排序方式: 共有61条查询结果,搜索用时 15 毫秒
1.
Vukadin M. Leovac Goran A. Bogdanović Valerija I. Češljević Ljiljana S. Jovanović Sladjana B. Novaković Ljiljana S. Vojinović-Ješić 《Structural chemistry》2007,18(1):113-119
The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H2SalGT]Cl (1), and two complexes [Cu(HSalGT)X2]·H2O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural
complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the
basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH3)3 group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C–H…X intramolecular interactions.
The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption
spectra. 相似文献
2.
Carlos Javier Villagomez Tomaso Zambelli Sébastien Gauthier André Gourdon Sladjana Stojkovic Christian Joachim 《Surface science》2009,603(10-12):1526-1532
An isomer of the methylterrylene molecule was adsorbed both on Cu(111) and on a NaCl bilayer deposited on Cu(111) and imaged by ultra high vacuum scanning tunneling microscopy at low temperature (5 K). On the bare metal surface, the STM images do not reveal any intramolecular resolution and do not depend on the applied tunnel bias. On the contrary, the images acquired at specific bias voltages for the molecule on the salt layer show a striking similarity with the spatial distribution of the electronic probability density in the highest occupied molecular orbital (HOMO) and in the lowest unoccupied molecular orbital (LUMO) of free methylterrylene. They are well reproduced by elastic scattering quantum chemistry calculations. These data provide a direct view of the hyperconjugative interaction between the methyl group and the frontier orbitals of terrylene. 相似文献
3.
Photoinduced charge separation reactions of J-aggregates coated on silver nanoparticles 总被引:2,自引:0,他引:2
Hranisavljevic J Dimitrijevic NM Wurtz GA Wiederrecht GP 《Journal of the American Chemical Society》2002,124(17):4536-4537
The photochemistry of cyanine J-aggregates on the surface of colloidal Ag nanoparticles is reported. The photochemistry is initiated through ultrafast photoexcitation of the plasmon band in Ag nanoparticles, producing an enhanced near-field that interacts with the J-aggregate monolayer. Through transient absorption spectroscopy, we show that photoexcitation of the plasmon in Ag nanoparticles leads to exciton dynamics that differ strongly from J-aggregates alone or for J-aggregate monolayers on bulk metal surfaces. Specifically, charge-separated states with a lifetime of approximately 300 ps between the J-aggregate and Ag colloid are formed. The reduction of the Ag nanoparticles is shown to be a multielectron process. 相似文献
4.
Predrag M. Rajković Sladjana D. Marinković Miomir S. Stanković 《The Ramanujan Journal》2006,12(2):245-255
We construct the sequence of orthogonal polynomials with respect to an inner product which is defined by q-integrals over a collection of intervals in the complex plane. We prove that they are connected with little q-Jacobi polynomials. For such polynomials we discuss a few representations, a recurrence relation, a difference equation,
a Rodrigues-type formula and a generating function.
2000 Mathematics Subject Classification Primary—33D45, 42C05 相似文献
5.
The existence of a positive solution for nonlinear fractional differential equations with integral boundary value conditions
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Alberto Cabada Sladjana Dimitrijevic Tatjana Tomovic Suzana Aleksic 《Mathematical Methods in the Applied Sciences》2017,40(6):1880-1891
In this paper, first, we consider the existence of a positive solution for the nonlinear fractional differential equation boundary value problem where 0≤λ < 1,CDα is the Caputo's differential operator of order α, and f:[0,1] × [0,∞)→[0,∞) is a continuous function. Using some cone theoretic techniques, we deduce a general existence theorem for this problem. Then, we consider two following more general problems for arbitrary α, 1≤n < α≤n + 1: Problem 1: where , 0≤λ < k + 1; Problem 2: where 0≤λ≤α and Dα is the Riemann–Liouville fractional derivative of order α. For these problems, we give existence results, which improve recent results in the literature. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
6.
