Selective volatilisation of trace metals from refractory solids into an inductively coupled plasma

Feasibility studies have been carried out on the use of a graphite electrode assembly for the introduction of U₃O₈ solid samples into a continuously running low-powered argon inductively coupled plasma for the assay of trace metallic elements in uranium. The d.c. arc carrier distillation procedure has been adopted here for the selective volatilisation of analyte elements from the refractory matrix by injecting analyte vapours into the central zone of the plasma using Scribner-Mullin electrodes covered with a graphite lid having a central opening. The experimental parameters have been optimised for the direct determination of B, Be, Cd, Co, Cr, Cu, Fe, K, Li, Mn, Na, Ni and Pb in U₃O₈ powders. The analytical performance of the method has been checked by analysing spiked U₃O₈ samples and is seen to be comparable to or better than d.c. arc methods for these analytes. These results indicate that the carrier-distillation-ICP combination shows promise as a sensitive and precise method for analysis of trace metallic elements in a refractory matrix with a complex spectrum.     

A new sensitive method for the spectrophotometric determination of molybdenum using 3-hydroxy-2-(2'-thienyl)-4H-chromen-4-one

A spectrophotometric method has been developed for the determination of Molybdenum (VI) using 3-hydroxy-2-(2'-thienyl)-4H-chromen-4-one as a complexing agent. The complex formed was dissolved in water in the presence of Triton X-100 and exhibits an absorption maximum at 410 nm. A large number of metal ions like Co(II), Ni(II), Mn(II), Cr(III), Zn(II), Cu(II), Hg(II), Bi(III), Fe(II), Fe(III), Zr(IV), V(V) can be tolerated at an appreciable concentrations. Molar absorptivity and Sandell's sensitivity of the method is 2.80 x 10(5) l mol-1cm-1 and 3.42 x 10(-4) micrograms cm-2, respectively. Beer's law is obeyed in the concentration range of 0.01-0.4 ppm Mo(VI). Aliquots containing 0.2 ppm of Mo(VI) give a mean absorbance of 0.56 with a relative standard deviation of 1.3%.     

Convex programming with single separable constraint and bounded variables

In this paper a minimization problem with convex objective function subject to a separable convex inequality constraint “≤” and bounded variables (box constraints) is considered. We propose an iterative algorithm for solving this problem based on line search and convergence of this algorithm is proved. At each iteration, a separable convex programming problem with the same constraint set is solved using Karush-Kuhn-Tucker conditions. Convex minimization problems subject to linear equality/ linear inequality “≥” constraint and bounds on the variables are also considered. Numerical illustration is included in support of theory.     

Capacitated transportation problem with bounds on RIM conditions

Motivated by dead-mileage problem assessed in terms of running empty buses from various depots to starting points, we consider a class of the capacitated transportation problems with bounds on total availabilities at sources and total destination requirements. It is often difficult to solve such problems and the present paper establishes their equivalence with a balanced capacitated transportation problem which can be easily solved by existing methods. Sometimes, total flow in transportation problem is also specified by some external decision maker because of budget/political consideration and optimal solution of such problem is of practical interest to the decision maker and has motivated us to discuss such problem. Various situations arising in unbalanced capacitated transportation problems have been discussed in the present paper as a particular case of original problem. In addition, we have discussed paradoxical situation in a balanced capacitated transportation problem and have obtained the paradoxical solution by solving one of the unbalanced problems. Numerical illustrations are included in support of theory.     

Power penalty in multitone radio-over-fibre system employing direct and external modulation with optical amplifiers

This paper presents a multitone RoF system employing a central station and a remote antenna station to transmit modulated microwave or mm-wave signals. Two configurations of the system employing direct and external modulation are presented. First, at the central station, the modulating signal is directly and externally modulated at 1549.5 and 1550.5 nm, respectively, and the combined signal is then transmitted using wireless mode. In the second configuration, the combined signal is transmitted over 20 km to the remote antenna station using optical fibre connectivity. At the remote antenna station, both channel wavelengths are separated and amplified with an EDFA and SOA and are detected. The demonstration results show that there exists a small power penalty between the direct and the external modulation. But a large power penalty is reported depending upon the choice of optical amplifier viz. EDFA or SOA. Better performance is recorded in later case. The results also show that power is being distributed among the operating frequency and sidebands adjacent to it after transmission over a fibre link.     

