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排序方式: 共有152条查询结果,搜索用时 6 毫秒
1.
In this paper, we explore a weakness of a specific implementation of the analytic center cutting plane method applied to convex optimization problems, which may lead to weaker results than Kelley's cutting plane method. Improvements to the analytic center cutting plane method are suggested, and tested on some example problems. 相似文献
2.
The binding of a chiral quaternary ammonium ion to a cyclopeptide containing aromatic amino acid subunits is affected not only by the configuration of the cation but also by the configuration of the chiral counterion. Analysis of the binding equilibria shows that complex formation involves interaction of the whole ion pair with the host indicating that steric requirements of the anion influence complex geometry and stability. 相似文献
3.
4.
I. Azzouz J. Vial D. Thiébaut R. Haudebourg K. Danaie P. Sassiat J. Breviere 《Analytical and bioanalytical chemistry》2014,406(4):981-994
This review covers the recent development of stationary phases for chip-based gas chromatography (GC). Portable systems for rapid and reliable analysis are urgently needed. One way to achieve this is to miniaturize the entire analysis. Because the column is the central component of the GC system and determines the feasibility and quality of separation, this review focuses on stationary phases reported in the literature and their use in different fields during the last two decades, with emphasis on different methods for introducing the stationary phase into the GC column. 相似文献
5.
Frontispiece: NMR Fingerprints of the Drug‐like Natural‐Product Space Identify Iotrochotazine A: A Chemical Probe to Study Parkinson’s Disease 下载免费PDF全文
6.
Lagrangian relaxation is commonly used in combinatorial optimization to generate lower bounds for a minimization problem.
We study a modified Lagrangian relaxation which generates an optimal integer solution. We call it semi-Lagrangian relaxation
and illustrate its practical value by solving large-scale instances of the p-median problem.
This work was partially supported by the Fonds National Suisse de la Recherche Scientifique, grant 12-57093.99 and the Spanish
government, MCYT subsidy dpi2002-03330. 相似文献
7.
[reaction: see text] Tropolone, binol, and PCl(5) react in CH(2)Cl(2) at reflux to generate in one step a novel C(2)-symmetric hexacoordinated phosphorus cation of configuration controlled by the binol ligand. It behaves as an efficient NMR chiral shift agent for chiral anionic phosphate and borate anions. 相似文献
8.
As mentioned in International Conference on Harmonisation publications, linearity is a principal parameter in method validation. The most popular statistical tool used is linear least-squares regression. Contrary to what is still very often practiced, the correlation coefficient can in no way be considered as an indicator of the fit quality. There is in fact a test called the "lack-of-fit test" that enables one to answer the question, "Is the linear model adapted to the calibration curve?". However, this test can give erroneous conclusions when, at each level, several sources of variation for the response are influent. It often occurs in high-performance liquid chromatography, as shown in a following example, where the calibration curve is obtained from repeated injections of repeated dilutions of a parent solution. The lack-of-fit test rejected linearity, although it was at least questionable. In fact, the reason for a discrepancy of this kind lies in the presence of a double source of variation: injection and dilution. It is possible to overcome the problem by mixing a nested ANOVA with the standard least-square linear regression. As shown in an example, implementing this methodology for data processing allows one not only to carry out an unbiased lack-of-fit test but also give estimates of the dispersion introduced respectively by the preparation and the injection. 相似文献
9.
In this paper we propose a new class of games, the “strategically zero-sum games,” which are characterized by a special payoff structure. We show that for a large body of correlation schemes which includes the correlated strategies “à la Aumann”, strategically zero-sum games are exactly these games for which no completely mixed Nash equilibrium can be improved upon. 相似文献
10.
Laurent Drouet Alain Haurie Francesco Moresino Jean-Philippe Vial Marc Vielle Laurent Viguier 《Computational Management Science》2008,5(1-2):119-140
This paper proposes a computational game-theoretic model for the international negotiations that should take place at the
end of the period covered by the Kyoto protocol. These negotiations could lead to a self-enforcing agreement on a burden sharing
scheme given the necessary global emissions limit that will be imposed when the real extent of climate change is known. The
model assumes a non-cooperative behavior of the parties except for the fact that they will be collectively committed to reach
a target on total cumulative emissions by the year 2050. The concept of normalized equilibrium, introduced by J.B. Rosen for
concave games with coupled constraints, is used to characterize a family of dynamic equilibrium solutions in an m-player game where the agents are (groups of) countries and the payoffs are the welfare gains obtained from a Computable General
Equilibrium (CGE) model. The model deals with the uncertainty about climate sensitivity by computing an S-adapted equilibrium. These equilibria are computed using an oracle-based method permitting an implicit definition of the
payoffs to the different players, obtained through simulations performed with the global CGE model GEMINI-E3.
Partly supported by GICC (French Ministry of Ecology), TOCSIN (EU-044287) and the Swiss-NSF NCCR-Climate program of the Swiss
NSF. For helpful comments and discussions, we thank A. Bernard, P. Thalmann, and the anonymous referee. 相似文献