Measured and Predicted Solubility Phase Diagrams of Quaternary Systems LiBr-NaBr-MgBr2-H2O and LiBr-KBr-MgBr2-H2O at 298.15 K

The stable phase equilibria of quaternary systems LiBr-NaBr-MgBr₂-H₂O and LiBr-KBr-MgBr₂-H₂O at 298.15 K were studied by both experimental measurement(isothermal solution saturation method) and theoretical prediction(Pitzer model). The solubilities of the saturated solution have been determined experimentally and two stable phase diagrams and relevant water diagrams of the two quaternary systems were obtained. Results show that quaternary system LiBr-NaBr-MgBr₂-H₂O is hydrate II type as NaBr and NaBr·2H₂O coexistence. Its phase diagram consists of only one invariant point, four univariant curves, and five crystallization fields. The quaternary system LiBr-KBr-MgBr₂-H₂O is a complex type as the double salt KBr·MgBr₂·6H₂O formed. In addition to this double salt, the three single salts LiBr·2H₂O, KBr and MgBr₂·6H₂O also crystallize. In this paper, the solubilities of phase equilibria in above quaternary systems were also calculated by the Pitzer's electrolyte solution model. All the needed parameters can be obtained from the literature or be fitted by experimental data. On the Basis of the experimental and calculated results, the phase diagram of the quaternary system was plotted for comparison. It shows that the calculation results are consistent with the experimental ones.     

Recent Progress on Nickel-Based Oxide/(Oxy)Hydroxide Electrocatalysts for the Oxygen Evolution Reaction

Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed.     

烟气中Hg的氧化机理的研究

本文对Ｈｇ与Ｃｌ２在烟气中的氧化反应进行了热力平衡计算和动力学计算。平衡计算的结果表明有ＣＩ元索存在时Ｈｇ的氧化率为１００％，而在相同的条件下动力学计算纺果为Ｈｇ的氧化率在２０％～８０％之间变化，与实验结果吻合。实际的氧化反应是一种超平衡状态，不能达到理想的平衡状态。因此应采用动力学与热力平衡分析相结合的方法研究Ｈｇ在烟气中的反应机理。同时，计算结果显示Ｃｌ含量对Ｈｇ的氧化率的影响很大．     

极谱法测定硫酸稀土复盐母液中的稀土总量

在pH9.0的NH3·H2O-(NH4)2SO4缓冲介质中,RE(Ⅲ)-TP的络合吸附波的波高与RE(Ⅲ)的浓度在0-10μg/mL间成线性。该方法的相对标准偏差2.23%,回收率99.51%-103.38%,用于硫酸稀土复盐母液中微量稀土总量测定,结果满意。     

三阶脉冲线性微分方程解的振动性与渐近性

给出引理解决了方程非振动解与其各阶导数的符号关系，并由此得到了若干判别准则，用于判别三阶线性脉冲微分方程解的振动性与渐近性，举例说明了准则的有效性。本文推广了相关文献的结果。     

双维位置灵敏CsI(Tl)探测器

描述了一种双维位置灵敏CsI(Tl)探测器.用3组分α源测量该探测器得到的位置分辨为0.81mm(FWHM),对于69MeV/u ³⁶Ar能量分辨为0.9％(FWHM).在RIBLL的ΔE-E粒子鉴别望远镜中常常作为E探测器.由于CsI(Tl)晶体对不同的粒子的能损-光输出的非线性,需要针对不同离子对CsI探测器作能量-光输出校正曲线.     

上市公司资本成本面板数据模型与实证分析

本文利用我国上市公司1997至2002年的有关财务数据,建立了我国上市公司资本成本面板数据模型,运用该模型分析了我国上市公司资本成本与财务杠杆、企业规模的关系.结果表明,财务杠杆的提升、企业规模的扩大将使资本成本下降.该结论对我国上市公司优化资本结构、提高企业价值具有一定的参考价值.     

形变谐振子相干态及其对SUq（3）的应用

该文讨论了形变诺振子相干态的一些有意义的性质，利用量子代数SUq（3）的形变谐振子实现，构造了SU3（q）在玻色、费米两种情况下的相干态．     

合浦珠母贝(Pinctada martensii,Dunker)珍珠囊体外预培育的初步研究

０．３％胰蛋白酶液（２５℃）消化外套膜组织的第５～１５ｍｉｎ时间段所收获的细胞产物中，表皮细胞具有最高的纯度和贴壁活性；细胞悬液的体外短期培养过程中小牛血清和珠母贝组织提取物对于细胞在体外的生长和在珠核表面的贴附具有促进作用．     

高功率横流CO2激光器脉冲预电离过程研究

本文给出了对高功率横流CO_2激光器脉冲预电离过程的理论和实验研究.表明了预电离过程中光电离的重要作用.实验结果表明,脉冲预电离可增大高功率横流CO_2.激光器的pd值(p为放电气压、d为放电间隔),增大放电区注入功率密度.对于提高此类型激光器的放电稳定性和输出激光功率是一种技术简单而有效的手段.