Dalibor Stankovic Dragan Manojlovic Goran Roglic Sladjana Kostic‐Rajacic Ivan Andjelkovic Biljana Dojcinovic Jelena Mutic 《Electroanalysis》2011,23(8):1928-1933
The determination of Pb and Cd with a Nafion‐modified glassy carbon electrode and Cu‐DPABA complex (Cu‐DPABA–NA/GCE; DPABA is methyl 3,5‐bis{bis‐[(pyridin‐2‐yl)methyl]amino}methyl‐benzoate) as an alternative electrode for anodic stripping voltammetry was described. Pb and Cd were accumulated in acetate buffer pH 4 at a potential of ?1.4 V (vs. Ag/AgCl electrode) for 120 s followed by a DPASV scan from ?1.2 to ?0.2 V. Under optimum conditions the calibration curves were linear in the range of 4.8×10?9–5.0×10?5 and 5.0×10?9–5×10?5 mol L?1 for Pb and Cd, respectively. Detection limits were 1.8×10?9 and 1.2×10?9 mol L?1 for Pb and Cd, respectively. Different parameters and conditions, such as membrane ingredients, accumulation time, potential and pH value were optimized. A study of interfering substances was also performed. A significant increase in current was achieved at the modified electrode in comparison with the bare glassy carbon electrode. The validation of the proposed method was made by Pb and Cd determination in the certified reference material Groundwater CRM 610 (BCR, Community Bureau of Reference, Brussels, Belgium). The electrode was successfully applied for determination of Pb and Cd in river water with a high content of organic contaminants without any pretreatment. 相似文献
7.
Miomir S. Stankovi?Sladjana D. Marinkovi? Predrag M. Rajkovi? 《Applied mathematics and computation》2011,218(6):2439-2448
In the recent development in various disciplines of physics, it is noted the need for including the deformed versions of the exponential functions. In last two decades, the Tsallis and Kaniadakis versions have found a lot of applications. In this paper, we consider the deformations which have two purposes. First, we introduce them like beginning of a more general mathematical approach where the Tsallis and Kaniadakis exponential functions are the special cases. Then, we wish to pay attention to the mathematical community that they have a lot of interesting properties from mathematical point of view and possibilities in applications. Really, we will show the differential and difference properties of our deformations which are important for the formation and explanation of continuous and discrete models of numerous phenomena. 相似文献
8.
A rapid, relatively sensitive, and low-cost method for the determination of water-soluble urea content in dermatological therapy products and cosmetics is proposed using a new spectrophotometric assay with water as the only extraction solvent. Spectrophotometric methods involve addition of a known excess of bromate to urea in an acid medium, followed by the determination of residual bromine and chlorine reacting with methyl orange and measurement of absorbance at 505 nm. The absorbance increases linearly with urea concentration (r = 0.9998). The systems obey Beer's law for 6 - 90 microg ml(-1). The calculated apparent molar absorbance values are found to be 4.537 x 10(3) dm(3) mol(-1) cm(-1) and the Sandell's sensitivity is 0.013 microg cm(-2). The variables affecting the rate of the reaction were investigated. The relative standard deviation for five-replication determination of 60 microg ml(-1) urea was 2.1% and the detection limit of the method is 0.34 ng ml(-1). 相似文献
9.
M.L. Dubernet V. Boudon M.S. Dimitrijevic C. Joblin G. Leto P.A. Loboda N.J. Mason G. Mulas L.A. Nuñez N. Piskunov G. Rixon E. Roueff A. Ryabtsev B. Schmitt J. Tennyson N.A. Walton C.J. Zeippen 《Journal of Quantitative Spectroscopy & Radiative Transfer》2010,111(15):2151-2159
The Virtual Atomic and Molecular Data Centre (VAMDC, http://www.vamdc.eu) is a European Union funded collaboration between groups involved in the generation, evaluation, and use of atomic and molecular data. VAMDC aims to build a secure, documented, flexible and interoperable e-science environment-based interface to existing atomic and molecular data. The project will cover establishing the core consortium, the development and deployment of the infrastructure and the development of interfaces to the existing atomic and molecular databases. It will also provide a forum for training potential users and dissemination of expertise worldwide. This review describes the scope of the VAMDC project; it provides a survey of the atomic and molecular data sets that will be included plus a discussion of how they will be integrated. Some applications of these data are also discussed. 相似文献
10.
de la Garza L Saponjic ZV Dimitrijevic NM Thurnauer MC Rajh T 《The journal of physical chemistry. B》2006,110(2):680-686
Control of surface states of titanium dioxide nanoparticles using 2-(3,4-dihydroxyphenyl)ethylamine (dopamine) and 3,4-dihydrophenylacetic acid, which act as ligands to the undercoordinated surface sites (carrier traps), is demonstrated by electrochemical techniques. The deepest traps were found to be most reactive and are selectively removed by the addition of the ligands which enhances the kinetics of electron accumulation in the film. Furthermore, a shift in the Fermi level to more positive potentials was detected for electrodes modified with the negatively charged ligand (3,4-dihydrophenylacetic acid) compared to that of electrodes modified with the positively charged ligand (dopamine). The presence of the negative charge on the ligand also contributed to the underpotential of hydrogen evolution on 3,4-dihydrophenylacetic acid-modified electrodes. 相似文献