全文获取类型
收费全文 | 21991篇 |
免费 | 804篇 |
国内免费 | 783篇 |
专业分类
化学 | 12666篇 |
晶体学 | 191篇 |
力学 | 1650篇 |
综合类 | 81篇 |
数学 | 2985篇 |
物理学 | 6005篇 |
出版年
2022年 | 255篇 |
2021年 | 340篇 |
2020年 | 396篇 |
2019年 | 458篇 |
2018年 | 492篇 |
2017年 | 503篇 |
2016年 | 644篇 |
2015年 | 437篇 |
2014年 | 611篇 |
2013年 | 827篇 |
2012年 | 852篇 |
2011年 | 850篇 |
2010年 | 786篇 |
2009年 | 786篇 |
2008年 | 777篇 |
2007年 | 769篇 |
2006年 | 618篇 |
2005年 | 538篇 |
2004年 | 468篇 |
2003年 | 501篇 |
2002年 | 565篇 |
2001年 | 506篇 |
2000年 | 394篇 |
1999年 | 300篇 |
1998年 | 271篇 |
1997年 | 257篇 |
1996年 | 244篇 |
1993年 | 253篇 |
1992年 | 257篇 |
1991年 | 260篇 |
1990年 | 285篇 |
1989年 | 267篇 |
1985年 | 280篇 |
1984年 | 284篇 |
1983年 | 264篇 |
1982年 | 274篇 |
1980年 | 256篇 |
1979年 | 303篇 |
1978年 | 329篇 |
1977年 | 320篇 |
1976年 | 404篇 |
1975年 | 359篇 |
1974年 | 388篇 |
1973年 | 397篇 |
1972年 | 369篇 |
1971年 | 331篇 |
1970年 | 314篇 |
1969年 | 298篇 |
1968年 | 253篇 |
1967年 | 250篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
1.
Chuprin A. S. Belova S. A. Bugaenko M. G. Vologzhanina A. V. Loktev A. S. Voloshin Ya. Z. Buznik V. M. Dedov A. G. 《Kinetics and Catalysis》2022,63(1):108-116
Kinetics and Catalysis - A new ruthenium(II) cage complex with polar terminal groups in the apical substituents has been synthesized; the molecular design of the complex contributes to the... 相似文献
2.
Moroz Ya. A. Lozinskyy N. S. Lopanov A. N. Chebyshev K. A. 《Russian Journal of General Chemistry》2022,92(1):101-107
Russian Journal of General Chemistry - Tungstophosphatozincates with the Keggin anion structure Kt5[PW11O39Zn(H2O)]?nH2O, Kt = Rb+, Cs+, (CH3)4N+; (C2H5)4N+ were synthesized. Their... 相似文献
3.
Journal of Visualization - The increasing availability of spatiotemporal data provides unprecedented opportunities for understanding the structure of an urban area in terms of people’s... 相似文献
4.
Zhang Tinggui Xi Ya Fei Shao-Ming 《International Journal of Theoretical Physics》2021,60(8):2909-2915
We study the Bell nonlocality of high dimensional quantum systems based on quantum entanglement. A quantitative relationship between the maximal expectation value B of Bell operators and the quantum entanglement concurrence C is obtained for even dimension pure states, with the upper and lower bounds of B governed by C.
相似文献5.
6.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献
7.
8.
Dr. Wan‐Ling Liu Ni‐Shin Yang Ya‐Ting Chen Stephen Lirio Cheng‐You Wu Prof. Chia‐Her Lin Prof. Hsi‐Ya Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):115-119
A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors. 相似文献
9.
10.
Briana L. Simms Nan Ji Indika Chandrasiri Mohammad Farid Zia Chinwe S. Udemgba Ravinder Kaur Jared H. Delcamp Alex Flynt Chalet Tan Davita L. Watkins 《Journal of polymer science. Part A, Polymer chemistry》2021,59(19):2177-2192
Here, we demonstrate the applicability of self-assembling linear-dendritic block copolymers (LDBCs) and their nanoaggregates possessing varied surfaces as therapeutic nanocarriers. These LDBCs are comprised of a hydrophobic, linear polyester chemically coupled to a hydrophilic dendron polyamidoamine (PAMAM)—the latter of which acts as the surface of the self-assembled nanoaggregate in aqueous media. To better understand how surface charge density affects the overall operability of these nanomaterials, we modified the nanoaggregate surface to yield cationic (NH3+), neutral (OH), and anionic (COO−) surfaces. The effect of these modifications on the physicochemical properties (i.e., size, morphology, and surface charge density), colloidal stability, and cellular uptake mechanism of the polymeric nanocarrier were investigated. This comparative study demonstrates the viability of nanoaggregates formed from PDLLA-PAMAM LDBCs to serve as nanocarriers for applications in drug delivery. 相似文献