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1.
Dermot Twomey 《Journal of heterocyclic chemistry》1986,23(2):615-620
3-Amino-10-aryl-2-arylimino-2,10-dihydrophenazines 1 undergo iodination in the 4-position of the phenazine nucleus yielding compounds which are identical with those obtained by oxidation of appropriate N-aryl-o-phenylenediamines with sodium iodate in the presence of acid. Bromination also takes place in this position but a second bromine atom enters the para-position of the arylimino moiety. The isomeric 10-aryl-3-aryl-amino-2,10-dihydro-2-iminophenazines 2 yield unstable iodo-derivatives but undergo bromination in the 1-and 4-position of the phenazine nucléus and in the ortho- and para-positions of the arylamino substituent. Preliminary chlorination experiments indicate that the substitution pattern is analogous to that established for the brominated products. The removal of bromine and iodine from the phenazine ring by reaction with a primary or secondary amine and their replacement by hydrogen rather than by the amine residue is also recorded. 相似文献
2.
3.
Ultrafine grain formation and coating mechanism arising from a blast coating process: A transmission electron microscopy analysis 下载免费PDF全文
Conor F. Dunne Kevin Roche Arne Janssen Xiangli Zhong M.G. Burke Barry Twomey Kenneth T. Stanton 《Surface and interface analysis : SIA》2017,49(12):1271-1278
This article examines the substrate/coating interface of a coating deposited onto mild steel and stainless steel substrates using an ambient temperature blast coating technique known as CoBlast. The process uses a coincident stream of an abrasive blast medium and coating medium particles to modify the substrate surface. The hypothesis for the high bond strength is that the abrasive medium roughens the surface while simultaneously disrupting the passivating oxide layer of the substrate, thereby exposing the reactive metal that then reacts with the coating medium. The aim of this study is to provide greater insight into the coating/substrate bonding mechanism by analysing the interface between a hydroxyapatite coating on both mild and stainless steel substrates. The coating adhesion was measured via a tensile test, and bond strengths of approximately 45 MPa were measured. The substrate/coating interface was examined using transmission electron microscopy and selected area diffraction. The analysis of the substrate/coating interface revealed the presence of ultrafine grains in both the coating and substrate at interface associated with deformation at the interface caused by particle impaction during deposition. The chemical reactivity resulting from the creation of these ultrafine grains is proposed to explain the high adhesive strength of CoBlast coatings. 相似文献
4.
C. E. Nwankire V. J. Law A. Nindrayog B. Twomey K. Niemi V. Milosavljević W. G. Graham D. P. Dowling 《Plasma Chemistry and Plasma Processing》2010,30(5):537-552
Plasma diagnostics of atmospheric plasmas is a key tool in helping to understand processing performance issues. This paper
presents an electrical, optical and thermographic imaging study of the PlasmaStream atmospheric plasma jet system. The system
was found to exhibit three operating modes; one constricted/localized plasma and two extended volume plasmas. At low power
and helium flows the plasma is localized at the electrodes and has the electrical properties of a corona/filamentary discharge
with electrical chaotic temporal structure. With increasing discharge power and helium flow the plasma expands into the volume
of the tube, becoming regular and homogeneous in appearance. Emission spectra show evidence of atomic oxygen, nitric oxide
and the hydroxyl radical production. Plasma activated gas temperature deduced from the rotational temperature of nitrogen
molecules was found to be of order of 400 K: whereas thermographic imaging of the quartz tube yielded surface temperatures
between 319 and 347 K. 相似文献
5.
Correlating mode shapes based on the modal assurance criterion 总被引:1,自引:0,他引:1
Correlation of mode shape results has always been a difficult task. The element by element comparison approach for a pair of vectors may lead to unreasonable results if the differences between some corresponding elements of the two vectors are large. The newly implemented alternative is to correlate a pair of vectors based on the MAC coefficient of a pair of test and analysis mode shapes. This implementation has resulted in better correlation. 相似文献
6.
