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Maria V. Dinu Maria Cazacu Ecaterina S. Dr?gan 《Central European Journal of Chemistry》2013,11(2):248-258
The mechanical, rheological, thermal, and surface behaviors of three polyacrylamide/dextran (PAAm/Dx) semi-interpenetrating polymer network (semi-IPN) hydrogels, prepared at 22°C, 5°C and ?18°C, were investigated. The results were compared with those obtained on cross-linked PAAm without Dx synthesized under the same conditions. Hydrogels prepared at the lowest temperature were the most mechanically stable. The thermal stability of the semi-IPN hydrogels is slightly lower than the corresponding PAAm gels, irrespective of preparation temperature. The water vapor sorption capacity depended on the presence of Dx as well as preparation temperature, which determines the network morphology. 相似文献
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Dinu LC Muller HG Kazamias S Mullot G Augé F Balcou P Paul PM Kovacev M Breger P Agostini P 《Physical review letters》2003,91(6):063901
The absolute timing of the high-harmonic attosecond pulse train with respect to the generating IR pump cycle has been measured for the first time. The attosecond pulses occur 190+/-20 as after each pump field maxima (twice per optical cycle), in agreement with the "short" quantum path of the quasiclassical model of harmonic generation. 相似文献
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Ecaterina Stela Dragan Ionel Adrian Dinu Marcela Mihai 《Colloids and surfaces. A, Physicochemical and engineering aspects》2009,348(1-3):282-288
The interaction between strong polycations, which possess the ammonium quaternary centers attached to an acrylic macromolecular chain derived from poly(N,N-dimethylaminoethyl methacrylate) (polycations Qx), and divalent counterions was investigated by viscometry and turbidimetry. Conformational changes of polycations were influenced by the polycation charge density, counterion nature (SO42− or S2O82−) and concentration. The morphology of the polycation layers deposited onto silicon wafers has been studied by tapping mode atomic force microscopy, a strong influence of the polycation and ammonium persulfate concentration on the surface topography being observed. The optimum flocculation concentration of polycation decreased and the flocculation window increased in the presence of S2O82−, in the destabilization of kaolin model dispersion. Removal of Congo Red from aqueous solution by the complex system formed between polycations and divalent counterions was also investigated. The behavior of polycations Qx in separation processes was compared with that of one polycation containing 95 mol% N,N-dimethyl-2-hydroxypropyleneammonium chloride units in the backbone (PCA5). 相似文献
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Ecaterina Stela Dragan Maria Valentina Dinu Andrzej W. Trochimczuk 《European Polymer Journal》2009,45(7):2119-114
Cu(II), Co(II) and Ni(II) complexes of chelating resins (CR) bearing iminodiacetate (IDA) ligands were prepared. The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR). FT-IR spectra of the CR-metal complexes showed the characteristic bands of CR were still present but red-shifted after the metal complexation, and new bands assigned to Me-N bonds were observed. Thermal behavior of the metal-CR complexes supported the metal complexation, metal complexation leading to the decrease of the thermal stability of the CR, the lowest thermal stability being found when the highest amount of Cu(II) was loaded. Based on the EPR results and the thermal behavior of Cu(II)-CR complexes, the scheme for the complexation of Cu(II) on the CR was suggested. 相似文献
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Ecaterina Stela Dragan Maria Valentina Dinu Claudiu Augustin Ghiorghita Maria Marinela Lazar Florica Doroftei 《Molecules (Basel, Switzerland)》2021,26(22)
Curcumin (CCM) is a natural hydrophobic polyphenol known for its numerous applications in the food industry as a colorant or jelly stabilizer, and in the pharmaceutical industry due to its anti-inflammatory, antibacterial, antioxidant, anti-cancer, and anti-Alzheimer properties. However, the large application of CCM is limited by its poor solubility in water and low stability. To enhance the bioavailability of CCM, and to protect it against the external degradation agents, a novel strategy, which consists in the preparation of semi-interpenetrating polymer networks, (s-IPNs) based on poly(N,N-dimethylaminoethyl methacrylate) entrapped in poly(acrylamide) networks, by a cryogelation technique, was developed in this work. All s-IPN cryogels were characterized by SEM, EDX, FTIR, and swelling at equilibrium as a function of pH. Functionalization of semi-IPN cryogel with monochlorotriazinyl-β-cyclodextrin (MCT-β-CD) led to IPN cryogel. The release profile of CCM from the composite cryogels was investigated at 37 °C, in pH 3. It was found that the cumulative release increased with the increase of the carrier hydrophobicity, as a result of increasing the cross-linking degree, the content and the molar mass of PDMAEMA. Fitting Higuchi, Korsmeyer–Peppas, and first order kinetic models on the CCM release profiles indicated the diffusion as the main driving force of drug release from the composite cryogels. 相似文献
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Cláudia M. Morais Valérie Montouillout Michael Deschamps Dinu Iuga Franck Fayon Filipe A. A. Paz João Rocha Christian Fernandez Dominique Massiot 《Magnetic resonance in chemistry : MRC》2009,47(11):942-947
From one‐ to two‐ and three‐dimensional MAS NMR solid‐state experiments involving 31P and 27Al, we show that the structure of microporous alumino‐phosphate AlPO4‐40 contains at least four times more sites than expected, and we attribute two types of AlIV sites. The newly described 27Al‐31P MQ‐HMQC opens new possibilities of describing details of three‐dimensional bounded networks. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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A parallel is considered between Burnat's “algebraic” approach [restricted to a genuine nonlinearity] and Martin's “differential” approach regarding their contribution to describing some nondegenerate one-dimensional gasdynamic regular interaction solutions. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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We present an experiment on the photodestruction of the NO2− anion at 266 nm. We have quantified the competition between photodetachment and photodissociation and have identified the nature of the photodissociation process from the photofragment angular distribution. This study involves a novel technique; time resolved multicoincident detection photofragment spectroscopy. A three-dimensional double exposure CCD camera is employed. The system provides the position (x,y) and the relative arrival time (t) of all fragments. In the case of photodissociation events, NO and O− fragments are detected for each event. The detection of multiple events per laser shot is made possible by using center-of-mass selection. 相似文献