Two-dimensional capillary gas chromatography without intermediate trapping. Electron capture detector quantitation of an amino alcohol (KABI 2128) in serum after trifluoroacetylation

A two- dimensional gas chromatograph based on the Deans switching principle is described. The unit comprises two separate ovens, each containing a fused silica capillary column. The columns are joined in a specially designed manifold permitting heart cuts to be performed without significant decrease in efficiency. The switching speed and the retention time stability of the system made it possible to perform heart cuts of only a few seconds' duration. The system has been used under isothermal conditions for the determination of an amino alcohol (KABI 2128) in the low ng/ml range after trifluoroacetylation and with electron capture detection. A much shorter clean-up procedure could be used in combination with the two-dimensional gas chromatograph as compared to a method using a single glass capillary column.     

On the determination of the number of periodic (or closed) solutions of a scalar differential equation with convexity

It is well known that a scalar differential equation , where f(t,x) is continuous, T-periodic in t and weakly convex or concave in x has no, one or two T-periodic solutions or a connected band of T-periodic solutions. The last possibility can be excluded if f(t,x) is strictly convex or concave for some t in the period interval. In this paper we investigate how the actual number of T-periodic solutions for a given equation of this type in principle can be determined, if f(t,x) is also assumed to have a continuous derivative . It turns out that there are three cases. In each of these cases we indicate the monotonicity properties and the domain of values for the function P(ξ)=S(ξ)−ξ, where S(ξ) is the Poincaré successor function. From these informations the actual number of periodic solutions can be determined, since a zero of P(ξ) represents a periodic solution.     

Ueber eine elektrolyt-kolloid-kristallinische Flüssigkeit

Ohne Zusammenfassung     

A Necessary and Sufficient Condition for a Linear Differential System to be Strongly Monotone

In order to present the results of this note, we begin withsome definitions. Consider a differential system [formula] where IR is an open interval, and f(t, x), (t, x)IxRⁿ, is acontinuous vector function with continuous first derivativesf_r/x_s, r, s=1, 2, ..., n. Let D_xf(t, x), (t, x)IxRⁿ, denote the Jacobi matrix of f(t,x), with respect to the variables x₁, ..., x_n. Let x(t, t₀,x₀), tI(t₀, x₀) denote the maximal solution of the system (1)through the point (t₀, x₀)IxRⁿ. For two vectors x, yRⁿ, we use the notations x>y and x>>yaccording to the following definitions: [formula] An nxn matrix A=(a_rs) is called reducible if n2 and there existsa partition [formula] (p1, q1, p+q=n) such that [formula] The matrix A is called irreducible if n=1, or if n2 and A isnot reducible. The system (1) is called strongly monotone if for any t₀I, x₁,x₂Rⁿ [formula] holds for all t>t₀ as long as both solutions x(t, t₀, x_i),i=1, 2, are defined. The system is called cooperative if forall (t, x)IxRⁿ the off-diagonal elements of the nxn matrix D_xf(t,x) are nonnegative. 1991 Mathematics Subject Classification34A30, 34C99.     

Localization of Closed (or Periodic) Solutions of a Differential System with Concave Nonlinearities

Consider a scalar differential equation , where I is an open interval containing [0,T]. Assumethat f(t, x) is continuous with a continuous derivative , and weakly concave (or weakly convex)in x for all t I, though strictly concave (or strictly convex)for some t [0, T]. It is well known that in this case therecan be either no, one or two closed solutions; that is, solutions(t) for which (0) = (T) If there are two closed solutions, thenthe greater has a negative characteristic exponent and the smallerhas a positive one. It is easily seen that this is equivalentto a statement on localization of closed solutions. It is shownhow this statement can be generalized to systems of differentialequations . The requirements are that the coordinate functions ) be continuous with continuous derivatives with respect to x₁,x₂, ...,x_n, that the f_j are weakly concave (or weakly convex)in , and that a certain condition pertaining to strict concavity (or strict convexity) is fulfilled.2000 Mathematics Subject Classification 34C25, 34C12.