R. M. Keyser W. Hensley T. R. Twomey D. L. Upp 《Journal of Radioanalytical and Nuclear Chemistry》2008,276(2):399-405
The necessity to monitor international commercial transportation for illicit nuclear materials resulted in the installation
of many nuclear radiation detection systems in Portal Monitors. To overcome the difficulty of innocent alarms due to a large
content of natural radioactivity or medical nuclides, Department of Homeland Security (DHS) supported the writing of the ANSI
N42.38 standard (Performance Criteria for Spectroscopy-Based Portal Monitors used for Homeland Security) to define the performance
of a portal monitor with nuclide identification capabilities, called a Spectroscopy Portal Monitor. To accomplish the necessary
performance, several different HPGe detector configurations were modeled using MCNP for the horizontal field of view (FOV)
and vertical linearity of response over the detection zone of 5 meters by 4.5 meters for 661 keV as representative of the
expected nuclides of interest. The configuration with the best result was built and tested. The results for the FOV as a function
of energy and the linearity show good agreement with the model and performance exceeding the requirements of N42.38. 相似文献
7.
8.
Kovaric BC Kokona B Schwab AD Twomey MA de Paula JC Fairman R 《Journal of the American Chemical Society》2006,128(13):4166-4167
The anionic porphyrin, meso-tetrakis(4-sulfonatophenyl)porphine, is found to tightly bind to an engineered 14-residue peptide, resulting in induced alpha-helix formation when mixed in aqueous solutions. The small porphyrin-peptide dissociation constant (2 muM) observed is related to the energetics of peptide helix formation coupled with electrostatic interactions between the anionic porphyrin and cationic residues in the coiled peptide. Analytical ultracentrifugation measurements indicate the porphyrin-peptide complexes dimerize, probably into a coiled coil, and weakly associate to form even higher order structures. 相似文献
9.
Coakley WT Bazou D Morgan J Foster GA Archer CW Powell K Borthwick KA Twomey C Bishop J 《Colloids and surfaces. B, Biointerfaces》2004,34(4):221-230
An ultrasonic standing wave trap [Langmuir 19 (2003) 3635] in which the morphologies of 2-D latex–microparticle aggregates, forming a pressure node plane, were characterised has been applied here to different cell suspensions with increasing order of specificity of cross-linking molecule, i.e. polylysine with chondrocytes; wheat germ agglutinin (WGA) with erythrocytes and surface receptors on neural cells. The outcome of initial cell–cell contact, i.e. whether the cells stuck at the point of contact (collision efficiency=1) or rolled around each other (collision efficiency=0), was monitored in situ by video-microscopy. The perimeter fractal dimensions (FD) of 2-D hexagonally symmetric, closely packed aggregates of control erythrocytes and chondrocytes were 1.16 and 1.18, respectively while those for the dendrititc aggregates formed initially by erythrocytes in 0.5 μg/ml WGA and chondrocytes in 20 μg/ml polylysine were 1.49 and 1.66. The FDs for control and molecularly cross-linked cells were typical of reaction-limited aggregation (RLA) and transport diffusion-limited aggregation (DLA), respectively. The FDs of the aggregates of cross-linked cells decreased with time to give more closely packed aggregates without clear hexagonal symmetry. Suspensions of neural cells formed dendritic aggregates. Spreading of inter-cellular membrane contact area occurred over 15 min for both erythrocyte and neural cell dendritic aggregates. The potential of the technique to characterise and control the progression of cell adhesion in suspension away from solid substrata is discussed. 相似文献
10.
B. Twomey A. Nindrayog K. Niemi W. G. Graham D. P. Dowling 《Plasma Chemistry and Plasma Processing》2011,31(1):139-156
The effect of varying process parameters on atmospheric plasma characteristics and properties of nanometre thick siloxane
coatings is investigated in a reel-to-reel deposition process. Varying plasma operation modes were observed with increasing
applied power for helium and helium/oxygen plasmas. The electrical and optical behaviour of the dielectric barrier discharge
were determined from current/voltage, emission spectroscopy and time resolved light emission measurements. As applied power
increased, multiple discharge events occurred, producing a uniform multi-peak pseudoglow discharge, resulting in an increase
in the discharge gas temperature. The effects of different operating modes on coating oxidation and growth rates were examined
by injecting hexamethyldisiloxane liquid precursor into the chamber under varying operating conditions. A quenching effect
on the plasma was observed, causing a decrease in plasma input power and emission intensity. Siloxane coatings deposited in
helium plasmas had a higher organic component and higher growth rates than those deposited in helium/oxygen plasmas. 相似文献