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LiClO4 catalyses the addition of CHCl2CO2H to olefins (cyclopentene cycloheptene and trans-cyclo-octene). Specific salt effects are discussed in terms of general acid catalysis. This mechanism is supported by the linear relation: log kex = ? αHo + β. Solvent isotope effects show a slow proton transfer. Eyring parameters are determined; ΔS* < 0. These experiments are consistent with a mechanism involving carbocation formation as the slow step. 相似文献
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A Raman study of K3H(SO4)2 as a function of temperature reveals that this compound undergoes a phase transition at Tc = 483 K prior to the decomposition at 508 K. 相似文献
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Mathieu Toumi 《Tetrahedron letters》2008,49(7):1175-1179
A practical synthesis of enantiopure substituted 3-hydroxy-pyrrolidines is reported. In four steps, starting from commercially available amino acids as chiral educts, this method allows for an efficient preparation of a variety of 3-hydroxy-pyrrolidines, as well as 3-hydroxy-piperidines and azepanes. Application of this methodology for a straightforward asymmetric synthesis of (−)-bulgecinine is also described. 相似文献
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Jamil Salhi James MacLaurin Salwa Toumi 《Stochastics An International Journal of Probability and Stochastic Processes》2018,90(1):49-60
In this paper we obtain a time-uniform propagation estimate for a system of interacting diffusion processes. Using a well defined metric function h , our result guarantees a time-uniform estimate for the convergence of a class of interacting stochastic differential equations towards their mean field limit, under conditions that ensure that the decay associated to the internal dynamics term dominates the interaction and noise terms. Our result should have diverse applications, particularly in neuroscience, and allows for models more elaborate than the one of Wilson and Cowan. In particular, the internal dynamics need not be that of linear decay. 相似文献
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Mathieu Toumi 《Tetrahedron letters》2010,51(47):6126-6128
A flexible six-step synthesis of potential cyclin-dependent kinase 2 (CDK2) inhibitors is reported. The synthesis involves the condensation between 3-chloro-4,4-dimethoxy-2-butanone and amidines, which provides acetyl-imidazoles and late stage palladium-catalyzed N-arylation to give the target pyrimidine derivatives. 相似文献
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A simple proof for a theorem of Luxemburg and Zaanen 总被引:1,自引:0,他引:1
Mohamed Ali Toumi 《Journal of Mathematical Analysis and Applications》2006,322(2):1231-1234
In this paper a simple proof for the following theorem, due to Luxemburg and Zaanen is given: an Archimedean vector lattice A is Dedekind σ-complete if and only if A has the principal projection property and A is uniformly complete. As an application, we give a new and short proof for the following version of Freudenthal's spectral theorem: let A be a uniformly complete vector lattice with the principal projection property and let 0<u∈A. For any element w in A such that 0?w?u there exists a sequence in A which satisfies , where each element sn is of the form , with real numbers α1,…,αk such that 0?αi?1 (i=1,…,k) and mutually disjoint components p1,…,pk of u. 相似文献
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An efficient, asymmetric synthesis of the cytotoxic natural product chaetominine was achieved in 14 steps. The strategy employs a copper(I)-mediated cyclization reaction as a key step to install the abc-tricyclic ring system, which was further elaborated by diastereoselective oxidation and reduction reactions. This effort also documents the first example of an oxidative rearrangement yielding to homochiral spirocyclic pyrrolidinyloxindoles. 相似文献
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Mohamed Ali Toumi 《Positivity》2016,20(2):337-342
In (Chil et al. Positivity, 2014), the authors claim to give a counterexample to the main result, about Wickstead’s question, in a recent paper of Toumi (see Theorem 3, When orthomorphisms are in the ideal center, Positivity 18(3):579–583, 2014). In this note we show that their example is consistent with the main result of Toumi and not a counterexample. 相似文献
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R. Trabelsi Shaik Babu H. Salhi N. Ouerfelli A. Toumi 《Physics and Chemistry of Liquids》2018,56(6):801-815
Excess molar volumes and refractive index, molar refraction deviations and isentropic compressibility changes in 1,4-dioxane + isobutyric acid binary mixtures (from 295.15 to 313.15) K. were calculated from experimental density, refractive index and sound velocity data presented in previous work. Here, these experimental values were used to test the applicability of the correlative reduced Redlich–Kister equation as well as their corresponding relative functions which are important to reduce the effect of temperature and, consequently, to reveal the effects of different types of interactions. The results of these observations have been interpreted in terms of structural effects of the solvents. The correlating equation recently proposed by Belda, has also been applied to the present system in order to assess the validity of this equation and to give thermodynamic limiting partial molar quantities interesting to evaluate solute–solvent interaction. 相似文献