4.
The High Temperature Superconductors are characterized by a very anisotropical structure and by typical arrangements of Cu- and O-atoms within CuO
2-planes. In studying the electronic structure of these compounds there is a strong demand for high resolution valence band spectroscopy. Using an electron probe microanalyzer we study the X-ray emission of O-K
ga and Cu-L
emerging from polycrystalline YBa
2Cu
3O
7 and Tl
2Ba
2Ca
2Cu
3O
10. The O-K
emission band is analyzed using a chlinochlore crystal in (001) orientation (2d = 28.4 Å). For the Cu-L
emission band we use a beryl crystal in (10¯10) orientation (2d = 15.9 Å). Furthermore, orientation dependent X-ray emission spectroscopy of single-crystalline YBa
2Cu
3O
7 and Tl
2Ba
2Ca
1Cu
2O
8 specimens was performed. We present the partial O-K
spectra which represent the O-2p
( = x, y, z) electronic densities of states of the valence band and compare them with calculated data.
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