sr-Ca-Cu-O superconductors, photo-absorption and -decomposition properties were examined with respect to copper and alkaline-earth ß-diketonates. It was confirmed that all ß-diketonates examined were promising as source materials for photochemical vapour deposition (photo-CVD) using a low-pressure mercury lamp, in view of their large light absorption coefficients at wavelength 254 nm. The light irradiation was effective for the formation of highly crystalline oxide films at temperatures below 600 °C. By combining two sources, Ca2CuO3 and SrCuO2 films were prepared. Photo-CVD of c-axis oriented Bi2Sr2CuOx film was achieved by the irradiation of ternary sources of Bi(C6H5)3 and strontium and copper ß-diketonates at 500 °C. 相似文献
6.
H. Ohta M. Kimata K. Koyama Y. Oshima M. Motokawa H. Nishikawa K. Kikuchi I. Ikemoto 《International Journal of Infrared and Millimeter Waves》2005,26(11):1525-1530
We have developed a new magneto-optical measurement system using a rotational cavity system equipped with a millimeter vector
network analyzer and a 14 T solenoid type super conducting magnet. The measurement can be performed in the transmission configuration
down to 1.6 K. The results of the precise angular dependence measurement of quasi-one-dimensional organic conductor (DMET)2I3 using the new system are shown, and its Fermi surface will be discussed in connection with the previous reports. 相似文献
7.
8.
The first total synthesis of (+)?3-deoxyaphidicolin, a selective inhibitor of eukaryotic DNA polymerase α, has been completed efficiently and stereoselectively starting from 1-abietic acid. 相似文献
9.
[reaction: see text] Inclusion ability of thiacalix[4]arenetetrasulfonate (TCAS) toward water-miscible organic molecules such as alcohols, ketones, cyclic ethers, and so on was studied by salting-out of the inclusion complex. NMR spectra of the recovered precipitates showed size selectivity to include the guest molecules. X-ray crystallographic analyses of TCAS salts including acetone and 1,4-dioxane suggested that guests are retained with the aid of cation coordination and H-bonding. 相似文献
10.
Solvent extraction of alkali metal ions by batch and counter-current distribution methods was investigated with tetrathiocyanatodiamminechromate(III) and tetrathiocyanatodianilinechromate(III) as reagents and nitromethane and nitrobenzene as organic solvents. The distribution ratios of alkali metal ions in the various systems were measured. Cesium was readily extracted with the aniline compound and nitrobenzene. The separation of sodium from potassium in trace amounts was possible by the counter-current distribution method. 相似文献