Physicochemical studies of (o-vanillin thiosemicarbazonato)-nickel(ii) chelate

Summary Five- and six-membered rings result from the chelation of nickel(II) by the dibasic tridentate Schiff base ligand, o-vanillin thiosemicarbazone(o-VTSC), a new chelate prepared and characterized. The structural results are discussed in the light of spectroscopic and other data.Presented at 29th ICCC, Lausanne, Switzerland, 1992.     

An alternate approach to solve two-level hierarchical time minimization transportation problem

This paper discusses a two-level hierarchical time minimization transportation problem, which is an important class of transportation problems arising in industries. This problem has been studied by various researchers (Sharma et al. in Eur J Oper Res 246:700–707, 2015; Sonia and Puri in TOP 12(2):301–330, 2004; Xie et al. in Comput Oper Res 86:124–139, 2017) and therefore, a number of polynomial time iterative algorithms are available to find its solution. All the existing algorithms, though efficient, have some shortcomings. The current study proposes an alternate solution algorithm for the problem that is more efficient in terms of computational time than the existing algorithms. The results justifying the underlying theory of the proposed algorithm are given. Further, a detailed comparison of the computational behaviour of all the algorithms for randomly generated instances of this problem, of different sizes validates the efficiency of the proposed algorithm.

     

Thioredoxin Reductase Activity may be More Important than GSH Level in Protecting Human Lens Epithelial Cells against UVA Light

This study compares the abilities of the glutathione (GSH) and thioredoxin (Trx) antioxidant systems in defending cultured human lens epithelial cells (LECs) against UVA light. Levels of GSH were depleted with either L‐buthionine‐(S,R)‐sulfoximine (BSO) or 1‐chloro‐2,4‐dinitrobenzene (CDNB). CDNB treatment also inhibited the activity of thioredoxin reductase (TrxR). Two levels of O₂, 3% and 20%, were employed during a 1 h exposure of the cells to 25 J cm^?2 of UVA radiation (338–400 nm wavelength, peak at 365 nm). Inhibition of TrxR activity by CDNB, combined with exposure to UVA light, produced a substantial loss of LECs and cell damage, with the effects being considerably more severe at 20% O₂ compared to 3%. In contrast, depletion of GSH by BSO, combined with exposure to UVA light, produced only a slight cell loss, with no apparent morphological effects. Catalase was highly sensitive to UVA‐induced inactivation, but was not essential for protection. Although UVA light presented a challenge for the lens epithelium, it was well tolerated under normal conditions. The results demonstrate an important role for TrxR activity in defending the lens epithelium against UVA light, possibly related to the ability of the Trx system to assist DNA synthesis following UVA‐induced cell damage.     

Carrier distillation-ICAP approach for trace metal assay of U3O8 powder

Summary A new approach for the trace metal assay of U₃O₈ powder has been described. The carrier distillation technique used for selective volatilization of trace metals in U₃O₈ with d.c. arc excitation is adapted for the release of analytes from the solid sample into the ICAP source by inductively heating the sample. The experimental parameters have been optimised for the direct determination of Cd, Cu, K, Na, Ni and Pb. The performance of the method developed here is tested for the precision and accuracy of determinations by analysing spiked U₃O₈ samples and NBL U₃O₈ reference standards (standard deviation 2–9%). The method appears promising to be developed as a highly precise analytical optical emission spectrometric method as it adds to the ingenuity of the carrier distillation method, the advantages of ICAP.

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Bestimmung von Metallspuren in U₃O₈-Pulver durch Trägerdestillation/ICAP

Zusammenfassung Das Trägerdestillationsverfahren zur selektiven Verdampfung von Spurenmetallen in U₃O₈ im Gleichstrombogen wurde mit induktiver Probeerhitzung für ICAP angepaßt. Die experimentellen Parameter wurden für die direkte Bestimmung von Cd, Cu, K, Na, Ni und Pb optimiert. Die Leistungsfähigkeit des Verfahrens wurde mit Hilfe von Proben mit bestimmten Zusätzen sowie mit zertifiziertem Referenzmaterial überprüft (Standardabweichung 2–9%). Durch die Verbindung der Vorteile von Trägerdestillation und ICAP bietet sich eine Methode von hoher Präzision.