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排序方式: 共有59条查询结果,搜索用时 15 毫秒
1.
Cui Shisheng Shanbhag Uday Staudigl Mathias Vuong Phan 《Computational Optimization and Applications》2022,82(2):465-498
Computational Optimization and Applications - We develop a globalized Proximal Newton method for composite and possibly non-convex minimization problems in Hilbert spaces. Additionally, we impose... 相似文献
2.
Ganapati V. Shanbhag 《Tetrahedron letters》2006,47(2):141-143
Heterogeneous intermolecular hydroamination of alkynes with aromatic amines using inexpensive transition metal-exchanged clay catalysts was investigated. Reaction of terminal alkynes with aromatic amines gave higher yields of imines. 相似文献
3.
A rapid and selective method for the solvent extraction of Sb(III) using malachite green (C. I. Basic green 4) has been described. Effect of different parameters affecting the extraction coefficient value of Sb(III) such as acidity, time of equilibration, KI concentration, solvents, anions, etc. has been studied. For various elements the separation factor has been evaluated. The stoichiometry of the extracted species has been determined by the method of substoichiometric extraction. The decontamination factor for some elements using substoichiometric quantities of the extracting agent has been evaluated. Radiotracers were employed for the extraction studies. The method elaborated has been employed for the quantitative determination of antimony in normal, benign and cancerous tissues of the human brain. 相似文献
4.
K. S. Viswanathan G. S. Dwarakanath V. V. Shanbhag 《Proceedings Mathematical Sciences》1971,74(3):115-132
The structure of strong shock waves in monatomic gases is studied using the Fokker-Planck model to represent the particle collisions and the Mott-Smith distribution to describe the distribution function within the shock front. The differential equation governing the variation of the density within the shock is derived by using the variational principle. The thickness of the shock front is evaluated numerically for various monatomic gases for Mach numbers varying from 2 to 20, and besides, the variation of the shock thickness with viscosity is also studied for different gases. Several parameters of physical interest within the shock, such as density, temperature and mean velocity of flow are evaluated numerically and detailed curves showing their variation within the shock are presented for different Mach numbers. It is found that the temperature rises very steeply, reaches a maximum within a distance less than half the thickness of the shock and then diminishes slowly to attain its asymptotic downstream values. The variation of the mean velocity is slow for weak shocks, but for higher Mach numbers, the mean velocity diminishes steeply and reaches the downstream values within half the thickness of the shock. 相似文献
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Traditionally, most stochastic approximation (SA) schemes for stochastic variational inequality (SVI) problems have required the underlying mapping to be either strongly monotone or monotone and Lipschitz continuous. In contrast, we consider SVIs with merely monotone and non-Lipschitzian maps. We develop a regularized smoothed SA (RSSA) scheme wherein the stepsize, smoothing, and regularization parameters are reduced after every iteration at a prescribed rate. Under suitable assumptions on the sequences, we show that the algorithm generates iterates that converge to the least norm solution in an almost sure sense, extending the results in Koshal et al. (IEEE Trans Autom Control 58(3):594–609, 2013) to the non-Lipschitzian regime. Additionally, we provide rate estimates that relate iterates to their counterparts derived from a smoothed Tikhonov trajectory associated with a deterministic problem. To derive non-asymptotic rate statements, we develop a variant of the RSSA scheme, denoted by aRSSA\(_r\), in which we employ a weighted iterate-averaging, parameterized by a scalar r where \(r = 1\) provides us with the standard averaging scheme. The main contributions are threefold: (i) when \(r<1\) and the parameter sequences are chosen appropriately, we show that the averaged sequence converges to the least norm solution almost surely and a suitably defined gap function diminishes at an approximate rate \(\mathcal{O}({1}\slash {\root 6 \of {k}})\) after k steps; (ii) when \(r<1\), and smoothing and regularization are suppressed, the gap function admits the rate \(\mathcal{O}({1}\slash {\sqrt{k}})\), thus improving the rate \(\mathcal{O}(\ln (k)/\sqrt{k})\) under standard averaging; and (iii) we develop a window-based variant of this scheme that also displays the optimal rate for \(r < 1\). Notably, we prove the superiority of the scheme with \(r < 1\) with its counterpart with \(r=1\) in terms of the constant factor of the error bound when the size of the averaging window is sufficiently large. We present the performance of the developed schemes on a stochastic Nash–Cournot game with merely monotone and non-Lipschitzian maps. 相似文献
7.
Balaji V. S. Iyer Sachin Shanbhag Vinay A. Juvekar Ashish K. Lele 《Journal of Polymer Science.Polymer Physics》2008,46(21):2370-2379
In a topologically constraining environment the size of a flexible nonconcatenated ring polymer (macrocycles) and its dynamics are known to differ from that of linear polymers. Hence, the diffusion coefficient of ring polymers can be expected to be different from linear chains. We present here scaling arguments for the concentration and molecular weight dependence of self‐diffusion coefficient of ring polymers in semidilute solutions, and show that contrary to expectations these scaling relations are identical to what is known for linear polymers. At higher concentrations excluded volume interactions arising from possibilities of segmental overlap can become effective for large ring polymers. In this regime the diffusion coefficient of large ring polymers shows a relatively weaker dependence on concentration and molecular weight. ©2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 2370–2379, 2008 相似文献
8.
Probability Theory and Related Fields - 相似文献
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10.
D. W. Rangnekar V. R. Kanetkar G. S. Shankarling J. V. Malanker C. R. Shanbhag 《Journal of heterocyclic chemistry》1999,36(5):1213-1214
Ethyl quinoxalin-3( 4 H)-on-2-ylacetate was prepared by the condensation of 1,2-diaminobenzene and diethyl oxalacetate (sodium salt). The key quinoxaline intermediate was condensed with a variety of 4-dialkylaminobenzaldehydes/substituted benzaldehydes to yield novel brilliant quinoxalin-2-yl styryl dyes which were applied on polyester fibers as disperse dyes and their dyeing properties were studied. 相似文献