Electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols in aprotic media.

The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed.     

Distance of convergence in measure on spaces of measurable functions

Positivity - In this paper we investigate the distance of convergence in measure whenever the measure is not $$\sigma $$ -finite and identify the topological coreflection of this approach structure...     

A-distributional summability in topological spaces

In the present paper we introduce a new concept of $A$ -distributional convergence in an arbitrary Hausdorff topological space which is equivalent to $A$ -statistical convergence for a degenerate distribution function. We investigate $A$ -distributional convergence as a summability method in an arbitrary Hausdorff topological space. We also study the summability of spliced sequences, in particular, for metric spaces and give the Bochner integral representation of $A$ -limits of the spliced sequences for Banach spaces.     

Effect of conjugated core building block dibenzo[a,c]phenazine unit on π‐conjugated electrochromic polymers: Red‐shifted absorption

A comparative investigation was undertaken for the electrosynthesis and electrochemical properties of three different electroactive polymers having a conjugated core building block, dibenzo[a,c]phenazine. A series of monomers has been synthesized as regards to thiophene based units; thiophene, 3‐hexyl thiophene, and 3,4‐ethylenedioxythiophene. The effects of different donor substituents on the polymers' electrochemical properties were examined by cyclic voltammetry. Introducing highly electron‐donating (ethylene dioxy) group to the monomer enables solubility while also lowering the oxidation potential. The planarity of the monomer unit enhances π‐stacking and consequently lowering the E_g from 2.4 eV (PHTP) to 1.7 (PTBP). Cyclic voltammetry and spectroelectrochemical measurements revealed that 2,7‐bis(4‐hexylthiophen‐2‐yl)dibenzo[a,c]phenazine (HTP) and 2,7‐bis(2,3‐dihydrothieno[3,4‐b][1,4]dioxin‐5‐yl)dibenzo[a,c]phenazine (TBP) possessed electrochromic behavior. The colorimetry analysis revealed that while PTBP have a color change from red to blue, PHTP has yellow color at neutral state and blue color at oxidized state. Hence the presence of the phenazine derivative as the acceptor unit causes a red shift in the polymers' absorption to have a blue color. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1714–1720, 2010     

Synthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behaviour of N,N'-(2-hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II)

N,N'-(2-Hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II) has been synthesized. The crystal structure has been determined by X-ray diffraction analysis, and linear optical characterization has been determined by UV-vis spectroscopy. It was found that the molecule under investigation has solvatochromic behaviour in the UV region, implying non-zero microscopic first hyperpolarizability. To reveal the microscopic nonlinear optical (NLO) properties, the static first hyperpolarizabilities (beta) and the electric dipole moments (mu) were evaluated by using the ab initio finite field (FF) method. According to the results of the FF calculations, the synthesized compound exhibits non-zero beta values, and it might have microscopic NLO behaviour.     

A Mach‐uniform preconditioner for incompressible and subsonic flows

In this study, a novel Mach‐uniform preconditioning method is developed for the solution of Euler equations at low subsonic and incompressible flow conditions. In contrast to the methods developed earlier in which the conservation of mass equation is preconditioned, in the present method, the conservation of energy equation is preconditioned, which enforces the divergence free constraint on the velocity field even at the limiting case of incompressible, zero Mach number flows. Despite most preconditioners, the proposed Mach‐uniform preconditioning method does not have a singularity point at zero Mach number. The preconditioned system of equations preserves the strong conservation form of Euler equations for compressible flows and recovers the artificial compressibility equations in the case of zero Mach number. A two‐dimensional Euler solver is developed for validation and performance evaluation of the present formulation for a wide range of Mach number flows. The validation cases studied show the convergence acceleration, stability, and accuracy of the present Mach‐uniform preconditioner in comparison to the non‐preconditioned compressible flow solutions. The convergence acceleration obtained with the present formulation is similar to those of the well‐known preconditioned system of equations for low subsonic flows and to those of the artificial compressibility method for incompressible flows. Copyright © 2013 John Wiley & Sons, Ltd.     

The Investigation of K Shell X-Ray Fluorescence Parameters for Sulphur Atom in Different 1 ,2,4-Triazoles

The measurement of K shell fluorescence parameters is an easy and practical way to investigate the electronic structures of elements in alloys,compounds or complexes.Since the number of valence electrons will change the screening effect,the measured parameters will be affected from the changes.In this study,the measured parameters were investigated for sulphur element according to the number of CH_2 groups.For the experimental measurements,the samples were excited by 59.5keVγrays from a 241 Am annular radioactive source.The emitted K X-rays from the samples were counted by ab Ultra-LEGe detector with a resolution of 150 eV at 5.9keV.     

Fragment‐Based Drug Design Facilitated by Protein‐Templated Click Chemistry: Fragment Linking and Optimization of Inhibitors of the Aspartic Protease Endothiapepsin

There is an urgent need for the development of efficient methodologies that accelerate drug discovery. We demonstrate that the strategic combination of fragment linking/optimization and protein‐templated click chemistry is an efficient and powerful method that accelerates the hit‐identification process for the aspartic protease endothiapepsin. The best binder, which inhibits endothiapepsin with an IC₅₀ value of 43 μm , represents the first example of triazole‐based inhibitors of endothiapepsin. Our strategy could find application on a whole range of drug targets.     

Spectroscopic studies and crystal structure of (E)-N′-(2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide

The structure of compound has also been examined cyrstallographically. It crystallizes in the monoclinic space group P2₁/c with a = 7.673(1), b = 16.251(2), c = 10.874(1) Å, β = 110.42(1)°, V = 1270.7(3) ų, D _x = 1.418 g cm^?3, R ₁ = 0.0349 and wR ₂ = 0.0935 [I > 2σ(I)], respectively. The title compound has been synthesized from the reaction of isonicotinohydrazide with 2-hydroxy-3-methoxybenzaldehyde. It has been characterized by using elemental analysis, MS, IR, ¹H NMR, ¹³C NMR and UV-Visible spectroscopic techniques.