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1.
The original formula of Gibbs for the reversible work of critical nucleus formation is evaluated in three approximate ways for ordinary and heavy water. The least approximate way employs an equation of state to evaluate the pressure difference between the new and old phases. This form of the theory yields a temperature dependence for the nucleation rate close to that observed experimentally. This is a substantial improvement over the most commonly used (and most approximate) form of classical theory. 相似文献
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Sofian M. Kanan Fatin Samara Imad A. Abu-Yousef Naser Abdo Danial Tobias 《Research on Chemical Intermediates》2010,36(5):473-482
Ag (I) nanoclusters doped in mordenite zeolite were prepared and spectroscopically analyzed. Strong luminescence emission
that is dependent on the excitation wavelength was observed. These variations in the emission modes are due to the site selective
luminescence where various luminophores might be excited upon selecting the proper excitation wavelength. The selected material
was found to have strong affinity to remove the quinalphos pesticide, which is widely used for the protection of several vegetable
and fruit crops, from water bodies. HPLC and GC–MS techniques were used to follow the kinetic data and to identify the photodecomposition
products, respectively. The photodecomposition of quinalphos in the presence of the silver doped mordenite catalyst gives
different products compared to the irradiation of quinalphos without catalyst. The presence of the Ag-mordenite catalyst not
only adsorbs the quinalphos from the solution but it also reduces its toxic effect as tested on the fruit fly (Drosophila melanogaster). 相似文献
3.
Summary We prove a Schur test for mixed-norm spaces Lp,q, 1 < p,q < ∞. Also we prove another version of the Schur test for discrete weighted mixed-norm spaces lp,q w, 1 < p,q < ∞, and wis a weight. We show that if w 1, and w 2are two weight functions on the index sets Jx Iand K x Lrespectively, and A =(a ji, kl ) j∈J, i∈I, k∈K, l∈L is an infinite matrix, then under certain conditions, Ais a bounded operator from lp,q w1, 1 < p,q < ∞ to lp,q w2. This will be a key result in proving boundedness of important operators in our work in time-frequency analysis.</o:p> 相似文献
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Fourier-transform infrared spectroscopy (FTIR) was successfully used for quantitative determination of diethylene glycol in glycerin raw material. In addition to the pure samples of both diethylene glycol and glycerin, nine binary mixtures of the two components with mixing ratios ranging from (70 to 98)%wt were created and studied as a training set. Glycerine showed, thereby, characteristic infrared bands at 1110, 992, 974, and 922?cm?1 while those of diethylene glycol appear at 1085, 887, and 881?cm?1. The quantitative determination of diethylene glycol in binary mixtures with glycerin was achieved upon using the absorbance difference between the 992?cm?1 and the 881?cm?1 as well as between 1110 and 1085?cm?1 bands. With an average %error of 0.60 and 1.74, respectively and a limit of detection down to 0.85%, the created calibration curves from the training set were applied successfully to determine the composition of another eight binary mixtures of the two materials representing a validation set. The method was also applied to aqueous solutions of diethylene glycol and glycerin that contains (25 and 50)%wt water. Once more, training and validation sets of mixtures with different diethylene glycol and glycerin ratios at the two water percentages were prepared and measured. Again, successful determination of diethylene glycol in these aqueous solutions was achieved with an average %error of 0.92 and 0.47, respectively. 相似文献
6.
Moyet Matthew A. Kanan Sofian M. Varney Hannah M. Abu-Farha Nedal Gold Davis B. Lain William J. Pike Robert D. Patterson Howard H. 《Research on Chemical Intermediates》2019,45(12):5919-5933
Research on Chemical Intermediates - Phosphonium iodobismuthates(III) (MePh3P)3[Bi3I12] (1) and (Ph4P)3[Bi3I12] (2) were prepared, and X-ray crystal structures were determined for both complexes.... 相似文献
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Anthony Linden A. S. Muhammad Sofian C. Kuan Lee 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(12):o718-o720
At 160 K, one of the Cl atoms in the furanoid moiety of 3‐O‐acetyl‐1,6‐dichloro‐1,4,6‐trideoxy‐β‐d ‐fructofuranosyl 2,3,6‐tri‐O‐acetyl‐4‐chloro‐4‐deoxy‐α‐d ‐galactopyranoside, C20H27Cl3O11, is disordered over two orientations, which differ by a rotation of about 107° about the parent C—C bond. The conformation of the core of the molecule is very similar to that of 3‐O‐acetyl‐1,4,6‐trichloro‐1,4,6‐trideoxy‐β‐d ‐tagatofuranosyl 2,3,6‐tri‐O‐acetyl‐4‐chloro‐4‐deoxy‐α‐d ‐galactopyranoside, particularly with regard to the conformation about the glycosidic linkage. 相似文献
9.
Infrared study of UV-irradiated tungsten trioxide powders containing adsorbed dimethyl methyl phosphonate and trimethyl phosphate 总被引:1,自引:0,他引:1
Anil Waghe Sofian M. Kanan Imad Abu-Yousef Bruce Jensen Carl P. Tripp 《Research on Chemical Intermediates》2006,32(7):613-623
The photodecomposition of dimethyl methylphosphonate (DMMP) and trimethyl phosphate (TMP) adsorbed on monoclinic WO3 powders when irradiated by ultraviolet light (UV) in air, oxygen, and under evacuation was investigated using infrared spectroscopy
(IR). The IR spectra show that DMMP decomposes into methyl phosphonate upon exposure to 254 nm UV for 2 h at room temperature
in air. The same decomposition of DMMP occurs only at temperatures above 300°C without UV illumination. TMP differs from DMMP
in that the photodecomposition product is not the same as the decomposition product obtained by heating above 300°C. Thermal
decomposition leads to formation of a phosphate on the surface, whereas photodecomposition leads to the same adsorbed methyl
phosphonate as found for the thermal or photodecomposition of DMMP. Since TMP does not contain a P-CH3 bond, the formation of a methyl phosphonate on the surface after UV illumination involves a mechanism where CH3 groups migrate from the methoxy group to the phosphorous central atom. No decomposition is observed at room temperature when
DMMP or TMP adsorbed on WO3 is irradiated under vacuum or in nitrogen atmosphere. Therefore, the photodecomposition of either DMMP or TMP adsorbed on
WO3 at room temperature does not involve a reaction with the lattice oxygen but rather a reaction with the oxygen radicals produced
by the decomposition of ozone. 相似文献
10.
Anthony Linden A. S. Muhammad Sofian C. Kuan Lee 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(12):o711-o714
At 160 K, the glucopyranosyl ring in 1,6‐dichloro‐1,6‐dideoxy‐β‐d ‐fructofuranosyl 4‐chloro‐4‐deoxy‐α‐d ‐glucopyranoside monohydrate, C12H19Cl3O8·H2O, has a near ideal 4C1 chair conformation, while the fructofuranosyl ring has a 4T3 conformation. The conformation of the sugar molecule is quite different to that of sucralose, particularly in the conformation about the glycosidic linkage, which affects the observed pattern of intramolecular hydrogen bonds. A complex series of intermolecular hydrogen bonds links the sugar and water molecules into an infinite three‐dimensional framework. 相似文献