全文获取类型
收费全文 | 1151篇 |
免费 | 26篇 |
国内免费 | 2篇 |
专业分类
化学 | 752篇 |
晶体学 | 42篇 |
力学 | 26篇 |
数学 | 133篇 |
物理学 | 226篇 |
出版年
2022年 | 13篇 |
2021年 | 15篇 |
2020年 | 13篇 |
2019年 | 14篇 |
2018年 | 12篇 |
2017年 | 17篇 |
2016年 | 32篇 |
2015年 | 21篇 |
2014年 | 23篇 |
2013年 | 68篇 |
2012年 | 51篇 |
2011年 | 69篇 |
2010年 | 31篇 |
2009年 | 37篇 |
2008年 | 49篇 |
2007年 | 62篇 |
2006年 | 47篇 |
2005年 | 50篇 |
2004年 | 42篇 |
2003年 | 28篇 |
2002年 | 28篇 |
2001年 | 19篇 |
2000年 | 20篇 |
1999年 | 20篇 |
1998年 | 20篇 |
1997年 | 13篇 |
1996年 | 25篇 |
1995年 | 26篇 |
1994年 | 18篇 |
1993年 | 19篇 |
1992年 | 18篇 |
1991年 | 16篇 |
1990年 | 17篇 |
1989年 | 14篇 |
1988年 | 15篇 |
1987年 | 9篇 |
1986年 | 16篇 |
1985年 | 17篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 14篇 |
1978年 | 11篇 |
1976年 | 10篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1972年 | 9篇 |
1971年 | 7篇 |
排序方式: 共有1179条查询结果,搜索用时 15 毫秒
1.
Synthesis of Small‐Sized,Porous, and Low‐Toxic Magnetite Nanoparticles by Thin POSS Silica Coating
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Swee Kuan Yen D. Prathyusha Varma Wei Mei Guo Dr. Vincent H. B. Ho Dr. Vimalan Vijayaragavan Dr. Parasuraman Padmanabhan Prof. Kishore Bhakoo Prof. Subramanian Tamil Selvan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):3914-3918
In this communication, we report the synthesis of small‐sized (<10 nm), water‐soluble, magnetic nanoparticles (MNPs) coated with polyhedral oligomeric silsesquioxanes (POSS), which contain either polyethylene glycol (PEG) or octa(tetramethylammonium) (OctaTMA) as functional groups. The POSS‐coated MNPs exhibit superparamagnetic behavior with saturation magnetic moments (51–53 emu g?1) comparable to silica‐coated MNPs. They also provide good colloidal stability at different pH and salt concentrations, and low cytotoxicity to MCF‐7 human breast epithelial cells. The relaxivity data and magnetic resonance (MR) phantom images demonstrate the potential application of these MNPs in bioimaging. 相似文献
2.
In this paper we present a polynomial-time algorithm that finds paths of length Ω((logn/loglogn)2) in undirected Hamiltonian graphs, improving the previous best of Ω(logn). 相似文献
3.
Complex impedance spectra were obtained on a crystal of CaCu3Ti4O12 (CCTO) from 289 to 456 K. As in the case of ceramic CCTO, these spectra can be interpreted as arising from a conducting material containing insulating barriers. This is then further evidence for the existence of planar defects within crystals of CCTO that act as insulating barriers and produce the large dielectric constant through a space charge mechanism. 相似文献
4.
Sang‐Uk Kim Choonkeun Lee Saimani Sundar Wonbong Jang Seung‐Jin Yang Haksoo Han 《Journal of Polymer Science.Polymer Physics》2004,42(23):4303-4312
A series of polyimides were synthesized from 2,2‐Bis(3,4‐dicarboxyphenyl)hexafluoropropane, 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane, and 4,4′‐oxydianiline by chemical imidization. The effects of the diamine ratios on the properties of the films were evaluated through the study of their thermal, electrical, and morphological properties. All the polymers exhibited better solubility in most of the organic solvents and hence were easily processable. Polyimides with more 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane exhibited better solubility and a low refractive index, which is highly desired for microelectronic applications. The dielectric constant and birefringence were strongly dependent on the fluorine content. With an increase in the fluorine substitution, both the dielectric constant and birefringence decreased. All the polymers exhibited high thermal stability (>400 °C). The absence of crystalline melting in differential scanning calorimetry and broad wide‐angle X‐ray diffraction patterns revealed the amorphous nature of the polymers, which was due to the presence of bulky CF3 groups and hinged ether linkages of the diamine component. The residual stress values decreased with an increase in the 4,4′‐oxydianiline content, and the results were in agreement with the dielectric constant. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4303–4312, 2004 相似文献
5.
Absolute total electron scattering cross sections for carbon dioxide have been measured at low electron energies using a photoelectron
source. The measurements have been carried out at 27 electron energies varying from 0.91–9.14 eV with an accuracy of ±3%.
The cross sections obtained in the present experiment have been compared with other measurements and theoretical computations. 相似文献
6.
7.
8.
9.
A. Subramanian T.-Y. Choi L.X. Dong J. Tharian U. Sennhauser D. Poulikakos B.J. Nelson 《Applied Physics A: Materials Science & Processing》2007,89(1):133-139
We report on a novel method for local control of shell engineering in multiwalled carbon nanotubes (MWNTs) using Joule-heating
induced electric breakdown. By modulating the heat dissipation along a nanotube, we can confine its thinning and shell breakdown
to occur within localized regions of peak temperatures, which are distributed over one-half of the NT length. The modulation
is achieved by using suitably designed nanomachined heat sinks with different degrees of thermal coupling at different parts
of a current-carrying nanotube. The location of electric breakdown occurs precisely at the regions of high temperatures predicted
by the classical finite-element model of Joule heating in the MWNT. The experiments herein provide new insight into the electric
breakdown mechanism and prove unambiguously that shell removal occurs due to thermal stress, underpinning the diffusive nature
of MWNTs. The method demonstrated here has the potential to be a powerful tool in realizing MWNT bearings with complex architectures
for use in integrated nanoelectromechanical systems (NEMS). In addition, the breakdown current and power in the nanotubes
are significantly higher than those observed in nanotubes without heat removal via additional heat sinks. This indicates future
avenues for enhancing the performance of MWNTs in electrical interconnect and nanoelectronic applications.
PACS 73.63.Fg; 65.80.+n 相似文献
10.