Singular numbers of the monodromy operator and sufficient conditions of the asymptotic stability of periodic system of differential equations with fixed delay

To obtain sufficient conditions for the asymptotic stability of linear periodic systems with fixed delay commensurable with the period of coefficients, singular numbers of the monodromy operator are used. To find these numbers, a self-adjoint boundary value problem for ordinary differential equations is applied. We study the motion of eigenvalues of this boundary value problem under a variation of a parameter. Obtaining sufficient conditions for the asymptotic stability is reduced to finding the bifurcation value of the parameter for the boundary value problem.     

Hydrolytic degradation and thermal stability of poly(naphthylimides) based on naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides)

The molecular properties of a number of new poly(naphthylimides) derived from naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides) have been studied. On the basis of hydrodynamic studies of the polymers at various stages of their thermal degradation in 96% H₂SO₄ and thermogravimetric measurements, the hydrolytic stability and thermooxidative resistance of the polymers have been compared. A correlation between the experimental data and the chemical structure of molecular chains has been established.     

A database for QA/QC in neutron activation analysis and gamma-ray spectrometry

A database has been designed for storing, retrieving and analyzing information about samples, experimental conditions and results obtained by neutron activation analysis and gamma-ray spectrometry. It has been created using Microsoft ACCESS 2002 under a Windows operating system. The database has been designed not only for saving information but also for quality assurance and quality control purposes. The structure of the relational design has been discussed and demonstrated with a new graphical feature of ACCESS 2002 called PIVOTCHART.     

The state of water in finely disperse hydrogels based on acrylamide and acrylic acid

The sorption capacity (upon water sorption from the bulk and vapor phases) of copolymeric hydrogels based on acrylamide and acrylic acid and the state of water in the hydrogels are studied. It is established that, for hydrogels prepared in the form of fine powders, pore sizes vary from 90 to 770 Å and the pore radius of hydrogels obtained as monolithic plates ranges from 27 to 200 Å. The acrylamide-to-acrylic acid unit ratio in the hydrogels is found to affect both the amount and the state of sorbed water. It is shown that the properties of water sorbed by hydrogels are governed by carboxyl group concentration rather than by the density of macromolecular chains.     

The influence of different reclamation agents and microorganisms on the aggregative stability of the colloidal fraction of meadow chernozem soil

The influence of various reclamation agents (montmorillonite, peat, activated sludge microbocenosis) on the stability of dispersions of the colloidal fraction of meadow chernozem soil is studied. It is established that biocolloids possess the strongest coagulating action in the aforementioned series of reclamation agents. It is shown that, in the process of microorganism growth involving glucose or polypeptides as a carbon source, exopolymers are synthesized that caused the coagulation of soil dispersions. Upon the growth of microorganisms on polypeptides (alkaligeneous metabolism), precipitates are formed that are denser and less peptized by water than those grown on glucose (acidogeneous metabolism). The addition of montmorillonite and peat intensifies the aggregation processes in soil-microbe heterodispersions. The inverse relationship between the content of an organic substance in a colloidal system and the stability of aggregates of soil colloids is revealed.     

Synthetic asymmetric lipid-like organosilanes for liposomal nanohybrid cerasomes toward potential medical applications

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Retention of alkali,alkaline earth and transition metals on an itaconic acid cation-exchange column. Eluent pH,ionic strength and temperature effects upon selectivity

The unusual selectivity of a methylene succinic (itaconic) acid modified polymeric column was investigated for the separation of alkali, alkaline earth, transition and heavy metals employing non-chelating inorganic eluents. The retention of selected metal ions on the column was investigated with simple HNO3 eluents and eluents prepared from KNO3 and KCl salts of varying pH (adjusted using HNO3). From these studies both the effect of eluent ionic strength and pH upon retention was evaluated for the itaconic acid stationary phase. The results obtained showed that despite slow exchange kinetics causing poor efficiencies, acceptable baseline separations of selected alkaline earth and transitions could be obtained under optimum conditions (the baseline separation of Mg(II), Ca(II), Mn(II), Cd(II), Zn(II) and Co(II) was possible using a 15 mM KNO3-5 mM KCl eluent at pH 3.50 in under 25 min). The use of an simple ionic strength step gradient was shown that facilitated the addition of Pb(II) to the above group of metal ions. An investigation into the effect of temperature upon peak efficiency and retention showed increased column temperature could be used to improve the resolution of closely eluting metal ions such as Ca(II) and Sr(II) and Ca(II) and Mn(II).     

Physicochemical properties of KOH-H<Subscript>2</Subscript>O<Subscript>2</Subscript>-H<Subscript>2</Subscript>O solutions

Density, viscosity, and surface tension of KOH-H₂O₂-H₂O solutions used to synthesize potassium superoxide in sprayer apparatus were studied with various relative amounts of the components in the temperature range 0–30°C. Analytical dependences of the above-mentioned quantities on temperature and solvent (water) content of the system were found.     

Synergistic extraction of Ce(III), Eu(III) and Tm(III) with a mixture of picrolonic acid and benzo-15-crown-5 in chloroform

Summary The synergistic mixture comprising picrolonic acid (HPA) and benzo-15-crown-5 (B15C5) in chloroform has been used for the extraction of Ce(III), Eu(III) and Tm(III) as representatives of lanthanide(III) ions from pH 1-2 solutions having ionic strength of 0.1 mol^. dm^-3(K⁺/H⁺, Cl^-). The composition of the extracted species has been determined as M(PA)₃^. nB15C5 where M is Ce, Eu and Tm and n=1 or 2. The influence of various anions and cations on the extraction of these ions has also been studied and only oxalate, cyanide and tartrate have some deleterious effect. The extraction equilibrium constants have been evaluated and discussed.