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1.
Accelerated phase transformations and chemical reactions of metastable aluminas and kaolinite, doped with Cu2
+, Mn3
+/Mn2
+ and Fe3
+/Fe2
+ ions, are accompanied with accelerated decrease of surface area and pore volume values. The phenomena in metal ion doped
samples are explained by a catalytic mechanism, in terms of the Jahn-Teller effect.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
2.
Julien Ferrari Christian Terreaux Tibor Kurtn Attila Szikszai‐Kiss Sndor Antus JeromeD. Msonthi Kurt Hostettmann 《Helvetica chimica acta》2003,86(8):2768-2778
Investigation of the methanol extract of the roots of Gnidia involucrata (Thymelaeaceae) led to the isolation and characterization of two new 3,8″‐biflavonoid diastereoisomers, named GB‐4 ( 6a ) and GB‐4a ( 6b ). Their absolute configurations were determined in mixture by on‐line LC/CD measurements, which also allowed the revision of absolute configurations of the biflavanoids GB‐1 and GB‐2, and the configurational assignment of GB‐3. 相似文献
3.
We prove that RANDOM EDGE, the simplex algorithm that always chooses a random improving edge to proceed on, can take a mildly exponential number of steps in the model of abstract objective functions (introduced by Williamson Hoke [Completely unimodal numberings of a simple polytope, Discrete Appl. Math. 20 (1988) 69-81.] and by Kalai [A simple way to tell a simple polytope from its graph, J. Combin. Theory Ser. A 49(2) (1988) 381-383.] under different names). We define an abstract objective function on the n-dimensional cube for which the algorithm, started at a random vertex, needs at least exp(const·n1/3) steps with high probability. The best previous lower bound was quadratic. So in order for RANDOM EDGE to succeed in polynomial time, geometry must help. 相似文献
4.
We present a new verified optimization method to find regions for Hénon systems where the conditions of chaotic behaviour
hold. The present paper provides a methodology to verify chaos for certain mappings and regions. We discuss first how to check
the set theoretical conditions of a respective theorem in a reliable way by computer programs. Then we introduce optimization
problems that provide a model to locate chaotic regions. We prove the correctness of the underlying checking algorithms and
the optimization model. We have verified an earlier published chaotic region, and we also give new chaotic places located
by the new technique. 相似文献
5.
A two-dimensional framework (G,p) is
a graph G = (V,E) together with a map p: V → ℝ2. We view (G,p) as a straight line realization of G in ℝ2. Two realizations of G are equivalent if the corresponding edges in the two frameworks have the same length.
A pair of vertices {u,v} is globally linked in G if %and for all equivalent frameworks (G,q), the distance between the points
corresponding to u and v is the same
in all pairs of equivalent generic realizations of G. The graph G is globally rigid
if all of its pairs of vertices are globally linked. We extend the characterization of globally rigid graphs given by the
first two authors [13] by characterizing globally linked pairs in M-connected graphs, an important family of rigid graphs.
As a byproduct we simplify the proof of a result of Connelly [6] which is a key step in the characterization of globally rigid
graphs. We also determine the number of distinct realizations of an M-connected graph, each of which is equivalent to a given
generic realization. Bounds on this number for minimally rigid graphs were obtained by Borcea and Streinu in [3]. 相似文献
6.
Márton Kiss 《Acta Mathematica Hungarica》2006,110(3):253-259
Summary New results for the eigenvalue ratios of vibrating strings are presented partially in connection with previous results concerning
Schr?dinger operators. 相似文献
7.
A new preconditioned conjugate gradient (PCG)-based domain decomposition method is given for the solution of linear equations
arising in the finite element method applied to the elliptic Neumann problem. The novelty of the proposed method is in the
recommended preconditioner which is constructed by using cyclic matrix. The resulting preconditioned algorithms are well suited
to parallel computation. 相似文献
8.
Presented by R. Freese. 相似文献
9.
Dan Hefetz Michael Krivelevich Tibor Szabó 《Journal of Combinatorial Theory, Series A》2007,114(5):840-853
Let p and q be positive integers and let H be any hypergraph. In a (p,q,H) Avoider-Enforcer game two players, called Avoider and Enforcer, take turns selecting previously unclaimed vertices of H. Avoider selects p vertices per move and Enforcer selects q vertices per move. Avoider loses if he claims all the vertices of some hyperedge of H; otherwise Enforcer loses. We prove a sufficient condition for Avoider to win the (p,q,H) game. We then use this condition to show that Enforcer can win the (1,q) perfect matching game on K2n for every q?cn/logn for an appropriate constant c, and the (1,q) Hamilton cycle game on Kn for every q?cnloglogloglogn/lognlogloglogn for an appropriate constant c. We also determine exactly those values of q for which Enforcer can win the (1,q) connectivity game on Kn. This result is quite surprising as it substantially differs from its Maker-Breaker analog. Our method extends easily to improve a result of Lu [X. Lu, A note on biased and non-biased games, Discrete Appl. Math. 60 (1995) 285-291], regarding forcing an opponent to pack many pairwise edge disjoint spanning trees in his graph. 相似文献
10.
Tibor Cserháti 《Analytical and bioanalytical chemistry》1994,349(10-11):751-755
The interaction between 23 anticancer drugs and acetyl-β-cyclodextrin (acetyl-β-CD) was studied by reversed-phase charge-transfer thin-layer chromatography and the relative strength of interaction was calculated. Acetyl-β-CD formed inclusion complexes with 16 compounds, the complex always being more hydrophilic than the uncomplexed drug. The inclusion forming capacity of drugs differed considerably according to their chemical structure. The significant linear correlation between the hydrophobicity and specific hydrophobic surface area of anticancer drugs indicated that they can be considered as a homologous series of compounds, however, their chemical structures are highly different. 相似文献