New Constructions of Disjoint Distinct Difference Sets

New constructions of regular disjoint distinct difference sets (DDDS) are presented. In particular, multiplicative and additive DDDS are considered.     

Digisorb 2600型物理吸附仪真空系统检漏、故障分析及对策

就Ｄｉｇｉｓｏｒｂ２６００型物理吸附仪的真空系统拟出了表格形式的基本检漏步骤，并在此基础上详细介绍了几例特殊真空故障的查找，分析及解决方法。     

催化动力学光度法测定痕量铜的研究

本研究了在氨水介质中铜（Ⅱ）催化过氧化氢氧化亮黄的褪色反应及其动力学条件，建立了一种超高灵敏、高选择性的测定环境试样中痕量铜的新方法，可测定０．００４～０．５μｇ／２５ｍＬ范围内的铜（Ⅱ）。     

Synthesis and properties of fluorous arenes and triaryl phosphorus compounds with branched fluoroalkyl moieties (“split pony tails”)

Most compounds designed for immobilization in fluorous media feature linear pony tails of the formula (CH₂)_m(CF₂)_n−1CF₃ [(CH₂)_mR_fn]. This paper presents a first-generation approach to compounds with branched or “split” pony tails of the formula (CH₂)_lCH[(CH₂)_mR_fn]₂. Allyl tri(n-butyl)tin is reacted twice with perfluorooctyl iodide (R_f8I; first, photochemical, 78-81%; second, thermal with radical initiator, 71%; 13-18 g scales) to give the secondary alkyl iodide ICH(CH₂R_f8)₂ (3). A subsequent Ni(Cl)₂(PPh₃)₂-catalyzed reaction with allyl tri(n-butyl)tin yields the branched alkene H₂CCHCH₂CH(CH₂R_f8)₂ (74%). A palladium-catalyzed Heck coupling with OP(p-C₆H₄Br)₃ gives the fluorous phosphine oxide OP(p-C₆H₄CHCHCH₂CH(CH₂R_f8)₂)₃ (84%), and Pd/C-catalyzed hydrogenation affords OP(p-C₆H₄(CH₂)₃CH(CH₂R_f8)₂)₃ (>99%). Reduction with SiHCl₃ gives P(p-C₆H₄(CH₂)₃CH(CH₂R_f8)₂)₃, which is protected as the air-stable borane adduct H₃B·P(p-C₆H₄(CH₂)₃CH(CH₂R_f8)₂)₃ (9, 64%). The CF₃C₆F₁₁/toluene partition coefficient of 9 is much higher than that of the analog with p-(CH₂)₃R_f8 groups (96.6:3.4 versus 37.3:62.7). The iodide 3 is unreactive towards PAr₃ at 175-250 °C. However, a CuBr-catalyzed reaction with C₆H₅MgBr gives C₆H₅CH(CH₂R_f8)₂, which also exhibits a high partition coefficient (97.9:2.1).     

二溴硝基偶氮氯膦催化动力学光度法测定痕量钴的研究

研究了在ｐＨ７．０磷酸盐介质中，钴催化Ｈ２Ｏ２氧化二溴硝基偶氮氯膦色反应，建立了催化光度法测定痕量钴的新方法，其检出限为５×１０＾－７ｇ／Ｌ，在０．５－３２μｇ／Ｌ范围内，钴与ｌｇ呈良好的关系。     

用WAXD和SAXS研究辐照聚酰胺1010结构

用ＷＡＸＤ和ＳＡＸＳ方法研究了聚酰胺１０１０的聚集态结构和结晶结构的辐射损伤过程和机理。辐射交联与裂解主要在非晶区和结晶表面或中间相发生；辐射损伤并从这里开始，随辐射剂量增大，非晶化逐渐向晶区伸展，有氢键的（０１０）晶面损伤几率高于（１００）晶面；辐射后效应导致新的交联与裂解生成，主要影响（０１０）晶面的形成与完善，使Ｌ１００及Ｗｃ变小。     

Filiform李代数Q_n的Hom-结构

首先证明了有限维Z-阶化李代数上的一个线性算子是Hom-结构的充分必要条件,即它的每个齐次分支也是Hom-结构.然后计算了特征零代数闭域上一类有限维Z-阶化Filiform李代数Qn的齐次Hom-结构,从而决定了Qn的所有Hom-结构.     

The Roles of Composition and Mesostructure of Cobalt-Based Spinel Catalysts in Oxygen Evolution Reactions

By using the crystalline precursor decomposition approach and direct co-precipitation the composition and mesostructure of cobalt-based spinels can be controlled. A systematic substitution of cobalt with redox-active iron and redox-inactive magnesium and aluminum in a cobalt spinel with anisotropic particle morphology with a preferred 111 surface termination is presented, resulting in a substitution series including Co₃O₄, MgCo₂O₄, Co₂FeO₄, Co₂AlO₄ and CoFe₂O₄. The role of redox pairs in the spinels is investigated in chemical water oxidation by using ceric ammonium nitrate (CAN test), electrochemical oxygen evolution reaction (OER) and H₂O₂ decomposition. Studying the effect of dominant surface termination, isotropic Co₃O₄ and CoFe₂O₄ catalysts with more or less spherical particles are compared to their anisotropic analogues. For CAN-test and OER, Co³⁺ plays the major role for high activity. In H₂O₂ decomposition, Co²⁺ reveals itself to be of major importance. Redox active cations in the structure enhance the catalytic activity in all reactions. A benefit of a predominant 111 surface termination depends on the cobalt oxidation state in the as-prepared catalysts and the investigated reaction.     

硫酸铵水溶液中丙烯酰胺与正离子单体的分散共聚研究

以硫酸铵(AS)水溶液为介质,进行丙烯酰胺(AM)与正离子单体甲基丙烯酰氧乙基三甲基氯化铵(DMC)分散共聚合,制备出水溶性聚合物分散体.研究了盐浓度、分散稳定剂浓度及其分子量、单体浓度等对反应体系及分散体粒径的影响.结果表明,随着分散稳定剂的用量从6%增加到14%,分散体的平均粒径先下降,后又随之上升.分散稳定剂分子量越大,所得分散体的平均粒径越小.硫酸铵和单体的浓度对平均粒径和粒子形态等影响显著,只有在较小的范围内才能制备出粒径较均一的正离子型水溶性聚合物分散体;硫酸铵浓度越大,生成聚合物分子量越低.     

Multipliers,covers, and stem extensions for Lie superalgebras

Suppose that the underlying field is of characteristic different from 2 and 3. We first prove that the so-called stem deformations of a free presentation of a finite-dimensional Lie superalgebra L exhaust all the maximal stem extensions of L; up to equivalence of extensions. Then we prove that multipliers and covers always exist for a Lie superalgebra and they are unique up to superalgebra isomorphisms. Finally, we describe the multipliers, covers, and maximal stem extensions of Heisenberg superalgebras and model filiform Lie superalgebras.