全文获取类型
收费全文 | 605篇 |
免费 | 44篇 |
国内免费 | 1篇 |
专业分类
化学 | 474篇 |
晶体学 | 4篇 |
力学 | 8篇 |
数学 | 99篇 |
物理学 | 65篇 |
出版年
2023年 | 13篇 |
2022年 | 10篇 |
2021年 | 20篇 |
2020年 | 17篇 |
2019年 | 10篇 |
2018年 | 17篇 |
2017年 | 7篇 |
2016年 | 26篇 |
2015年 | 31篇 |
2014年 | 35篇 |
2013年 | 41篇 |
2012年 | 43篇 |
2011年 | 57篇 |
2010年 | 34篇 |
2009年 | 26篇 |
2008年 | 40篇 |
2007年 | 31篇 |
2006年 | 37篇 |
2005年 | 22篇 |
2004年 | 22篇 |
2003年 | 29篇 |
2002年 | 14篇 |
2001年 | 4篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 2篇 |
1939年 | 1篇 |
1931年 | 2篇 |
1917年 | 2篇 |
排序方式: 共有650条查询结果,搜索用时 15 毫秒
1.
Daniel C. Cohen Peter Orlik 《Transactions of the American Mathematical Society》2005,357(8):3031-3050
We study the Gauss-Manin connection for the moduli space of an arrangement of complex hyperplanes in the cohomology of a complex rank one local system. We define formal Gauss-Manin connection matrices in the Aomoto complex and prove that, for all arrangements and all local systems, these formal connection matrices specialize to Gauss-Manin connection matrices.
2.
Exponential growth is estimated for integral operators with continuous periodic kernels of exponential type. The result is
applied to the boundary-value problem for a general hyperbolic differential equation having periodic coefficients with Goursat
boundary conditions. It is proved that the exponential characteristic for such a boundary-value problem has canonical form.
__________
Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 38, Suzdal
Conference-2004, Part 3, 2006. 相似文献
3.
In this article we focus on the multiplicities of resonances, ratios of resonant over non-resonant states and rescattering processes in heavy ion collisions. Therefore we utilize a hadron transport model (UrQMD v1.3). We find that rescattering of decay particles is of great importance when studying resonances in a hadronic medium. 相似文献
4.
5.
A study was carried out on the composition and nature of the stabilizing additive on the activity of nickel-containing composites
based on zirconia in the methane steam conversion. The methane conversions were 91–99% on Ni/ZrO2(Y, Sc, Ce) at 700–800 °C. 相似文献
6.
S. N. Orlik V. P. Stasevich V. L. Struzhko M. G. Martsenyuk-Kukharuk 《Theoretical and Experimental Chemistry》1996,32(4):209-212
New data are presented for the reduction of nitric oxide by C1-C4 hydrocarbons (alkanes and olefins) on active copper, cerium, and cobalt zeolite catalysts both with and without oxygen in the reaction mixture. The following hydrocarbon reactivity series were obtained. Olefins: C4H8 > C3H6 > C2H4. Alkanes: C4H10 > C3H8 > CH4.L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, 252039 Kiev, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 32, No. 4, pp. 238–242, July–August, 1996. Original article submitted September 14, 1995. 相似文献
7.
Wagner-Czauderna Elżbieta Orlik Marek Zajączkowska Agnieszka Kalinowski Marek K. 《Transition Metal Chemistry》2004,29(3):276-279
Microsolvation of the [Ni(acac)(tmen)]+ complex by a series of aliphatic n-alcohols (Solv) has been studied in ClCH2CH2Cl solutions by spectrophotometry. Based on the changes in the electronic spectrum of the afore-mentioned complex, observed under the influence of any alcohol, the equilibrium constants for the formation of the [Ni(acac)(tmen)Solv]+ and [Ni(acac)(tmen)Solv2]+ species have been computed according to the algorithm presented in this work. It was found that, in all the systems studied, the stability of five-coordinated [Ni(acac)(tmen)Solv]+ is higher than that of octahedral [Ni(acac)(tmen)Solv2]+. The resulting values are discussed in terms of the Lewis basicity of alcohols. 相似文献
8.
Dieter Seebach Laurent Schaeffer Franois Gessier Pascal Bindschdler Corinna Jger Delphine Josien Sascha Kopp Grald Lelais YogeshR. Mahajan Peter Micuch Radovan Sebesta BerndW. Schweizer 《Helvetica chimica acta》2003,86(6):1852-1861
Multigram amounts of suitably protected β2‐amino acids with 17 of the 20 proteinogenic side chains are prepared by diastereoselective reactions of Li, B, or Ti enolates of the corresponding 3‐acyl‐4‐isopropyl‐5,5‐diphenyloxazolidin‐2‐ones (acyl‐DIOZ; 1 ) with appropriate electrophiles (amidomethylation, hydroxyalkylation, (benzyloxycarbonyl)methylation) in yields of 55–90% and with diastereoselectivities of 80 to >97% (Scheme). The primary products 2 – 8 thus obtained are converted to protected β2‐amino acids by standard procedures (Table 1). Many of the DIOZ derivatives are highly crystalline compounds (31 X‐ray crystal structures in Table 2). The chiral auxiliary DIOZ, readily prepared in either enantiomeric form, is recovered with high yield. 相似文献
9.
Optical sensor systems for bioprocess monitoring 总被引:3,自引:0,他引:3
Bioreactors are closed systems in which microorganisms can be cultivated under defined, controllable conditions that can be optimized with regard to viability, reproducibility, and product-oriented productivity. To drive the biochemical reaction network of the biological system through the desired reaction optimally, the complex interactions of the overall system must be understood and controlled. Optical sensors which encompass all analytical methods based on interactions of light with matter are efficient tools to obtain this information. Optical sensors generally offer the advantages of noninvasive, nondestructive, continuous, and simultaneous multianalyte monitoring. However, at this time, no general optical detection system has been developed. Since modern bioprocesses are extremely complex and differ from process to process (e.g., fungal antibiotic production versus mammalian cell cultivation), appropriate analytical systems must be set up from different basic modules, designed to meet the special demands of each particular process. In this minireview, some new applications in bioprocess monitoring of the following optical sensing principles will be discussed: UV spectroscopy, IR spectroscopy, Raman spectroscopy, fluorescence spectroscopy, pulsed terahertz spectroscopy (PTS), optical biosensors, in situ microscope, surface plasmon resonance (SPR), and reflectometric interference spectroscopy (RIF). 相似文献
10.
Orlik S. N. Ostapyuk V. A. Alekseenko L. M. 《Theoretical and Experimental Chemistry》2002,38(3):195-198
The possibility of making products of partial oxidation, alcohols and acids in particular, by the reaction of C3-C4 alkanes with nitrogen monoxide over oxide and zeolite catalysts is demonstrated. The most effective catalysts are CeO2 and Fe-TsVK. The dependence of the rate and selectivity of the process on the reaction conditions has been established. 相似文献